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Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, and Co Salen-Type Complexes
Abstract
Binaphthyldiamino salen-type Zn, Cu, and Co complexes can efficiently catalyze reactions of epoxides with carbon dioxide in the presence of various catalytic amounts of organic bases. The simplest binaphthyldiamino salen-type Zn complex gave the five-membered cyclic carbonate 2 in excellent yield in the presence of triethylamine. A Lewis acid and Lewis base cocatalyzed mechanism is proposed.
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Citations
Cites
Shaikh, A.-A. G., & Sivaram, S. (1996) · Chemical Reviews · doi:10.1021/cr950067i · Cited by 1,381
Cited by
Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593
Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Catalysts for CO 2 /epoxide copolymerisation
Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797
Transformation technologies for CO2 utilisation: Current status, challenges and future prospects
Kamkeng, A. D. N., Wang, M., Hu, J., Du, W., & Qian, F. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.128138 · Cited by 475
Metadata
- Authors
- Shen, Y.-M., Duan, W.-L., & Shi, M.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-01-08
- Volume
- 68
- Issue
- 4
- Pages
- 1559-1562
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W2151016427
- Cited by
- 315
- References
- 1
- FWCI
- 20.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shen, Y.-M., Duan, W.-L., & Shi, M. (2003). Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, and Co Salen-Type Complexes. The Journal of Organic Chemistry. https://doi.org/10.1021/jo020191j
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
