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Intervalley scattering by acoustic phonons in two-dimensional MoS2 revealed by double-resonance Raman spectroscopy
Open accessAbstract
Double-resonance Raman scattering is a sensitive probe to study the electron-phonon scattering pathways in crystals. For semiconducting two-dimensional transition-metal dichalcogenides, the double-resonance Raman process involves different valleys and phonons in the Brillouin zone, and it has not yet been fully understood. Here we present a multiple energy excitation Raman study in conjunction with density functional theory calculations that unveil the double-resonance Raman scattering process in monolayer and bulk MoS 2. Results show that the frequency of some Raman features shifts when changing the excitation energy, and first-principle simulations confirm that such bands arise from distinct acoustic phonons, connecting different valley states. The double-resonance Raman process is affected by the indirect-to-direct bandgap transition, and a comparison of results in monolayer and bulk allows the assignment of each Raman feature near the M or K points of the Brillouin zone. Our work highlights the underlying physics of intervalley scattering of electrons by acoustic phonons, which is essential for valley depolarization in MoS 2.
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Semiempirical GGA‐type density functional constructed with a long‐range dispersion correction
Grimme, S. (2006) · Journal of Computational Chemistry · doi:10.1002/jcc.20495 · Cited by 31,038
Atomically Thin MoS 2 : A New Direct-Gap Semiconductor
Mak, K. F., Lee, C., Hone, J., Shan, J., & Heinz, T. F. (2010) · Physical Review Letters · doi:10.1103/physrevlett.105.136805 · Cited by 15,586
Raman spectroscopy in graphene
Malard, L. M., Pimenta, M. A., Dresselhaus, G., & Dresselhaus, M. S. (2009) · Physics Reports · doi:10.1016/j.physrep.2009.02.003 · Cited by 6,059
Self-citationCoupled Spin and Valley Physics in Monolayers ofMoS2and Other Group-VI Dichalcogenides
Xiao, D., Liu, G.-B., Feng, W., Xu, X., & Yao, W. (2012) · Physical Review Letters · doi:10.1103/physrevlett.108.196802 · Cited by 5,152
Anomalous Lattice Vibrations of Single- and Few-Layer MoS2
Lee, C., Yan, H., Brus, L. E., Heinz, T. F., Hone, J., & Ryu, S. (2010) · ACS Nano · doi:10.1021/nn1003937 · Cited by 4,859
Studying disorder in graphite-based systems by Raman spectroscopy
Pimenta, M. A., Dresselhaus, G., Dresselhaus, M. S., Cançado, L. G., Jorio, A., & Saito, R. (2007) · Phys. Chem. Chem. Phys. · doi:10.1039/b613962k · Cited by 4,623
Self-citationControl of valley polarization in monolayer MoS2 by optical helicity
Mak, K. F., He, K., Shan, J., & Heinz, T. F. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.96 · Cited by 4,034
Valley polarization in MoS2 monolayers by optical pumping
Zeng, H., Dai, J., Yao, W., Xiao, D., & Cui, X. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.95 · Cited by 3,693
Optical Spectrum ofMoS2: Many-Body Effects and Diversity of Exciton States
Qiu, D. Y., da Jornada, F. H., & Louie, S. G. (2013) · Physical Review Letters · doi:10.1103/physrevlett.111.216805 · Cited by 1,614
Identification of individual and few layers of WS2 using Raman Spectroscopy
Berkdemir, A., Gutiérrez, H. R., Botello-Méndez, A. R., Perea-López, N., Elías, A. L., Chia, C.-I., Wang, B., Crespi, V. H., López-Urías, F., Charlier, J.-C., et al. (2013) · Scientific Reports · doi:10.1038/srep01755 · Cited by 1,599
Self-citationLarge excitonic effects in monolayers of molybdenum and tungsten dichalcogenides
Ramasubramaniam, A. (2012) · Physical Review B · doi:10.1103/physrevb.86.115409 · Cited by 1,566
Phonons in single-layer and few-layer MoS2and WS2
Molina-Sánchez, A., & Wirtz, L. (2011) · Physical Review B · doi:10.1103/physrevb.84.155413 · Cited by 1,443
Quasiparticle band structure calculation of monolayer, bilayer, and bulk MoS2
Cheiwchanchamnangij, T., & Lambrecht, W. R. L. (2012) · Physical Review B · doi:10.1103/physrevb.85.205302 · Cited by 1,351
Phonon-limited mobility inn-type single-layer MoS2from first principles
Kaasbjerg, K., Thygesen, K. S., & Jacobsen, K. W. (2012) · Physical Review B · doi:10.1103/physrevb.85.115317 · Cited by 1,295
Quasiparticle band structures and optical properties of strained monolayer MoS2and WS2
Shi, H., Pan, H., Zhang, Y.-W., & Yakobson, B. I. (2013) · Physical Review B · doi:10.1103/physrevb.87.155304 · Cited by 911
Effect of disorder on Raman scattering of single-layerMoS2
Mignuzzi, S., Pollard, A. J., Bonini, N., Brennan, B., Gilmore, I. S., Pimenta, M. A., Richards, D., & Roy, D. (2015) · Physical Review B · doi:10.1103/physrevb.91.195411 · Cited by 784
Self-citationExcitonic Effects on the Optical Response of Graphene and Bilayer Graphene
Yang, L., Deslippe, J., Park, C.-H., Cohen, M. L., & Louie, S. G. (2009) · Physical Review Letters · doi:10.1103/physrevlett.103.186802 · Cited by 702
Venezuela, P. P. D. M., Lazzeri, M., & Mauri, F. (2011) · Physical Review B · doi:10.1103/physrevb.84.035433 · Cited by 622
Raman and resonance Raman investigation ofMoS2nanoparticles
Frey, G. L., Tenne, R., Matthews, M. J., Dresselhaus, M. S., & Dresselhaus, G. (1999) · Physical Review B · doi:10.1103/physrevb.60.2883 · Cited by 547
Layer‐dependent resonant Raman scattering of a few layer MoS2
Chakraborty, B., Matte, H. S. S. R., Sood, A. K., & Rao, C. N. R. (2013) · Journal of Raman Spectroscopy · doi:10.1002/jrs.4147 · Cited by 508
Intrinsic electrical transport properties of monolayer silicene and MoS2from first principles
Li, X., Mullen, J. T., Jin, Z., Borysenko, K. M., Buongiorno Nardelli, M., & Kim, K. W. (2013) · Physical Review B · doi:10.1103/physrevb.87.115418 · Cited by 462
Intrinsic transport properties of electrons and holes in monolayer transition-metal dichalcogenides
Jin, Z., Li, X., Mullen, J. T., & Kim, K. W. (2014) · Physical Review B · doi:10.1103/physrevb.90.045422 · Cited by 453
Monolayer MoS2: Trigonal warping, theΓvalley, and spin-orbit coupling effects
Kormányos, A., Zólyomi, V., Drummond, N. D., Rakyta, P., Burkard, G., & Fal'ko, V. I. (2013) · Physical Review B · doi:10.1103/physrevb.88.045416 · Cited by 442
Lattice Mode Degeneracy in MoS2and Other Layer Compounds
Verble, J. L., & Wieting, T. J. (1970) · Physical Review Letters · doi:10.1103/physrevlett.25.362 · Cited by 387
Exciton band structure of monolayerMoS2
Wu, F., Qu, F., & MacDonald, A. H. (2015) · Physical Review B · doi:10.1103/physrevb.91.075310 · Cited by 333
Maultzsch, J., Reich, S., & Thomsen, C. (2004) · Physical Review B · doi:10.1103/physrevb.70.155403 · Cited by 291
Second order Raman spectrum of MoS2
Chen, J. M., & Wang, C. S. (1974) · Solid State Communications · doi:10.1016/0038-1098(74)90150-1 · Cited by 230
Group theory analysis of phonons in two-dimensional transition metal dichalcogenides
Ribeiro-Soares, J., Almeida, R. M., Barros, E. B., Araujo, P. T., Dresselhaus, M. S., Cançado, L. G., & Jorio, A. (2014) · Physical Review B · doi:10.1103/physrevb.90.115438 · Cited by 227
Carvalho, B. R., Malard, L. M., Alves, J. M., Fantini, C., & Pimenta, M. A. (2015) · Physical Review Letters · doi:10.1103/physrevlett.114.136403 · Cited by 225
Self-citationComparative Study of Raman Spectroscopy in Graphene and MoS2-type Transition Metal Dichalcogenides
Pimenta, M. A., del Corro, E., Carvalho, B. R., Fantini, C., & Malard, L. M. (2015) · Accounts of Chemical Research · doi:10.1021/ar500280m · Cited by 196
Self-citationStokes and anti-Stokes double resonance Raman scattering in two-dimensional graphite
Cançado, L. G., Pimenta, M. A., Saito, R., Jorio, A., Ladeira, L. O., Grueneis, A., Souza-Filho, A. G., Dresselhaus, G., & Dresselhaus, M. S. (2002) · Physical Review B · doi:10.1103/physrevb.66.035415 · Cited by 172
Self-citationAnomalous excitonic resonance Raman effects in few-layered MoS 2
Lee, J., Park, J., Son, Y., & Cheong, H. (2015) · Nanoscale · doi:10.1039/c4nr05785f · Cited by 148
Optical polarization and intervalley scattering in single layers of MoS2 and MoSe2
Kioseoglou, G., Hanbicki, A. T., Currie, M., Friedman, A. L., & Jonker, B. T. (2016) · Scientific Reports · doi:10.1038/srep25041 · Cited by 133
A comprehensive multiphonon spectral analysis in MoS 2
Livneh, T., & Spanier, J. E. (2015) · 2D Materials · doi:10.1088/2053-1583/2/3/035003 · Cited by 104
Anomalous lattice vibrations of monolayer MoS 2 probed by ultraviolet Raman scattering
Liu, H., Guo, H., Yang, T. K., Zhi-dong, Z., Kumamoto, Y., Shen, C.-C., Hsu, Y., Li, L., Saito, R., & Kawata, S. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp01347j · Cited by 51
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Recent Progress on Two-Dimensional Materials
Chang, C., Chen, W., Chen, Y., Chen, Y., Chen, Y., Ding, F., Fan, C., Jin Fan, H., Fan, Z., Gong, C., et al. (2021) · Acta Physico Chimica Sinica · doi:10.3866/pku.whxb202108017 · Cited by 472
Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS3
Kim, K., Lim, S. Y., Lee, J.-U., Lee, S., Kim, T. Y., Park, K., Jeon, G. S., Park, C.-H., Park, J.-G., & Cheong, H. (2019) · Nature Communications · doi:10.1038/s41467-018-08284-6 · Cited by 452
Zhu, H., Yi, J., Li, M.-Y., Xiao, J., Zhang, L., Yang, C.-W., Kaindl, R. A., Li, L.-J., Wang, Y., & Zhang, X. (2018) · Science · doi:10.1126/science.aar2711 · Cited by 429
Self-citationObservation of ultralong valley lifetime in WSe 2 /MoS 2 heterostructures
Kim, J., Jin, C., Chen, B., Cai, H., Zhao, T., Lee, P., Kahn, S., Watanabe, K., Taniguchi, T., Tongay, S., et al. (2017) · Science Advances · doi:10.1126/sciadv.1700518 · Cited by 304
Metadata
- Authors
- Carvalho, B. R., Wang, Y., Mignuzzi, S., Roy, D., Terrones, M., Fantini, C., Crespi, V. H., Malard, L. M., & Pimenta, M. A.
- Venue
- Nature Communications
- Published
- 2017-03-09
- Volume
- 8
- Issue
- 1
- Pages
- 14670-14670
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2594733919
- Cited by
- 283
- References
- 40
- FWCI
- 12.65
- Type
- journal article
- Language
- en
- Open access
- gold
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