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High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus
Open accessAbstract
Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we present a detailed theoretical investigation of the atomic and electronic structure of few-layer black phosphorus (BP) to predict its electrical and optical properties. This system has a direct bandgap, tunable from 1.51 eV for a monolayer to 0.59 eV for a five-layer sample. We predict that the mobilities are hole-dominated, rather high and highly anisotropic. The monolayer is exceptional in having an extremely high hole mobility (of order 10,000 cm2 V−1 s−1) and anomalous elastic properties which reverse the anisotropy. Light absorption spectra indicate linear dichroism between perpendicular in-plane directions, which allows optical determination of the crystalline orientation and optical activation of the anisotropic transport properties. These results make few-layer BP a promising candidate for future electronics. Two-dimensional (2D) materials with a large electronic bandgap in addition to high carrier mobility are required for future nanoelectronics. Here, the authors present a theoretical investigation of black phosphorous, a new category of 2D semiconductor with high potential for nanoelectronic applications.
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Metadata
- Authors
- Qiao, J., Kong, X., Hu, Z.-X., Yang, F., & Ji, W.
- Venue
- Nature Communications
- Published
- 2014-07-21
- Volume
- 5
- Issue
- 1
- Pages
- 4475-4475
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2029281675
- Cited by
- 4,442
- References
- 50
- FWCI
- 162.46
- Type
- journal article
- Language
- en
- Open access
- hybrid
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