On Nanoparticle Formation by Laser Ablation in Liquids
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Nanoparticle formation by laser ablation in liquids is studied numerically. We investigate such processes as cluster ejection, cluster nucleation, and aggregation. First, laser plume formation, its expansion, and confinement by the liquid are considered. These processes are connected with the formation of two shock waves: one moving inside the solid and the second one propagating in the liquid. If short and ultrashort laser pulses are used, the created plasma plume does not absorb laser radiation. In this case, a larger energy fraction is transferred into the solid during much shorter time, so that the ablation process is explosive. As a result, cluster precursors are ejected directly from the target, and the created plasma is confined to a smaller volume. Shorter laser pulses thus provide more favorable conditions for nanoparticle formation. In addition to the following short plasma expansion stage, a much longer aggregation process occurring in the liquid phase is found to affect the final size distribution.
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In laser ablation of metal targets in air, material removal efficiency increases as the laser pulse width is shorter.
“For example, experiments on the laser ablation of metal targets in air showed that material removal efficiency is increased as the employed laser pulse width is shorter, 116,117 due to the reduced thermal interaction and more efficient use of the energy for material removal process.114,118,119”
From Green nanoparticle synthesis at scale: a perspective on overcoming the limits of pulsed laser ablation in liquids for high-throughput production (2023) · cites this paper as [119]
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- Authors
- Itina, T. E.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Itina, Tatiana E.
- ORCID
- Itina, Tatiana E.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-30
- Volume
- 115
- Issue
- 12
- Pages
- 5044-5048
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2324858554
- Cited by
- 179
- References
- 29
- Citations by year
- 2026: 9 · 2025: 12 · 2024: 13 · 2023: 13 · 2022: 10 · 2021: 11 · 2020: 15 · 2019: 10 · 2018: 12 · 2017: 14 · 2016: 19 · 2015: 17 · 2014: 10 · 2013: 6 · 2012: 7
- FWCI
- 2.64
- Type
- journal article
- Language
- en
- Open access
- green
- ujm.hal.science
- Licence
- other-oa
- Locations
- The Journal of Physical Chemistry C (publishedVersion)
- HAL (submittedVersion, other-oa)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Engineering › Computational Mechanics › Laser Material Processing Techniques
- Physical Sciences › Engineering › Mechanics of Materials › Laser-induced spectroscopy and plasma
- Keywords
- laser ablation in liquid, nanoparticle formation, cluster ejection, cluster nucleation, nanoparticle aggregation, laser-induced plasma plume, shock waves, ultrashort laser pulses, nanoparticle size distribution
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