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A Bicontinuous Double Gyroid Hybrid Solar Cell
Open accessAbstract
We report the first successful application of an ordered bicontinuous gyroid semiconducting network in a hybrid bulk heterojunction solar cell. The freestanding gyroid network is fabricated by electrochemical deposition into the 10 nm wide voided channels of a self-assembled, selectively degradable block copolymer film. The highly ordered pore structure is ideal for uniform infiltration of an organic hole transporting material, and solid-state dye-sensitized solar cells only 400 nm thick exhibit up to 1.7% power conversion efficiency. This patterning technique can be readily extended to other promising heterojunction systems and is a major step toward realizing the full potential of self-assembly in the next generation of device technologies.
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Self-citation
Metadata
- Authors
- Crossland, E. J. W., Kamperman, M., Nedelcu, M., Ducati, C., Wiesner, U., Smilgies, D. M., Toombes, G. E. S., Hillmyer, M. A., Ludwigs, S., Steiner, U., & Snaith, H. J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-11-14
- Volume
- 9
- Issue
- 8
- Pages
- 2807-2812
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2145815074
- Cited by
- 490
- References
- 3
- FWCI
- 16.17
- Type
- journal article
- Language
- en
- Open access
- green
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- Crossland, E. J. W., Kamperman, M., Nedelcu, M., Ducati, C., Wiesner, U., Smilgies, D. M., Toombes, G. E. S., Hillmyer, M. A., Ludwigs, S., Steiner, U., & Snaith, H. J. (2009). A Bicontinuous Double Gyroid Hybrid Solar Cell. Nano Letters. https://doi.org/10.1021/nl803174p
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