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Absolute Photoluminescence Quantum Yields of IR-26 Dye, PbS, and PbSe Quantum Dots
Abstract
In this study, we have directly measured the photoluminescence quantum yield (Φ PL ) of IR-26 at a range of concentrations and the Φ PL of PbS and PbSe QDs for a range of sizes. We find that the Φ PL of IR-26 has a weak concentration dependence due to reabsorption, with a Φ PL of 0.048 ± 0.002% for low concentrations, lower than previous reports by a full order of magnitude. We also find that there is a dramatic size dependence for both PbS and PbSe QDs, with the smallest dots exhibiting a Φ PL in excess of 60%, while larger dots fall below 3%. A model, including nonradiative transition between electronic states and energy transfer to ligand vibrations, appears to explain this size dependence. These findings provide both a better characterization of photoluminescence for near-infrared emitters and some insight into how improved QDs can be developed.
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Cited by
Carr, J. A., Franke, D., Caram, J. R., Perkinson, C. F., Saif, M., Askoxylakis, V., Datta, M., Fukumura, D., Jain, R. K., Bawendi, M. G., et al. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1718917115 · Cited by 721
A high quantum yield molecule-protein complex fluorophore for near-infrared II imaging
Antaris, A. L., Chen, H., Diao, S., Ma, Z., Zhang, Z., Zhu, S., Wang, J., Lozano, A. X., Fan, Q., Chew, L., et al. (2017) · Nature Communications · doi:10.1038/ncomms15269 · Cited by 623
Bright quantum dots emitting at ∼1,600 nm in the NIR-IIb window for deep tissue fluorescence imaging
Zhang, M., Yue, J., Cui, R., Ma, Z., Wan, H., Wang, F., Zhu, S., Zhou, Y., Kuang, Y., Zhong, Y., et al. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1806153115 · Cited by 432
Flavylium Polymethine Fluorophores for Near‐ and Shortwave Infrared Imaging
Cosco, E. D., Caram, J. R., Bruns, O. T., Franke, D., Day, R. A., Farr, E. P., Bawendi, M. G., & Sletten, E. M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706974 · Cited by 415
Lei, Z., Sun, C., Pei, P., Wang, S., Li, D., Zhang, X., & Zhang, F. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201904182 · Cited by 362
Metadata
- Authors
- Semonin, O. E., Johnson, J. C., Luther, J. M., Midgett, A. G., Nozik, A. J., & Beard, M. C.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-07-28
- Volume
- 1
- Issue
- 16
- Pages
- 2445-2450
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2068641096
- Cited by
- 310
- References
- 0
- FWCI
- 8.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- Semonin, O. E., Johnson, J. C., Luther, J. M., Midgett, A. G., Nozik, A. J., & Beard, M. C. (2010). Absolute Photoluminescence Quantum Yields of IR-26 Dye, PbS, and PbSe Quantum Dots. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/jz100830r
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