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A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation
Abstract
A base-resistant porphyrin metal–organic framework (MOF), namely PCN-602 has been constructed with 12-connected [Ni 8 (OH) 4 (H 2 O) 2 Pz 12 ] (Pz = pyrazolate) cluster and a newly designed pyrazolate-based porphyrin ligand, 5,10,15,20-tetrakis(4-(pyrazolate-4-yl)phenyl)porphyrin under the guidance of the reticular synthesis strategy. Besides its robustness in hydroxide solution, PCN-602 also shows excellent stability in aqueous solutions of F –, CO 3 2–, and PO 4 3– ions. Interestingly, the Mn 3+ -porphyrinic PCN-602, as a recyclable MOF catalyst, presents high catalytic activity for the C–H bond halogenation reaction in a basic system, significantly outperforming its homogeneous counterpart. For the first time, a porphyrinic MOF was thus used as an efficient catalyst in a basic solution with coordinating anions, to the best of our knowledge.
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Metadata
- Authors
- Lv, X.-L., Wang, K., Wang, B., Su, J., Zou, X., Xie, Y., Li, J.-R., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-23
- Volume
- 139
- Issue
- 1
- Pages
- 211-217
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2559757410
- Cited by
- 312
- References
- 38
- FWCI
- 12.63
- Type
- journal article
- Language
- en
- Open access
- closed
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