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A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts
Abstract
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
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Metadata
- Authors
- Shultz, A. M., Farha, O. K., Hupp, J. T., & Nguyen, S. T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-09
- Volume
- 131
- Issue
- 12
- Pages
- 4204-4205
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1970188546
- Cited by
- 546
- References
- 0
- FWCI
- 34.36
- Type
- journal article
- Language
- en
- Open access
- closed
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