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A Water-Stable Metal–Organic Framework with Highly Acidic Pores for Proton-Conducting Applications

Taylor, Jared M., Dawson, Karl W., Shimizu, George K. H.·2013·Journal of the American Chemical Society

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Abstract

Metal-organic framework (MOF) materials are a nontraditional route to ion conductors, but their crystallinity can give insight into molecular-level transport mechanisms. However, some MOFs can be structurally compromised in humid environments. A new 3D metal-organic framework, PCMOF-5, is reported which conducts protons above 10(-3) S/cm at 60 °C and 98% relative humidity. The MOF contains free phosphonic acid groups, shows high humidity stability, and resists swelling in the presence of hydration. Channels filled with crystallographically located water and acidic groups are also observed.

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Authors: Taylor, J. M., Dawson, K. W., & Shimizu, G. K. H.
Venue: Journal of the American Chemical Society
Publisher: American Chemical Society (ACS)
Published: 2013-01-14
Volume: 135
Issue: 4
Pages: 1193-1196
ISSN: 0002-7863 (ISSN-L)
1520-5126
DOI: 10.1021/ja310435e
OpenAlex: W1968550114
Cited by: 440
References: 54
FWCI: 25.77
Type: journal article
Language: en
Open access: closed

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A Water-Stable Metal–Organic Framework with Highly Acidic Pores for Proton-Conducting Applications

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