The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Quadruple H-Bonding Cross-Linked Supramolecular Polymeric Materials as Substrates for Stretchable, Antitearing, and Self-Healable Thin Film Electrodes
Open accessAbstract
Herein, we report a de novo chemical design of supramolecular polymer materials (SPMs- 1 – 3 ) by condensation polymerization, consisting of (i) soft polymeric chains (polytetramethylene glycol and tetraethylene glycol) and (ii) strong and reversible quadruple H-bonding cross-linkers (from 0 to 30 mol %). The former contributes to the formation of the soft domain of the SPMs, and the latter furnishes the SPMs with desirable mechanical properties, thereby producing soft, stretchable, yet tough elastomers. The resulting SPM- 2 was observed to be highly stretchable (up to 17 000% strain), tough (fracture energy ∼30 000 J/m 2 ), and self-healing, which are highly desirable properties and are superior to previously reported elastomers and tough hydrogels. Furthermore, a gold, thin film electrode deposited on this SPM substrate retains its conductivity and combines high stretchability (∼400%), fracture/notch insensitivity, self-healing, and good interfacial adhesion with the gold film. Again, these properties are all highly complementary to commonly used polydimethylsiloxane-based thin film metal electrodes. Last, we proceed to demonstrate the practical utility of our fabricated electrode via both in vivo and in vitro measurements of electromyography signals. This fundamental understanding obtained from the investigation of these SPMs will facilitate the progress of intelligent soft materials and flexible electronics.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Highly stretchable and tough hydrogels
Sun, J.-Y., Zhao, X., Illeperuma, W. R. K., Chaudhuri, O., Oh, K. H., Mooney, D. J., Vlassak, J. J., & Suo, Z. (2012) · Nature · doi:10.1038/nature11409 · Cited by 5,481
Functional Supramolecular Polymers
Aida, T., Meijer, E. W., & Stupp, S. I. (2012) · Science · doi:10.1126/science.1205962 · Cited by 3,696
De Greef, T. F. A., Smulders, M. M. J., Wolffs, M., Schenning, A. P. H. J., Sijbesma, R. P., & Meijer, E. W. (2009) · Chemical Reviews · doi:10.1021/cr900181u · Cited by 2,459
Pursuing prosthetic electronic skin
Chortos, A., Liu, J., & Bao, Z. (2016) · Nature Materials · doi:10.1038/nmat4671 · Cited by 2,396
Self-citationReversible Polymers Formed from Self-Complementary Monomers Using Quadruple Hydrogen Bonding
Sijbesma, R. P., Beijer, F. H., Brunsveld, L., Folmer, B. J. B., Hirschberg, J. H. K. K., Lange, R. F. M., Lowe, J. K. L., & Meijer, E. W. (1997) · Science · doi:10.1126/science.278.5343.1601 · Cited by 2,393
Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity
Sun, T. L., Kurokawa, T., Kuroda, S., Ihsan, A. B., Akasaki, T., Sato, K., Haque, M. A., Nakajima, T., & Gong, J. P. (2013) · Nature Materials · doi:10.1038/nmat3713 · Cited by 2,089
The rise of plastic bioelectronics
Someya, T., Bao, Z., & Malliaras, G. G. (2016) · Nature · doi:10.1038/nature21004 · Cited by 1,884
Self-citationUsing the dynamic bond to access macroscopically responsive structurally dynamic polymers
Wojtecki, R. J., Meador, M. A., & Rowan, S. J. (2011) · Nature Materials · doi:10.1038/nmat2891 · Cited by 1,636
Stimuli-responsive supramolecular polymeric materials
Yan, X., Wang, F., Zheng, B., & Huang, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35091b · Cited by 1,631
Self-citationMicro/nanorobots for biomedicine: Delivery, surgery, sensing, and detoxification
Li, J., Esteban-Fernández de Ávila, B., Gao, W., Zhang, L., & Wang, J. (2017) · Science Robotics · doi:10.1126/scirobotics.aam6431 · Cited by 1,565
Self-citationA highly stretchable autonomous self-healing elastomer
Li, C.-H., Wang, C., Keplinger, C., Zuo, J.-L., Jin, L., Sun, Y., Zheng, P., Cao, Y., Lissel, F., Linder, C., et al. (2016) · Nature Chemistry · doi:10.1038/nchem.2492 · Cited by 1,496
Self-citationTee, B. C.-K., Wang, C., Allen, R., & Bao, Z. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.192 · Cited by 1,419
Self-citationSupramolecular Polymers: Historical Development, Preparation, Characterization, and Functions
Yang, L., Tan, X., Wang, Z., & Zhang, X. (2015) · Chemical Reviews · doi:10.1021/cr500633b · Cited by 1,326
Multiphase design of autonomic self-healing thermoplastic elastomers
Chen, Y., Kushner, A. M., Williams, G. A., & Guan, Z. (2012) · Nature Chemistry · doi:10.1038/nchem.1314 · Cited by 1,232
Toughening Elastomers with Sacrificial Bonds and Watching Them Break
Ducrot, E., Chen, Y., Bulters, M., Sijbesma, R. P., & Creton, C. (2014) · Science · doi:10.1126/science.1248494 · Cited by 1,203
Soft Microfluidic Assemblies of Sensors, Circuits, and Radios for the Skin
Xu, S., Zhang, Y., Jia, L., Mathewson, K. E., Jang, K.-I., Kim, J., Fu, H., Huang, X., Chava, P., Wang, R., et al. (2014) · Science · doi:10.1126/science.1250169 · Cited by 1,199
Self-citationTough and Water‐Insensitive Self‐Healing Elastomer for Robust Electronic Skin
Kang, J., Son, D., Wang, G. N., Liu, Y., Lopez, J., Kim, Y., Oh, J. Y., Katsumata, T., Mun, J., Lee, Y., et al. (2018) · Advanced Materials · doi:10.1002/adma.201706846 · Cited by 1,124
Self-citationCai, G., Wang, J., Qian, K., Chen, J., Li, S., & Lee, P. S. (2017) · Advanced Science · doi:10.1002/advs.201600190 · Cited by 921
Superior Toughness and Fast Self‐Healing at Room Temperature Engineered by Transparent Elastomers
Kim, S., Jeon, H., Shin, S., Park, S., Jegal, J., Hwang, S. Y., Oh, D. X., & Park, J. (2018) · Advanced Materials · doi:10.1002/adma.201705145 · Cited by 857
Multifunctional Epidermal Electronics Printed Directly Onto the Skin
Yeo, W., Kim, Y., Lee, J., Ameen, A., Shi, L., Li, M., Wang, S., Ma, R., Jin, S. H., Kang, Z., et al. (2013) · Advanced Materials · doi:10.1002/adma.201204426 · Cited by 828
Self-citationSyringe-injectable electronics
Liu, J., Fu, T.-M., Cheng, Z., Hong, G., Zhou, T., Jin, L., Duvvuri, M., Jiang, Z., Kruskal, P., Xie, C., et al. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.115 · Cited by 687
Liang, J., Li, L., Tong, K., Ren, Z., Hu, W., Niu, X., Chen, Y., & Pei, Q. (2014) · ACS Nano · doi:10.1021/nn405887k · Cited by 673
Stretchable and self-healing polymers and devices for electronic skin
Benight, S. J., Wang, C., Tok, J. B. H., & Bao, Z. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.08.001 · Cited by 617
Self-citationStability and Lifetime of Quadruply Hydrogen Bonded 2-Ureido-4[1 H]-pyrimidinone Dimers
Söntjens, S. H. M., Sijbesma, R. P., van Genderen, M. H. P., & Meijer, E. W. (2000) · Journal of the American Chemical Society · doi:10.1021/ja000435m · Cited by 542
Electronic Muscles and Skins: A Review of Soft Sensors and Actuators
Chen, D., & Pei, Q. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00019 · Cited by 506
Extremely Stretchable and Fast Self‐Healing Hydrogels
Jeon, I., Cui, J., Illeperuma, W. R. K., Aizenberg, J., & Vlassak, J. J. (2016) · Advanced Materials · doi:10.1002/adma.201600480 · Cited by 491
Highly stretchable and transparent nanomesh electrodes made by grain boundary lithography
Guo, C. F., Sun, T., Liu, Q., Suo, Z., & Ren, Z. (2014) · Nature Communications · doi:10.1038/ncomms4121 · Cited by 427
Mechanisms of reversible stretchability of thin metal films on elastomeric substrates
Lacour, S. P., Chan, D., Wagner, S., Li, T., & Suo, Z. (2006) · Applied Physics Letters · doi:10.1063/1.2201874 · Cited by 413
A Mechanically and Electrically Self‐Healing Supercapacitor
Wang, H., Zhu, B., Jiang, W., Yang, Y., Leow, W. R., Wang, H., & Chen, X. (2014) · Advanced Materials · doi:10.1002/adma.201305682 · Cited by 396
Self-citationGreensmith, H. W. (1963) · Journal of Applied Polymer Science · doi:10.1002/app.1963.070070316 · Cited by 346
Thickness‐Gradient Films for High Gauge Factor Stretchable Strain Sensors
Liu, Z., Qi, D., Guo, P., Liu, Y., Zhu, B., Yang, H., Liu, Y., Li, B., Zhang, C., Yu, J., et al. (2015) · Advanced Materials · doi:10.1002/adma.201503288 · Cited by 344
Self-citationAutonomic Restoration of Electrical Conductivity
Blaiszik, B. J., Kramer, S. L. B., Grady, M. E., McIlroy, D. A., Moore, J. S., Sottos, N. R., & White, S. R. (2012) · Advanced Materials · doi:10.1002/adma.201102888 · Cited by 321
A Biomimetic Modular Polymer with Tough and Adaptive Properties
Kushner, A. M., Vossler, J. D., Williams, G. A., & Guan, Z. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9009666 · Cited by 257
Yan, X., Li, S., Pollock, J. B., Cook, T. R., Chen, J., Zhang, Y., Ji, X., Yu, Y., Huang, F., & Stang, P. J. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1307472110 · Cited by 245
Self-citationBiomimetic Supramolecular Polymer Networks Exhibiting both Toughness and Self‐Recovery
Liu, J., Tan, C. S. Y., Yu, Z., Lan, Y., Abell, C., & Scherman, O. A. (2017) · Advanced Materials · doi:10.1002/adma.201604951 · Cited by 227
High‐Adhesion Stretchable Electrodes Based on Nanopile Interlocking
Liu, Z., Wang, X., Qi, D., Xu, C., Yu, J., Liu, Y., Jiang, Y., Liedberg, B., & Chen, X. (2017) · Advanced Materials · doi:10.1002/adma.201603382 · Cited by 225
Self-citationSelf‐Healing, Fully Functional, and Multiparametric Flexible Sensing Platform
Huynh, T., & Haick, H. (2016) · Advanced Materials · doi:10.1002/adma.201504104 · Cited by 210
A Healable, Semitransparent Silver Nanowire‐Polymer Composite Conductor
Gong, C., Liang, J., Hu, W., Niu, X., Ma, S., Hahn, H. T., & Pei, Q. (2013) · Advanced Materials · doi:10.1002/adma.201301069 · Cited by 197
Chen, X. (2017) · Small Methods · doi:10.1002/smtd.201600029 · Cited by 159
Self-citationSuper stretchable hydrogel achieved by non-aggregated spherulites with diameters <5 nm
Sun, G., Li, Z., Liang, R., Weng, L., & Zhang, L. (2016) · Nature Communications · doi:10.1038/ncomms12095 · Cited by 149
Kim, K., Jung, M., Kim, B., Kim, J., Shin, K., Kwon, O., & Jeon, S. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.09.024 · Cited by 142
Qin, B., Zhang, S., Song, Q., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201703572 · Cited by 139
Modular Domain Structure: A Biomimetic Strategy for Advanced Polymeric Materials
Guan, Z., Roland, J. T., Bai, J. Z., Ma, S. X., McIntire, T. M., & Nguyen, M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039127p · Cited by 129
Stretchable and compressible thin films of stiff materials on compliant wavy substrates
Xiao, J., Carlson, A., Liu, Z. J., Huang, Y. Y., Jiang, H., & Rogers, J. A. (2008) · Applied Physics Letters · doi:10.1063/1.2955829 · Cited by 84
Self-citationMicromechanics of macroelectronics
Suo, Z., Vlassak, J. J., & Wagner, S. (2005) · 中国颗粒学报：英文版 · doi:10.1016/s1672-2515(07)60210-3 · Cited by 52
Liu, Z., Yu, M., Lv, J., Li, Y., & Yu, Z. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am502454t · Cited by 50
Self-citationThe effect of the rate of strain on tearing in rubber
Sakulkaew, K., Thomas, A. G., & Busfield, J. J. C. (2010) · Polymer Testing · doi:10.1016/j.polymertesting.2010.11.014 · Cited by 48
Self-Healing Polymer Dielectric for a High Capacitance Gate Insulator
Ko, J., Kim, Y., & Kim, Y. S. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b08220 · Cited by 46
Cited by
Yang, J. C., Mun, J., Kwon, S. Y., Park, S., Bao, Z., & Park, S. (2019) · Advanced Materials · doi:10.1002/adma.201904765 · Cited by 1,641
Self-citationXia, D., Wang, P., Ji, X., Khashab, N. M., Sessler, J. L., & Huang, F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00839 · Cited by 734
Kang, J., Tok, J. B.-H., & Bao, Z. (2019) · Nature Electronics · doi:10.1038/s41928-019-0235-0 · Cited by 706
Self-citationLi, Z., Zhu, Y., Niu, W., Yang, X., Jiang, Z., Lu, Z., Liu, X., & Sun, J. (2021) · Advanced Materials · doi:10.1002/adma.202101498 · Cited by 668
Wang, X., Zhan, S., Lu, Z., Li, J., Yang, X., Qiao, Y., Men, Y., & Sun, J. (2020) · Advanced Materials · doi:10.1002/adma.202005759 · Cited by 575
Self-citation
Metadata
- Authors
- Yan, X., Liu, Z., Zhang, Q., Lopez, J., Wang, H., Wu, H.-C., Niu, S., Yan, H., Wang, S., Lei, T., Li, J., Qi, D., Huang, P., Huang, J., Zhang, Y., Wang, Y., Li, G., Tok, J. B.-H., Chen, X., & Bao, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-03-29
- Volume
- 140
- Issue
- 15
- Pages
- 5280-5289
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2794992598
- Cited by
- 632
- References
- 48
- FWCI
- 33.33
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
