The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Metal–Organic Framework Membranes Encapsulating Gold Nanoparticles for Direct Plasmonic Photocatalytic Nitrogen Fixation
Abstract
Photocatalytic nitrogen fixation reaction can harvest the solar energy to convert the abundant but inert N 2 into NH 3 . Here, utilizing metal–organic framework (MOF) membranes as the ideal assembly of nanoreactors to disperse and confine gold nanoparticles (AuNPs), we realize the direct plasmonic photocatalytic nitrogen fixation under ambient conditions. Upon visible irradiation, the hot electrons generated on the AuNPs can be directly injected into the N 2 molecules adsorbed on Au surfaces. Such N 2 molecules can be additionally activated by the strong but evanescently localized surface plasmon resonance field, resulting in a supralinear intensity dependence of the ammonia evolution rate with much higher apparent quantum efficiency and lower apparent activation energy under stronger irradiation. Moreover, the gas-permeable Au@MOF membranes, consisting of numerous interconnected nanoreactors, can ensure the dispersity and stability of AuNPs, further facilitate the mass transfer of N 2 molecules and (hydrated) protons, and boost the plasmonic photocatalytic reactions at the designed gas–membrane–solution interface. As a result, an ammonia evolution rate of 18.9 mmol g Au –1 h –1 was achieved under visible light (>400 nm, 100 mW cm –2 ) with an apparent quantum efficiency of 1.54% at 520 nm.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Ullmann's Encyclopedia of Industrial Chemistry
(2012) · Choice Reviews Online · doi:10.5860/choice.50-1224 · Cited by 3,049
Beyond fossil fuel–driven nitrogen transformations
Chen, J. G., Crooks, R. M., Seefeldt, L. C., Bren, K. L., Bullock, R. M., Darensbourg, M. Y., Holland, P. L., Hoffman, B., Janik, M. J., Jones, A. K., et al. (2018) · Science · doi:10.1126/science.aar6611 · Cited by 2,441
Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures
Christopher, P., Xin, H., & Linic, S. (2011) · Nature Chemistry · doi:10.1038/nchem.1032 · Cited by 2,000
Li, H., Shang, J., Ai, Z., & Zhang, L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03105 · Cited by 1,778
A theoretical evaluation of possible transition metal electro-catalysts for N2reduction
Skúlason, E., Bligaard, T., Gudmundsdóttir, S., Studt, F., Rossmeisl, J., Abild-Pedersen, F., Vegge, T., Jónsson, H., & Nørskov, J. K. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp22271f · Cited by 1,609
Guo, C., Ran, J., Vasileff, A., & Qiao, S.-Z. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02220d · Cited by 1,463
Wu, H., Chua, Y. S., Krungleviciute, V., Tyagi, M., Chen, P., Yildirim, T., & Zhou, W. (2013) · Journal of the American Chemical Society · doi:10.1021/ja404514r · Cited by 1,457
Montoya, J. H., Tsai, C., Vojvodic, A., & Nørskov, J. K. (2015) · ChemSusChem · doi:10.1002/cssc.201500322 · Cited by 1,384
Surface-Plasmon-Driven Hot Electron Photochemistry
Zhang, Y., He, S., Guo, W., Hu, Y., Huang, J., Mulcahy, J. R., & Wei, W. D. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00430 · Cited by 1,342
Self-citationPhotolysis of Water and Photoreduction of Nitrogen on Titanium Dioxide
Schrauzer, G. N., & Guth, T. D. (1977) · Journal of the American Chemical Society · doi:10.1021/ja00464a015 · Cited by 1,247
An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
Mubeen, S., Lee, J., Singh, N., Krämer, S., Stucky, G. D., & Moskovits, M. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.18 · Cited by 1,187
Bao, D., Zhang, Q., Meng, F., Zhong, H., Shi, M., Zhang, Y., Yan, J., Jiang, Q., & Zhang, X. (2017) · Advanced Materials · doi:10.1002/adma.201604799 · Cited by 1,164
Self-citationQuantifying hot carrier and thermal contributions in plasmonic photocatalysis
Zhou, L., Swearer, D. F., Zhang, C., Robatjazi, H., Zhao, H., Henderson, L., Dong, L., Christopher, P., Carter, E. A., Nordlander, P., et al. (2018) · Science · doi:10.1126/science.aat6967 · Cited by 1,141
Zhu, D., Zhang, L., Ruther, R. E., & Hamers, R. J. (2013) · Nature Materials · doi:10.1038/nmat3696 · Cited by 1,056
Zhang, N., Jalil, A., Wu, D., Chen, S., Liu, Y., Gao, C., Ye, W., Qi, Z., Ju, H., Wang, C., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b02076 · Cited by 997
Self-citationGreening Ammonia toward the Solar Ammonia Refinery
Wang, L., Xia, M., Wang, H., Huang, K., Qian, C., Maravelias, C. T., & Ozin, G. A. (2018) · Joule · doi:10.1016/j.joule.2018.04.017 · Cited by 995
Direct Photocatalysis by Plasmonic Nanostructures
Kale, M. J., Avanesian, T., & Christopher, P. (2014) · ACS Catalysis · doi:10.1021/cs400993w · Cited by 927
Hirakawa, H., Hashimoto, M., Shiraishi, Y., & Hirai, T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06634 · Cited by 891
Christopher, P., Xin, H., Marimuthu, A., & Linic, S. (2012) · Nature Materials · doi:10.1038/nmat3454 · Cited by 885
Light-driven dinitrogen reduction catalyzed by a CdS:nitrogenase MoFe protein biohybrid
Brown, K. A., Harris, D. F., Wilker, M. B., Rasmussen, A., Khadka, N., Hamby, H., Keable, S., Dukovic, G., Peters, J. W., Seefeldt, L. C., et al. (2016) · Science · doi:10.1126/science.aaf2091 · Cited by 868
Hao, Y.-C., Guo, Y., Chen, L.-W., Shu, M., Wang, X.-Y., Bu, T.-A., Gao, W.-Y., Zhang, N., Su, X., Feng, X., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0241-7 · Cited by 860
Self-citationYao, Y., Zhu, S., Wang, H., Li, H., & Shao, M. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12101 · Cited by 732
Zhao, Y., Zhao, Y., Waterhouse, G. I. N., Zheng, L., Cao, X., Teng, F., Wu, L., Tung, C., O'Hare, D., & Zhang, T. (2017) · Advanced Materials · doi:10.1002/adma.201703828 · Cited by 706
Plasmonic Harvesting of Light Energy for Suzuki Coupling Reactions
Wang, F., Li, C., Chen, H., Jiang, R., Sun, L.-D., Li, Q., Wang, J., Yu, J. C., & Yan, C.-H. (2013) · Journal of the American Chemical Society · doi:10.1021/ja310501y · Cited by 673
Chen, S., Perathoner, S., Ampelli, C., Mebrahtu, C., Su, D., & Centi, G. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201609533 · Cited by 615
Yang, J., Guo, Y., Jiang, R., Qin, F., Zhang, H., Lu, W., Wang, J., & Yu, J. C. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b03537 · Cited by 499
Self-citationEfficient electrocatalytic CO2 reduction on a three-phase interface
Li, J., Chen, G., Zhu, Y., Liang, Z., Pei, A., Wu, C.-L., Wang, H., Lee, H. R., Liu, K., Chu, S., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0108-3 · Cited by 483
Self-citationHeterogenous Catalysis Mediated by Plasmon Heating
Adleman, J. R., Boyd, D. A., Goodwin, D. G., & Psaltis, D. (2009) · Nano Letters · doi:10.1021/nl902711n · Cited by 475
Lazouski, N., Chung, M., Williams, K., Gala, M. L., & Manthiram, K. (2020) · Nature Catalysis · doi:10.1038/s41929-020-0455-8 · Cited by 433
Xue, Z.-H., Zhang, S.-N., Lin, Y.-X., Su, H., Zhai, G.-Y., Han, J.-T., Yu, Q.-Y., Li, X.-H., Antonietti, M., & Chen, J.-S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07963 · Cited by 371
Service, R. F. (2018) · Science · doi:10.1126/science.361.6398.120 · Cited by 311
Boosting Hot Electrons in Hetero-superstructures for Plasmon-Enhanced Catalysis
Guo, J., Zhang, Y., Shi, L., Zhu, Y., Mideksa, M. F., Hou, K., Zhao, W., Wang, D., Zhao, M., Zhang, X., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b08903 · Cited by 310
Self-citationThermodynamic and kinetic analysis of heterogeneous photocatalysis for semiconductor systems
Liu, B., Zhao, X., Terashima, C., Fujishima, A., & Nakata, K. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp55317e · Cited by 296
Tsumori, N., Chen, L., Wang, Q., Zhu, Q.-L., Kitta, M., & Xu, Q. (2018) · Chem · doi:10.1016/j.chempr.2018.03.009 · Cited by 256
Self-citationNitrogenase-mimic iron-containing chalcogels for photochemical reduction of dinitrogen to ammonia
Liu, J., Kelley, M. S., Wu, W., Banerjee, A., Douvalis, A. P., Wu, J., Zhang, Y., Schatz, G. C., & Kanatzidis, M. G. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1605512113 · Cited by 248
Self-citationLiu, H., Meng, X., Dao, T. D., Zhang, H., Li, P., Chang, K., Wang, T., Li, M., Nagao, T., & Ye, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201504933 · Cited by 219
Wen, M., Mori, K., Kuwahara, Y., & Yamashita, H. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00558 · Cited by 208
Mao, C., Li, H., Gu, H., Wang, J., Zou, Y., Qi, G., Xu, J., Deng, F., Shen, W., Li, J., et al. (2019) · Chem · doi:10.1016/j.chempr.2019.07.021 · Cited by 180
Self-citationMartirez, J. M. P., & Carter, E. A. (2017) · Science Advances · doi:10.1126/sciadv.aao4710 · Cited by 102
Excited-State N 2 Dissociation Pathway on Fe-Functionalized Au
Martirez, J. M. P., & Carter, E. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12301 · Cited by 97
Plasmonic Hot-Carrier-Mediated Tunable Photochemical Reactions
Zhang, Y., Nelson, T., Tretiak, S., Guo, H., & Schatz, G. C. (2018) · ACS Nano · doi:10.1021/acsnano.8b03830 · Cited by 97
Self-citationPromoting photocatalytic nitrogen fixation with alkali metal cations and plasmonic nanocrystals
Bu, T.-A., Hao, Y., Gao, W., Su, X., Chen, L., Zhang, N., & Yin, A. (2019) · Nanoscale · doi:10.1039/c9nr02502b · Cited by 75
Self-citationMartirez, J. M. P., & Carter, E. A. (2016) · ACS Nano · doi:10.1021/acsnano.6b00085 · Cited by 53
Cited by
Shangguan, W., Liu, Q., Wang, Y., Sun, N., Liu, Y., Zhao, R., Li, Y., Wang, C., & Zhao, J. (2022) · Nature Communications · doi:10.1038/s41467-022-31474-2 · Cited by 332
Thermo-photo catalysis: a whole greater than the sum of its parts
Fang, S., & Hu, Y. H. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00782c · Cited by 283
Kaur, H., Devi, N., Siwal, S. S., Alsanie, W. F., Thakur, M. K., & Thakur, V. K. (2023) · ACS Omega · doi:10.1021/acsomega.2c07719 · Cited by 273
Jiang, L., He, C.-H., Chen, H.-Y., Xi, C.-Y., Fodjo, E. K., Zhou, Z.-R., Qian, R.-C., Li, D.-W., & Hafez, M. E. (2021) · Analytical Chemistry · doi:10.1021/acs.analchem.1c02233 · Cited by 54
Metadata
- Authors
- Chen, L.-W., Hao, Y.-C., Guo, Y., Zhang, Q., Li, J., Gao, W.-Y., Ren, L., Su, X., Hu, L., Zhang, N., Li, S., Feng, X., Gu, L., Zhang, Y.-W., Yin, A.-X., & Wang, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-04-13
- Volume
- 143
- Issue
- 15
- Pages
- 5727-5736
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3153011445
- Cited by
- 303
- References
- 44
- FWCI
- 9.96
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
