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Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, and Co Salen-Type Complexes
Abstract
Binaphthyldiamino salen-type Zn, Cu, and Co complexes can efficiently catalyze reactions of epoxides with carbon dioxide in the presence of various catalytic amounts of organic bases. The simplest binaphthyldiamino salen-type Zn complex gave the five-membered cyclic carbonate 2 in excellent yield in the presence of triethylamine. A Lewis acid and Lewis base cocatalyzed mechanism is proposed.
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Cites
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The synthesis of organic carbonates from carbon dioxide
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Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2
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Progress in Study of Non-Isocyanate Polyurethane
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Efficient and Greener Synthesis of Propylene Carbonate from Carbon Dioxide and Propylene Oxide
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Metadata
- Authors
- Shen, Y.-M., Duan, W.-L., & Shi, M.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-01-08
- Volume
- 68
- Issue
- 4
- Pages
- 1559-1562
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W2151016427
- Cited by
- 315
- References
- 1
- FWCI
- 20.92
- Type
- journal article
- Language
- en
- Open access
- closed
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