The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Intrinsic White-Light Emission from Layered Hybrid Perovskites
Abstract
We report on the second family of layered perovskite white-light emitters with improved photoluminescence quantum efficiencies (PLQEs). Upon near-ultraviolet excitation, two new Pb-Cl and Pb-Br perovskites emit broadband "cold" and "warm" white light, respectively, with high color rendition. Emission from large, single crystals indicates an origin from the bulk material and not surface defect sites. The Pb-Br perovskite has a PLQE of 9%, which is undiminished after 3 months of continuous irradiation. Our mechanistic studies indicate that the emission has contributions from strong electron-phonon coupling in a deformable lattice and from a distribution of intrinsic trap states. These hybrids provide a tunable platform for combining the facile processability of organic materials with the structural definition of crystalline, inorganic solids.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Ye, S., Xiao, F., Pan, Y. X., Ma, Y. Y., & Zhang, Q. Y. (2010) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2010.07.001 · Cited by 2,203
An improved experimental determination of external photoluminescence quantum efficiency
de Mello, J. C., Wittmann, H. F., & Friend, R. H. (1997) · Advanced Materials · doi:10.1002/adma.19970090308 · Cited by 2,056
Excitation-power dependence of the near-band-edge photoluminescence of semiconductors
Schmidt, T., Lischka, K., & Zulehner, W. (1992) · Physical Review B · doi:10.1103/physrevb.45.8989 · Cited by 1,116
Tongay, S., Suh, J., Ataca, C., Fan, W., Luce, A., Kang, J. S., Liu, J., Ko, C., Raghunathanan, R., Zhou, J., et al. (2013) · Scientific Reports · doi:10.1038/srep02657 · Cited by 1,086
Self-Assembly of Broadband White-Light Emitters
Dohner, E. R., Hoke, E. T., & Karunadasa, H. I. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411045r · Cited by 784
Self-citationElectronic structures of lead iodide based low-dimensional crystals
Umebayashi, T., Asai, K., Kondo, T., & Nakao, A. (2003) · Physical Review B · doi:10.1103/physrevb.67.155405 · Cited by 539
Fonoberov, V. A., Alim, K. A., Balandin, A. A., Xiu, F., & Liu, J. (2006) · Physical Review B · doi:10.1103/physrevb.73.165317 · Cited by 437
Fluorescence quenching caused by aggregation of water-soluble CdSe quantum dots
Noh, M., Kim, T., Lee, H., Kim, C.-K., Joo, S.-W., & Lee, K. (2010) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2010.01.059 · Cited by 229
A Semiconductor Bulk Material That Emits Direct White Light
Ki, W., & Li, J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801601y · Cited by 198
Roushan, M., Zhang, X., & Li, J. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201105110 · Cited by 151
Cited by
Atomically thin two-dimensional organic-inorganic hybrid perovskites
Dou, L., Wong, A. B., Yu, Y., Lai, M., Kornienko, N., Eaton, S. W., Fu, A., Bischak, C. G., Ma, J., Ding, T., et al. (2015) · Science · doi:10.1126/science.aac7660 · Cited by 1,372
White-Light Emission from Layered Halide Perovskites
Smith, M. D., & Karunadasa, H. I. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00433 · Cited by 1,115
Self-citationLi, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires
Zhang, D., Eaton, S. W., Yu, Y., Dou, L., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05404 · Cited by 1,002
Trap States in Lead Iodide Perovskites
Wu, X., Trinh, M. T., Niesner, D., Zhu, H., Norman, Z., Owen, J. S., Yaffe, O., Kudisch, B. J., & Zhu, X.-Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512833n · Cited by 988
Scaling law for excitons in 2D perovskite quantum wells
Blancon, J.-C., Stier, A. V., Tsai, H., Nie, W., Stoumpos, C. C., Traoré, B., Pedesseau, L., Kepenekian, M., Katsutani, F., Noe, G. T., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-04659-x · Cited by 833
One-dimensional organic lead halide perovskites with efficient bluish white-light emission
Yuan, Z., Zhou, C., Tian, Y., Shu, Y., Messier, J., Wang, J. C., van de Burgt, L. J., Kountouriotis, K., Xin, Y., Holt, E., et al. (2017) · Nature Communications · doi:10.1038/ncomms14051 · Cited by 804
Tuning the Luminescence of Layered Halide Perovskites
Smith, M. D., Connor, B. A., & Karunadasa, H. I. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00477 · Cited by 802
Self-citationLuminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency
Zhou, C., Lin, H., Tian, Y., Yuan, Z., Clark, R., Chen, B., van de Burgt, L. J., Wang, J. C., Zhou, Y., Hanson, K., et al. (2018) · Chemical Science · doi:10.1039/c7sc04539e · Cited by 657
Synthetic Approaches for Halide Perovskite Thin Films
Dunlap-Shohl, W. A., Zhou, Y., Padture, N. P., & Mitzi, D. B. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00318 · Cited by 631
A foundation model for atomistic materials chemistry
Batatia, I., Benner, P., Chiang, Y., Elena, A. M., Kovács, D. P., Riebesell, J., Advincula, X. R., Asta, M., Avaylon, M., Baldwin, W. J., et al. (2024) · arXiv · doi:10.48550/arxiv.2401.00096 · Cited by 604
Pan, J., Sarmah, S. P., Murali, B., Dursun, I., Peng, W., Parida, M. R., Liu, J., Sinatra, L., Alyami, N., Zhao, C., et al. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b02460 · Cited by 527
Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites
Mao, L., Guo, P., Kepenekian, M., Hadar, I., Katan, C., Even, J., Schaller, R. D., Stoumpos, C. C., & Kanatzidis, M. G. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08691 · Cited by 508
Two-dimensional halide perovskite nanomaterials and heterostructures
Shi, E., Gao, Y., Finkenauer, B. P., Akriti, A., Coffey, A. H., & Dou, L. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00886d · Cited by 445
Lyu, M., Yun, J., Chen, P., Hao, M., & Wang, L. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602512 · Cited by 432
Colloidal Organohalide Perovskite Nanoplatelets Exhibiting Quantum Confinement
Tyagi, P., Arveson, S. M., & Tisdale, W. A. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00664 · Cited by 416
Layered Halide Double Perovskites: Dimensional Reduction of Cs2AgBiBr6
Connor, B. A., Leppert, L., Smith, M. D., Neaton, J. B., & Karunadasa, H. I. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01543 · Cited by 396
Self-citationEnhanced Charge Transport in 2D Perovskites via Fluorination of Organic Cation
Zhang, F., Kim, D. H., Lu, H., Park, J.-S., Larson, B. W., Hu, J., Gao, L., Xiao, C., Reid, O. G., Chen, X., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b00972 · Cited by 382
Mn2+‐Doped Metal Halide Perovskites: Structure, Photoluminescence, and Application
Su, B., Zhou, G., Huang, J., Song, E., Nag, A., & Xia, Z. (2021) · Laser & Photonics Reviews · doi:10.1002/lpor.202000334 · Cited by 319
Yangui, A., Garrot, D., Lauret, J. S., Lusson, A., Bouchez, G., Deleporte, E., Pillet, S., Bendeif, E. E., Castro, M., Triki, S., et al. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b06211 · Cited by 312
Broadband Extrinsic Self‐Trapped Exciton Emission in Sn‐Doped 2D Lead‐Halide Perovskites
Yu, J., Kong, J., Hao, W., Guo, X., He, H., Leow, W. R., Liu, Z., Cai, P., Qian, G., Li, S., et al. (2019) · Advanced Materials · doi:10.1002/adma.201806385 · Cited by 284
Han, Y., Yue, S., & Cui, B. (2021) · Advanced Science · doi:10.1002/advs.202004805 · Cited by 282
Perovskite Nanocrystals as a Color Converter for Visible Light Communication
Dursun, I., Shen, C., Parida, M. R., Pan, J., Sarmah, S. P., Priante, D., Alyami, N., Liu, J., Saidaminov, M. I., Alias, M. S., et al. (2016) · ACS Photonics · doi:10.1021/acsphotonics.6b00187 · Cited by 272
Exciton Binding Energy and the Nature of Emissive States in Organometal Halide Perovskites
Zheng, K., Zhu, Q., Abdellah, M., Messing, M. E., Zhang, W., Generalov, A., Niu, Y., Ribaud, L., Canton, S. E., & Pullerits, T. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01252 · Cited by 268
Zero-Dimensional Cesium Lead Halides: History, Properties, and Challenges
Akkerman, Q. A., Abdelhady, A. L., & Manna, L. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b00572 · Cited by 258
Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications
Zhou, K., Qi, B., Liu, Z., Wang, X., Sun, Y., & Zhang, L. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202411671 · Cited by 228
Plasmonic–perovskite solar cells, light emitters, and sensors
Ai, B., Fan, Z., & Wong, Z. J. (2022) · Microsystems & Nanoengineering · doi:10.1038/s41378-021-00334-2 · Cited by 172
Real-time and ultrasensitive humidity sensor based on lead-free Cs2SnCl6 perovskites
Pi, M., Wu, D., Wang, J., Chen, K., He, J., Yang, J., Zhang, D., Chen, S., & Tang, X. (2022) · Sensors and Actuators B: Chemical · doi:10.1016/j.snb.2021.131084 · Cited by 65
Metadata
- Authors
- Dohner, E. R., Jaffe, A., Bradshaw, L. R., & Karunadasa, H. I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-09-16
- Volume
- 136
- Issue
- 38
- Pages
- 13154-13157
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2332549384
- Cited by
- 1,077
- References
- 10
- FWCI
- 26.00
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
