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Silver Nanoparticles Capped by Oleylamine: Formation, Growth, and Self-Organization
Abstract
Nearly monodisperse silver nanoparticles have been prepared in a simple oleylamine-liquid paraffin system. Intensive study has found that the formation process of silver nanoparticles could be divided into three stages: growth, incubation, and Ostwald ripening stages. Ultraviolet-visible spectroscopy, transmission electron microscopy (TEM), and high-resolution TEM have all demonstrated the occurrence of Ostwald ripening, which could result in better control over the size and size distribution of silver nanoparticles. SAXS (small-angle X-ray scattering) results show that the as-obtained silver nanoparticles can self-assemble into ordered arrays. The possible reduction mechanism of silver ions by oleylamine is related to the Ag+-mediated conversion of primary amines to nitriles.
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Metadata
- Authors
- Chen, M., Feng, Y.-G., Wang, X., Li, T.-C., Zhang, J.-Y., & Qian, D.-J.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-04-11
- Volume
- 23
- Issue
- 10
- Pages
- 5296-5304
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1976755207
- Cited by
- 422
- References
- 52
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- closed
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