The DOI matches its Crossref record.
Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs
Open accessAbstract
Precise placement of multiple functional groups in a highly ordered metal-organic framework (MOF) platform allows the tailoring of the pore environment, which is required for advanced applications. To realize this, we present a comprehensive study on the linker installation method, in which a stable MOF with coordinatively unsaturated Zr6 clusters was employed and linkers bearing different functional groups were postsynthetically installed. A Zr-MOF with inherent missing linker sites, namely, PCN-700, was initially constructed under kinetic control. Twelve linkers with different substituents were then designed to study their effect on MOF formation kinetics and therefore resulting MOF structures. Guided by the geometrical analysis, linkers with different lengths were installed into a parent PCN-700, giving rise to 11 new MOFs and each bearing up to three different functional groups in predefined positions. Systematic variation of the pore volume and decoration of pore environment were realized by linker installation, which resulted in synergistic effects including an enhancement of H2 adsorption capacities of up to 57%. In addition, a size-selective catalytic system for aerobic alcohol oxidation reaction is built in PCN-700 through linker installation, which shows high activity and tunable size selectivity. Altogether, these results exemplify the capability of the linker installation method in the pore environment engineering of stable MOFs with multiple functional groups, giving an unparalleled level of control.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
Kirchon, A., Feng, L., Drake, H. F., Joseph, E. A., & Zhou, H.-C. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00688a · Cited by 1,448
Self-citationStable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Yuan, S., Qin, J.-S., Lollar, C. T., & Zhou, H.-C. (2018) · ACS Central Science · doi:10.1021/acscentsci.8b00073 · Cited by 561
Self-citationOptimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material
Lin, R.-B., Li, L., Wu, H., Arman, H., Li, B., Lin, R.-G., Zhou, W., & Chen, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03850 · Cited by 559
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Self-citationPore Chemistry of Metal–Organic Frameworks
Ji, Z., Wang, H., Canossa, S., Wuttke, S., & Yaghi, O. M. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000238 · Cited by 459
Feng, L., Yuan, S., Zhang, L.-L., Tan, K., Li, J.-L., Kirchon, A., Liu, L.-M., Zhang, P., Han, Y., Chabal, Y. J., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12916 · Cited by 423
Self-citationWhen defects turn into virtues: The curious case of zirconium-based metal-organic frameworks
Taddei, M. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.04.010 · Cited by 341
Supramolecular fluorescent sensors: An historical overview and update
Guo, C., Sedgwick, A. C., Hirao, T., & Sessler, J. L. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213560 · Cited by 284
Kapelewski, M. T., Runčevski, T., Tarver, J. D., Jiang, H. Z. H., Hurst, K. E., Parilla, P. A., Ayala, A., Gennett, T., FitzGerald, S. A., Brown, C. M., et al. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b03276 · Cited by 283
Dong, Z., Sun, Y., Chu, J., Zhang, X., & Deng, H. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b07392 · Cited by 282
Yuan, S., Qin, J.-S., Xu, H.-Q., Su, J., Rossi, D., Chen, Y., Zhang, L., Lollar, C., Wang, Q., Jiang, H.-L., et al. (2018) · ACS Central Science · doi:10.1021/acscentsci.7b00497 · Cited by 265
Self-citationLithium Extraction by Emerging Metal-Organic Framework-Based Membranes
Hou, J., Zhang, H., Thornton, A. W., Hill, A. J., Wang, H., & Konstas, K. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202105991 · Cited by 248
Metadata
- Authors
- Yuan, S., Chen, Y.-P., Qin, J.-S., Lu, W., Zou, L., Zhang, Q., Wang, X., Sun, X., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-07-11
- Volume
- 138
- Issue
- 28
- Pages
- 8912-8919
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2475039665
- Cited by
- 360
- References
- 0
- FWCI
- 17.78
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
