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Controlled Radical Polymerization of Acrylates Regulated by Visible Light
Open accessAbstract
The controlled radical polymerization of a variety of acrylate monomers is reported using an Ir-catalyzed visible light mediated process leading to well-defined homo-, random, and block copolymers. The polymerizations could be efficiently activated and deactivated using light while maintaining a linear increase in molecular weight with conversion and first order kinetics. The robust nature of the fac -[Ir(ppy) 3 ] catalyst allows carboxylic acids to be directly introduced at the chain ends through functional initiators or along the backbone of random copolymers (controlled process up to 50 mol % acrylic acid incorporation). In contrast to traditional ATRP procedures, low polydispersity block copolymers, poly(acrylate)- b -(acrylate), poly(methacrylate)- b -(acrylate), and poly(acrylate)- b -(methacrylate), could be prepared with no monomer sequence requirements. These results illustrate the increasing generality and utility of light mediated Ir-catalyzed polymerization as a platform for polymer synthesis.
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Citations
Cites
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Cited by
Metal-Free Atom Transfer Radical Polymerization
Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510389m · Cited by 939
Self-citationTay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Pearson, R. M., Lim, C.-H., McCarthy, B. G., Musgrave, C. B., & Miyake, G. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08068 · Cited by 339
Xu, J., Jung, K., & Boyer, C. (2014) · Macromolecules · doi:10.1021/ma500883y · Cited by 304
Yeow, J., Xu, J., & Boyer, C. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00523 · Cited by 266
Metadata
- Authors
- Treat, N. J., Fors, B. P., Kramer, J. W., Christianson, M., Chiu, C.-Y., Read de Alaniz, J., & Hawker, C. J.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-02
- Volume
- 3
- Issue
- 6
- Pages
- 580-584
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2327283322
- Cited by
- 251
- References
- 1
- FWCI
- 19.37
- Type
- journal article
- Language
- en
- Open access
- green
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- Treat, N. J., Fors, B. P., Kramer, J. W., Christianson, M., Chiu, C.-Y., Read de Alaniz, J., & Hawker, C. J. (2014). Controlled Radical Polymerization of Acrylates Regulated by Visible Light. ACS Macro Letters. https://doi.org/10.1021/mz500242a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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