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Growth of Large-Area and Highly Crystalline MoS2 Thin Layers on Insulating Substrates

Open access
Liu, Keng-Ku, Zhang, Wenjing, Lee, Yi-Hsien, Lin, Yu-Chuan, Chang, Mu-Tung, Su, Ching-Yuan, Chang, Chia-Seng, Li, Hai, Shi, Yumeng, Zhang, Hua, Lai, Chao-Sung, Li, Lain-Jong·2012·Nano Letters

Abstract

The two-dimensional layer of molybdenum disulfide (MoS(2)) has recently attracted much interest due to its direct-gap property and potential applications in optoelectronics and energy harvesting. However, the synthetic approach to obtain high-quality and large-area MoS(2) atomic thin layers is still rare. Here we report that the high-temperature annealing of a thermally decomposed ammonium thiomolybdate layer in the presence of sulfur can produce large-area MoS(2) thin layers with superior electrical performance on insulating substrates. Spectroscopic and microscopic results reveal that the synthesized MoS(2) sheets are highly crystalline. The electron mobility of the bottom-gate transistor devices made of the synthesized MoS(2) layer is comparable with those of the micromechanically exfoliated thin sheets from MoS(2) crystals. This synthetic approach is simple, scalable, and applicable to other transition metal dichalcogenides. Meanwhile, the obtained MoS(2) films are transferable to arbitrary substrates, providing great opportunities to make layered composites by stacking various atomically thin layers.

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Cites

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Metadata

Authors
Liu, K.-K., Zhang, W., Lee, Y.-H., Lin, Y.-C., Chang, M.-T., Su, C.-Y., Chang, C.-S., Li, H., Shi, Y., Zhang, H., Lai, C.-S., & Li, L.-J.
Venue
Nano Letters
Published
2012-03-05
Volume
12
Issue
3
Pages
1538-1544
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2120222489
Cited by
1,958
References
2
FWCI
74.43
Type
journal article
Language
en
Open access
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