The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Enhancing Mechanical Performance of a Covalent Self-Healing Material by Sacrificial Noncovalent Bonds
Abstract
Polymers that repair themselves after mechanical damage can significantly improve their durability and safety. A major goal in the field of self-healing materials is to combine robust mechanical and efficient healing properties. Here, we show that incorporation of sacrificial bonds into a self-repairable network dramatically improves the overall mechanical properties. Specifically, we use simple secondary amide side chains to create dynamic energy dissipative hydrogen bonds in a covalently cross-linked polymer network, which can self-heal via olefin cross-metathesis. We envision that this straightforward sacrificial bonding strategy can be employed to improve mechanical properties in a variety of self-healing systems.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Autonomic healing of polymer composites
White, S. R., Sottos, N. R., Geubelle, P. H., Moore, J. S., Kessler, M. R., Sriram, S. R., Brown, E. N., & Viswanathan, S. (2001) · Nature · doi:10.1038/35057232 · Cited by 4,575
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Scholl, M., Ding, S., Lee, C. W., & Grubbs, R. H. (1999) · Organic Letters · doi:10.1021/ol990909q · Cited by 3,467
Self-healing and thermoreversible rubber from supramolecular assembly
Cordier, P., Tournilhac, F., Soulié-Ziakovic, C., & Leibler, L. (2008) · Nature · doi:10.1038/nature06669 · Cited by 2,984
Safe and Convenient Procedure for Solvent Purification
Pangborn, A. B., Giardello, M. A., Grubbs, R. H., Rosen, R. K., & Timmers, F. J. (1996) · Organometallics · doi:10.1021/om9503712 · Cited by 2,737
A Thermally Re-mendable Cross-Linked Polymeric Material
Chen, X., Dam, M. A., Ono, K., Mal, A., Shen, H., Nutt, S. R., Sheran, K., & Wudl, F. (2002) · Science · doi:10.1126/science.1065879 · Cited by 2,645
Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity
Sun, T. L., Kurokawa, T., Kuroda, S., Ihsan, A. B., Akasaki, T., Sato, K., Haque, M. A., Nakajima, T., & Gong, J. P. (2013) · Nature Materials · doi:10.1038/nmat3713 · Cited by 2,089
Optically healable supramolecular polymers
Burnworth, M., Tang, L., Kumpfer, J. R., Duncan, A. J., Beyer, F. L., Fiore, G. L., Rowan, S. J., & Weder, C. (2011) · Nature · doi:10.1038/nature09963 · Cited by 1,778
Multi-scale multi-mechanism design of tough hydrogels: building dissipation into stretchy networks
Zhao, X. (2014) · Soft Matter · doi:10.1039/c3sm52272e · Cited by 1,252
Multiphase design of autonomic self-healing thermoplastic elastomers
Chen, Y., Kushner, A. M., Williams, G. A., & Guan, Z. (2012) · Nature Chemistry · doi:10.1038/nchem.1314 · Cited by 1,232
Self-citationMetal-Catalyzed Transesterification for Healing and Assembling of Thermosets
Capelot, M., Montarnal, D., Tournilhac, F., & Leibler, L. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302894k · Cited by 1,198
Self-healing materials: a review
Wool, R. P. (2008) · Soft Matter · doi:10.1039/b711716g · Cited by 1,033
Dynamic urea bond for the design of reversible and self-healing polymers
Ying, H., Zhang, Y., & Cheng, J. (2014) · Nature Communications · doi:10.1038/ncomms4218 · Cited by 988
Burattini, S., Greenland, B. W., Merino, D. H., Weng, W., Seppala, J., Colquhoun, H. M., Hayes, W., Mackay, M. E., Hamley, I. W., & Rowan, S. J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104446r · Cited by 935
Fantner, G. E., Hassenkam, T., Kindt, J. H., Weaver, J. C., Birkedal, H., Pechenik, L., Cutroni, J. A., Cidade, G. A. G., Stucky, G. D., Morse, D. E., et al. (2005) · Nature Materials · doi:10.1038/nmat1428 · Cited by 933
Super tough double network hydrogels and their application as biomaterials
Haque, M. A., Kurokawa, T., & Gong, J. P. (2012) · Polymer · doi:10.1016/j.polymer.2012.03.013 · Cited by 728
Dynamics of reversible networks
Leibler, L., Rubinstein, M., & Colby, R. H. (1991) · Macromolecules · doi:10.1021/ma00016a034 · Cited by 724
Self-Repairing Oxetane-Substituted Chitosan Polyurethane Networks
Ghosh, B., & Urban, M. W. (2009) · Science · doi:10.1126/science.1167391 · Cited by 713
Covalent Cross-Linked Polymer Gels with Reversible Sol−Gel Transition and Self-Healing Properties
Deng, G., Tang, C., Li, F., Jiang, H., & Chen, Y. (2010) · Macromolecules · doi:10.1021/ma9022197 · Cited by 676
The world of smart healable materials
Murphy, E. B., & Wudl, F. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.10.006 · Cited by 670
Zheng, P., & McCarthy, T. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2113257 · Cited by 625
Amamoto, Y., Kamada, J., Otsuka, H., Takahara, A., & Matyjaszewski, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201003888 · Cited by 602
Self-Healing Multiphase Polymers via Dynamic Metal–Ligand Interactions
Mozhdehi, D., Ayala, S., Cromwell, O. R., & Guan, Z. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5097094 · Cited by 584
Self-citationMaking Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568
Self-citationLu, Y.-X., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306287s · Cited by 545
Self-citationLang, K., Davis, L., Wallace, S., Mahesh, M., Cox, D. J., Blackman, M. L., Fox, J. M., & Chin, J. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302832g · Cited by 523
Imato, K., Nishihara, M., Kanehara, T., Amamoto, Y., Takahara, A., & Otsuka, H. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201104069 · Cited by 495
Surface-initiated self-healing of polymers in aqueous media
Ahn, B. K., Lee, D. W., Israelachvili, J. N., & Waite, J. H. (2014) · Nature Materials · doi:10.1038/nmat4037 · Cited by 482
Self‐Healing Polymer Coatings Based on Crosslinked Metallosupramolecular Copolymers
Bode, S., Zedler, L., Schacher, F. H., Dietzek, B., Schmitt, M., Popp, J., Hager, M. D., & Schubert, U. S. (2013) · Advanced Materials · doi:10.1002/adma.201203865 · Cited by 364
Martin, R., Rekondo, A., Ruiz de Luzuriaga, A., Cabañero, G., Grande, H. J., & Odriozola, I. (2014) · Journal of Materials Chemistry A · doi:10.1039/c3ta14927g · Cited by 263
A Rapid and Efficient Self‐Healing Thermo‐Reversible Elastomer Crosslinked with Graphene Oxide
Wang, C., Liu, N., Allen, R., Tok, J. B. ‐., Wu, Y., Zhang, F., Chen, Y., & Bao, Z. (2013) · Advanced Materials · doi:10.1002/adma.201302962 · Cited by 247
Yang, J., Han, C.-R., Zhang, X.-M., Xu, F., & Sun, R.-C. (2014) · Macromolecules · doi:10.1021/ma500729q · Cited by 222
Ring-opening metathesis polymerization of 8-membered cyclic olefins
Martinez, H., Ren, N., Matta, M. E., & Hillmyer, M. A. (2014) · Polymer Chemistry · doi:10.1039/c3py01787g · Cited by 178
Spiropyran as a Mechanochromic Probe in Dual Cross-Linked Elastomers
Zhang, H., Chen, Y., Lin, Y., Fang, X., Xu, Y., Ruan, Y., & Weng, W. (2014) · Macromolecules · doi:10.1021/ma500760p · Cited by 152
Kushner, A. M., Gabuchian, V., Johnson, E. G., & Guan, Z. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0742176 · Cited by 150
Self-citationKean, Z. S., Hawk, J. L., Lin, S., Zhao, X., Sijbesma, R. P., & Craig, S. L. (2014) · Advanced Materials · doi:10.1002/adma.201401570 · Cited by 104
Self-healing linear polymers based on RAFT polymerization
Li, Y., Yuan, Y., Rong, M. Z., & Zhang, M. Q. (2011) · Polymer · doi:10.1016/j.polymer.2011.05.024 · Cited by 68
Cited by
Yang, J. C., Mun, J., Kwon, S. Y., Park, S., Bao, Z., & Park, S. (2019) · Advanced Materials · doi:10.1002/adma.201904765 · Cited by 1,641
Wang, S., & Urban, M. W. (2020) · Nature Reviews Materials · doi:10.1038/s41578-020-0202-4 · Cited by 1,374
Soft Materials by Design: Unconventional Polymer Networks Give Extreme Properties
Zhao, X., Chen, X., Yuk, H., Lin, S., Liu, X., & Parada, G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01088 · Cited by 1,161
Dynamic Covalent Polymer Networks: from Old Chemistry to Modern Day Innovations
Zou, W., Dong, J., Luo, Y., Zhao, Q., & Xie, T. (2017) · Advanced Materials · doi:10.1002/adma.201606100 · Cited by 1,014
Scheutz, G. M., Lessard, J. J., Sims, M. B., & Sumerlin, B. S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07922 · Cited by 934
Metadata
- Authors
- Neal, J. A., Mozhdehi, D., & Guan, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-01
- Volume
- 137
- Issue
- 14
- Pages
- 4846-4850
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2320741036
- Cited by
- 465
- References
- 37
- FWCI
- 22.63
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
