Effects of Anion Identity and Concentration on Electrochemical Reduction of CO 2

CRC Handbook of Chemistry and Physics

(2014) · doi:10.1201/b17118 · Cited by 57,706 · see citing works

Opportunities and challenges for a sustainable energy future

Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550 · see citing works

Powering the planet: Chemical challenges in solar energy utilization

Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,316 · see citing works

Trends in the exchange current for hydrogen evolution

Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121 · see citing works

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels

Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784 · see citing works

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160 · see citing works

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media

Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140 · see citing works

Electrochemical CO2 Reduction on Metal Electrodes

Hori, Y. (2008) · Springer eBooks · doi:10.1007/978-0-387-49489-0_3 · Cited by 1,904 · see citing works

New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism

Durst, J., Siebel, A., Simon, C., Hasché, F., Herranz, J. S., & Gasteiger, H. A. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00440j · Cited by 1,673 · see citing works

Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles

Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661 · see citing works

Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces

Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649 · see citing works

Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution

Hori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,644 · see citing works

Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption

Strmcnik, D., Uchimura, M., Wang, C., Subbaraman, R., Danilovic, N., van der Vliet, D., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M. (2013) · Nature Chemistry · doi:10.1038/nchem.1574 · Cited by 1,426 · see citing works

Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes

Ledezma‐Yanez, I., Wallace, W. D. Z., Pascual, P. S., Climent, V., Feliu, J. M., & Koper, M. T. M. (2017) · Nature Energy · doi:10.1038/nenergy.2017.31 · Cited by 1,307 · see citing works

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide

Resasco, J., Chen, L. D., Clark, E. L., Tsai, C., Hahn, C., Jaramillo, T. F., Chan, K., & Bell, A. T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06765 · Cited by 1,199 · see citing works

Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy

Sheng, W., Zhuang, Z., Gao, M., Zheng, J., Chen, J. G., & Yan, Y. (2015) · Nature Communications · doi:10.1038/ncomms6848 · Cited by 1,136 · see citing works

Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction

Montoya, J. H., Shi, C., Chan, K., & Nørskov, J. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00722 · Cited by 861 · see citing works

Direct Observation on Reaction Intermediates and the Role of Bicarbonate Anions in CO 2 Electrochemical Reduction Reaction on Cu Surfaces

Zhu, S., Jiang, B., Cai, W., & Shao, M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10462 · Cited by 857 · see citing works

Electrochemical Reduction of CO at a Copper Electrode

Hori, Y., Takahashi, R., Yoshinami, Y., & Murata, A. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp970284i · Cited by 818 · see citing works

Understanding trends in electrochemical carbon dioxide reduction rates

Liu, X., Xiao, J., Peng, H., Hong, X., Chan, K., & Nørskov, J. K. (2017) · Nature Communications · doi:10.1038/ncomms15438 · Cited by 805 · see citing works

The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold

Dunwell, M., Lu, Q., Heyes, J., Rosen, J., Chen, J. G., Yan, Y. S., Jiao, F., & Xu, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13287 · Cited by 706 · see citing works

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO ₂ : New Theoretical Insights from an Improved Electrochemical Model

Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702 · see citing works

Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K

Cheng, T., Xiao, H. Y., & Goddard, W. A. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1612106114 · Cited by 675 · see citing works

Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions

Gupta, N., Gattrell, M., & MacDougall, B. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-9058-y · Cited by 558 · see citing works

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH

Varela, A. S., Kroschel, M., Reier, T., & Strasser, P. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.06.009 · Cited by 542 · see citing works

The Mechanism of the Cathodic Hydrogen Evolution Reaction

Bockris, J. O., & Potter, E. C. (1952) · Journal of The Electrochemical Society · doi:10.1149/1.2779692 · Cited by 525 · see citing works

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO ₂ Electroreduction by Process Conditions

Kas, R., Kortlever, R., Yılmaz, H., Koper, M. T. M., & Mul, G. (2015) · ChemElectroChem · doi:10.1002/celc.201402373 · Cited by 464 · see citing works

Reaction Mechanisms for the Electrochemical Reduction of CO₂ to CO and Formate on the Cu(100) Surface at 298 K from Quantum Mechanics Free Energy Calculations with Explicit Water

Cheng, T., Xiao, H., & Goddard, W. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08534 · Cited by 453 · see citing works

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide

Singh, M. R., Clark, E. L., & Bell, A. T. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03283k · Cited by 416 · see citing works

Inhibited proton transfer enhances Au-catalyzed CO 2 -to-fuels selectivity

Wuttig, A., Yaguchi, M., Motobayashi, K., Osawa, M., & Surendranath, Y. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1602984113 · Cited by 416 · see citing works

Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons

Hahn, C., Hatsukade, T., Kim, Y.-G., Vailionis, A., Baricuatro, J. H., Higgins, D. C., Nitopi, S. A., Soriaga, M. P., & Jaramillo, T. F. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1618935114 · Cited by 410 · see citing works

Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO2 Reduction

Lum, Y., Yue, B., Lobaccaro, P., Bell, A. T., & Ager, J. W. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b03673 · Cited by 347 · see citing works

The Evolution of the Polycrystalline Copper Surface, First to Cu(111) and Then to Cu(100), at a Fixed CO2RR Potential: A Study by Operando EC-STM

Kim, Y.-G., Baricuatro, J. H., Javier, A. C., Gregoire, J. M., & Soriaga, M. P. (2014) · Langmuir · doi:10.1021/la504445g · Cited by 323 · see citing works

Carbon dioxide equilibria and their applications

Landrum, J. T. (1983) · Organic Geochemistry · doi:10.1016/0146-6380(83)90006-2 · Cited by 318 · see citing works

Bicarbonate Is Not a General Acid in Au-Catalyzed CO2 Electroreduction

Wuttig, A., Yoon, Y., Ryu, J., & Surendranath, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b08345 · Cited by 268 · see citing works

Determination of the rate constants for the carbon dioxide to bicarbonate inter-conversion in pH-buffered seawater systems

Schulz, K. G., Riebesell, U., Rost, B., Thoms, S., & Zeebe, R. E. (2006) · Marine Chemistry · doi:10.1016/j.marchem.2005.11.001 · Cited by 195 · see citing works

Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO 2 reduction electrocatalysts

Lobaccaro, P., Singh, M. R., Clark, E. L., Kwon, Y., Bell, A. T., & Ager, J. W. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp05287h · Cited by 170 · see citing works

Potential of zero charge of monocrystalline copper electrodes in perchlorate solutions

Łukomska, A., & Sobkowski, J. (2004) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2003.11.063 · Cited by 156 · see citing works

Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution

Hori, Y., & Suzuki, S. (1982) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.55.660 · Cited by 140 · see citing works

Modeling CO2 reduction on Pt(111)

Shi, C., O’Grady, C. P., Peterson, A. A., Hansen, H. A., & Nørskov, J. K. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp50645b · Cited by 92 · see citing works

Thermodynamic Studies of Anion Adsorption at Stepped Platinum(hkl) Electrode Surfaces in Sulfuric Acid Solutions

Mostany, J. L., Herrero, E., Feliu, J. M., & Lipkowski, J. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp026561p · Cited by 69 · see citing works

Epitaxial growth of Cu on Si by magnetron sputtering

Jiang, H., Klemmer, T. J., Barnard, J. A., & Payzant, E. A. (1998) · Journal of Vacuum Science & Technology A Vacuum Surfaces and Films · doi:10.1116/1.581489 · Cited by 68 · see citing works

Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte

Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223 · see citing works

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747 · see citing works

Electrochemical CO ₂ Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works

Advances and Challenges for the Electrochemical Reduction of CO 2 to CO: From Fundamentals to Industrialization

Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101818 · Cited by 1,027 · see citing works

Understanding cation effects in electrochemical CO 2 reduction

Ringe, S., Clark, E. L., Resasco, J., Walton, A., Seger, B. J., Bell, A. T., & Chan, K. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01341e · Cited by 854 · see citing works

Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst

Morales‐Guio, C. G., Cave, E. R., Nitopi, S. A., Feaster, J. T., Wang, L., Kuhl, K. P., Jackson, A., Johnson, N. C., Abram, D. N., Hatsukade, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0139-9 · Cited by 776 · see citing works

Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques

Handoko, A. D., Wei, F., Jenndy, Yeo, B. S., & Seh, Z. W. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0182-6 · Cited by 739 · see citing works

Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction

Wagner, A., Sahm, C. D., & Reisner, E. (2020) · Nature Catalysis · doi:10.1038/s41929-020-00512-x · Cited by 732 · see citing works

Competition between CO2 Reduction and Hydrogen Evolution on a Gold Electrode under Well-Defined Mass Transport Conditions

Goyal, A., Marcandalli, G., Mints, V. A., & Koper, M. T. M. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b10061 · Cited by 647 · see citing works

Gas-Diffusion Electrodes for Carbon Dioxide Reduction: A New Paradigm

Higgins, D. C., Hahn, C., Xiang, C., Jaramillo, T. F., & Weber, A. Z. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b02035 · Cited by 609 · see citing works

A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction

Lv, J., Jouny, M., Luc, W., Zhu, W., Zhu, J., & Jiao, F. (2018) · Advanced Materials · doi:10.1002/adma.201803111 · Cited by 499 · see citing works

Electrolyte Effects on CO 2 Electrochemical Reduction to CO

Marcandalli, G., Monteiro, M. C. O., Goyal, A., & Koper, M. T. M. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.2c00080 · Cited by 492 · see citing works

Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials

Garg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 482 · see citing works

Catalyst–electrolyte interface chemistry for electrochemical CO 2 reduction

Jin, Y., Lee, C. W., Lee, S. Y., Na, J., Lee, U., & Hwang, Y. J. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00030b · Cited by 472 · see citing works

Electrochemical reduction of carbon dioxide to multicarbon (C 2+ ) products: challenges and perspectives

Chang, B., Pang, H., Raziq, F., Wang, S., Huang, K., Ye, J., & Zhang, H. (2023) · Energy & Environmental Science · doi:10.1039/d3ee00964e · Cited by 471 · see citing works

Solvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO2

König, M., Vaes, J., Klemm, E., & Pant, D. (2019) · iScience · doi:10.1016/j.isci.2019.07.014 · Cited by 429 · see citing works

Standards and Protocols for Data Acquisition and Reporting for Studies of the Electrochemical Reduction of Carbon Dioxide

Clark, E. L., Resasco, J., Landers, A. T., Lin, J. C., Chung, L.-T., Walton, A., Hahn, C., Jaramillo, T. F., & Bell, A. T. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01340 · Cited by 355 · see citing works

Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction

Deng, B., Huang, M. Y., Zhao, X., Mou, S., & Dong, F. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03501 · Cited by 331 · see citing works

Evidence for product-specific active sites on oxide-derived Cu catalysts for electrochemical CO2 reduction

Lum, Y., & Ager, J. W. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0201-7 · Cited by 322 · see citing works

Effects of Surface Roughness on the Electrochemical Reduction of CO 2 over Cu

Jiang, K. P., Huang, Y., Zeng, G., Toma, F. M., Goddard, W. A., & Bell, A. T. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00482 · Cited by 313 · see citing works

Recent Progresses in Electrochemical Carbon Dioxide Reduction on Copper‐Based Catalysts toward Multicarbon Products

Yu, J., Wang, J., Ma, Y., Zhou, J., Wang, Y., Lu, P., Yin, J., Ye, R., Zhu, Z., & Fan, Z. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202102151 · Cited by 311 · see citing works

In Situ Infrared Spectroscopy Reveals Persistent Alkalinity near Electrode Surfaces during CO2 Electroreduction

Yang, K., Kaş, R., & Smith, W. A. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07000 · Cited by 290 · see citing works

pH Effects on Hydrogen Evolution and Oxidation over Pt(111): Insights from First-Principles

Schlexer, P., Singh, A. R., & Chan, K. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00268 · Cited by 274 · see citing works

Advances and Challenges for the Electrochemical Reduction of CO 2 to CO: From Fundamentals to Industrialization

Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie · doi:10.1002/ange.202101818 · Cited by 268 · see citing works

Direct Observation of the Local Reaction Environment during the Electrochemical Reduction of CO 2

Clark, E. L., & Bell, A. T. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04058 · Cited by 257 · see citing works

Electrochemical CO Reduction Builds Solvent Water into Oxygenate Products

Lum, Y., Cheng, T., Goddard, W. A., & Ager, J. W. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b03986 · Cited by 251 · see citing works

Electrolyte Effects on the Faradaic Efficiency of CO 2 Reduction to CO on a Gold Electrode

Marcandalli, G., Goyal, A., & Koper, M. T. M. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c00272 · Cited by 220 · see citing works

Understanding Cation Effects on the Hydrogen Evolution Reaction

Bender, J. T., Petersen, A. S., Østergaard, F. C., Wood, M. A., Heffernan, S. M. J., Milliron, D. J., Rossmeisl, J., & Resasco, J. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.2c02500 · Cited by 216 · see citing works

Selective and High Current CO2 Electro-Reduction to Multicarbon Products in Near-Neutral KCl Electrolytes

Zhang, X., Li, J., Li, Y., Jung, Y., Kuang, Y., Zhu, G., Liang, Y., & Dai, H. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c13427 · Cited by 213 · see citing works

Pulse check: Potential opportunities in pulsed electrochemical CO2 reduction

Casebolt, R., Levine, K., Suntivich, J., & Hanrath, T. (2021) · Joule · doi:10.1016/j.joule.2021.05.014 · Cited by 210 · see citing works

Engineering Catalyst–Electrolyte Microenvironments to Optimize the Activity and Selectivity for the Electrochemical Reduction of CO 2 on Cu and Ag

Bui, J. C., Kim, C., King, A. J., Romiluyi, O., Kusoglu, A., Weber, A. Z., & Bell, A. T. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.1c00650 · Cited by 209 · see citing works

How pH affects electrochemical processes

Govindarajan, N., Xu, A., & Chan, K. (2022) · Science · doi:10.1126/science.abj2421 · Cited by 206 · see citing works

Electrokinetic and in situ spectroscopic investigations of CO electrochemical reduction on copper

Li, J., Chang, X., Zhang, H., Malkani, A. S., Cheng, M., Xu, B., & Lu, Q. (2021) · Nature Communications · doi:10.1038/s41467-021-23582-2 · Cited by 205 · see citing works

In operando investigations of oscillatory water and carbonate effects in MEA-based CO2 electrolysis devices

Moss, A. B., Garg, S., Mirolo, M., Rodriguez, C. A. G., Ilvonen, R., Chorkendorff, I., Drnec, J., & Seger, B. J. (2023) · Joule · doi:10.1016/j.joule.2023.01.013 · Cited by 205 · see citing works

Electrocatalytic CO2 Reduction to Fuels: Progress and Opportunities

Resasco, J., & Bell, A. T. (2020) · Trends in Chemistry · doi:10.1016/j.trechm.2020.06.007 · Cited by 202 · see citing works

Establishing new scaling relations on two-dimensional MXenes for CO 2 electroreduction

Handoko, A. D., Khoo, K. H., Tan, T. L., Jin, H., & Seh, Z. W. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06567e · Cited by 197 · see citing works

Electric Double Layer Effects in Electrocatalysis: Insights from Ab Initio Simulation and Hierarchical Continuum Modeling

Li, P., Jiao, Y., Huang, J., & Chen, S. (2023) · JACS Au · doi:10.1021/jacsau.3c00410 · Cited by 203 · see citing works

Role of a Hydroxide Layer on Cu Electrodes in Electrochemical CO2 Reduction

Iijima, G., Inomata, T., Yamaguchi, H., Ito, M., & Masuda, H. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00896 · Cited by 197 · see citing works

Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts

Tufa, R. A., Chanda, D., Ma, M., Aili, D., Demissie, T. B., Vaes, J., Li, Q., Liu, S., & Pant, D. (2020) · Applied Energy · doi:10.1016/j.apenergy.2020.115557 · Cited by 191 · see citing works

Using pH Dependence to Understand Mechanisms in Electrochemical CO Reduction

Kastlunger, G., Wang, L., Govindarajan, N., Heenen, H. H., Ringe, S., Jaramillo, T. F., Hahn, C., & Chan, K. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c05520 · Cited by 172 · see citing works

Effects of Electrolyte Anions on the Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper (100) and (111) Surfaces

Huang, Y., Ong, C. W., & Yeo, B. S. (2018) · ChemSusChem · doi:10.1002/cssc.201801078 · Cited by 172 · see citing works

Theories for Electrolyte Effects in CO2 Electroreduction

Xu, A., Govindarajan, N., Kastlunger, G., Vijay, S., & Chan, K. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.1c00679 · Cited by 160 · see citing works

Continuum Modeling of Porous Electrodes for Electrochemical Synthesis

Bui, J. C., Lees, E. W., Pant, L. M., Zenyuk, I. V., Bell, A. T., & Weber, A. Z. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00901 · Cited by 152 · see citing works

Morphology Manipulation of Copper Nanocrystals and Product Selectivity in the Electrocatalytic Reduction of Carbon Dioxide

Suen, N., Kong, Z.-R., Hsu, C., Chen, H., Tung, C., Lu, Y., Dong, C., Shen, C., Chung, J., & Chen, H. M. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00790 · Cited by 148 · see citing works

An overview of flow cell architecture design and optimization for electrochemical CO 2 reduction

Ma, D., Jin, T., Xie, K., & Huang, H. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta06101a · Cited by 144 · see citing works

System Design Rules for Intensifying the Electrochemical Reduction of CO 2 to CO on Ag Nanoparticles

Bhargava, S. S., Proietto, F., Azmoodeh, D., Cofell, E. R., Henckel, D. A., Verma, S., Brooks, C. J., Gewirth, A. A., & Kenis, P. J. A. (2020) · ChemElectroChem · doi:10.1002/celc.202000089 · Cited by 142 · see citing works

Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction

Zhu, C., Zhang, Z., Zhong, L., Hsu, C., Xu, X., Li, Y., Zhao, S., Chen, S., Yu, J. J., Chen, S., et al. (2020) · Chem · doi:10.1016/j.chempr.2020.10.018 · Cited by 140 · see citing works

Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Li, J., Abbas, S. U., Wang, H., Zhang, Z., & Hu, W. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00738-9 · Cited by 140 · see citing works

Interplay of Homogeneous Reactions, Mass Transport, and Kinetics in Determining Selectivity of the Reduction of CO 2 on Gold Electrodes

Zhang, B. A., Özel, T., Elias, J. S., Costentin, C., & Nocera, D. G. (2019) · ACS Central Science · doi:10.1021/acscentsci.9b00302 · Cited by 135 · see citing works

Understanding Multi-Ion Transport Mechanisms in Bipolar Membranes

Bui, J. C., Digdaya, I. A., Xiang, C., Bell, A. T., & Weber, A. Z. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c12686 · Cited by 138 · see citing works

Electrochemical CO 2 reduction on nanostructured metal electrodes: fact or defect?

Kaş, R., Yang, K., Bohra, D., Kortlever, R., Burdyny, T., & Smith, W. A. (2020) · Chemical Science · doi:10.1039/c9sc05375a · Cited by 133 · see citing works

Improving the intrinsic activity of electrocatalysts for sustainable energy conversion: where are we and where can we go?

Govindarajan, N., Kastlunger, G., Heenen, H. H., & Chan, K. (2021) · Chemical Science · doi:10.1039/d1sc04775b · Cited by 134 · see citing works

Electrochemical CO 2 reduction to methane with remarkably high Faradaic efficiency in the presence of a proton permeable membrane

Pan, H., & Barile, C. J. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02189j · Cited by 124 · see citing works

Time-Resolved Local pH Measurements during CO 2 Reduction Using Scanning Electrochemical Microscopy: Buffering and Tip Effects

Monteiro, M. C. O., Mirabal, A., Jacobse, L., Doblhoff-Dier, K., Barton, S. C., & Koper, M. T. M. (2021) · JACS Au · doi:10.1021/jacsau.1c00289 · Cited by 124 · see citing works

Enhancing the connection between computation and experiments in electrocatalysis

Resasco, J., Abild‐Pedersen, F., Hahn, C., Bao, Z., Koper, M. T. M., & Jaramillo, T. F. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00789-0 · Cited by 124 · see citing works

High-Performance Electrochemical CO 2 Reduction Cells Based on Non-noble Metal Catalysts

Xu, L. X., Wu, Y., Yuan, X., Huang, L., Wu, Z., Xuan, J., Wang, Y., & Wang, H. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01681 · Cited by 120 · see citing works

Anion Effect in Electrochemical CO 2 Reduction: From Spectators to Orchestrators

Yoo, J. M., Ingenmey, J., Salanne, M., & Lukatskaya, M. R. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c10661 · Cited by 119 · see citing works

Switchable Product Selectivity in the Electrochemical Reduction of Carbon Dioxide Using Boron-Doped Diamond Electrodes

Tomisaki, M., Kasahara, S., Natsui, K., Ikemiya, N., & Einaga, Y. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b01773 · Cited by 117 · see citing works

Recent advances in CO 2 capture and reduction

Wei, K., Guan, H., Luo, Q., He, J., & Sun, S. (2022) · Nanoscale · doi:10.1039/d2nr02894h · Cited by 112 · see citing works

Understanding the complexity in bridging thermal and electrocatalytic methanation of CO 2

Kang, H. D., Ma, J., Perathoner, S., Chu, W., Centi, G., & Liu, Y. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00214k · Cited by 108 · see citing works

Guiding Electrochemical Carbon Dioxide Reduction toward Carbonyls Using Copper Silver Thin Films with Interphase Miscibility

Higgins, D. C., Landers, A. T., Ji, Y., Nitopi, S. A., Morales‐Guio, C. G., Wang, L., Chan, K., Hahn, C., & Jaramillo, T. F. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01736 · Cited by 103 · see citing works

Chlorine anion stabilized Cu2O/ZnO photocathode for selective CO2 reduction to CH4

Guo, S., Tang, Z., Du, Y., Liu, T., Ouyang, T., & Liu, Z. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122035 · Cited by 102 · see citing works

Emerging Atomistic Modeling Methods for Heterogeneous Electrocatalysis

Levell, Z. H., Le, J., Yu, S., Wang, R., Ethirajan, S. K., Rana, R., Kulkarni, A. R., Resasco, J., Lu, D., Cheng, J. J., et al. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00735 · Cited by 99 · see citing works

Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields

McGregor, J.-M., Bender, J. T., Petersen, A. S., Cañada, L. M. C., Rossmeisl, J., Brennecke, J. F., & Resasco, J. (2025) · Nature Catalysis · doi:10.1038/s41929-024-01278-2 · Cited by 111 · see citing works

Advanced manufacturing for electrosynthesis of fuels and chemicals from CO ₂

Corral, D., Feaster, J. T., Sobhani, S., DeOtte, J. R., Lee, D. U., Wong, A. A., Hamilton, J., Beck, V. A., Sarkar, A., Hahn, C., et al. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03679j · Cited by 98 · see citing works

Deciphering Electrolyte Selection for Electrochemical Reduction of Carbon Dioxide and Nitrogen to High‐Value‐Added Chemicals

Ni, J., Cheng, Q., Liu, S., Wang, M., He, Y., Qian, T., Yan, C., & Lu, J. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202212483 · Cited by 99 · see citing works

Kinetic Analysis on the Role of Bicarbonate in Carbon Dioxide Electroreduction at Immobilized Cobalt Phthalocyanine

Zeng, J. S., Corbin, N. S., Williams, K. S., & Manthiram, K. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05272 · Cited by 96 · see citing works

Along the Channel Gradients Impact on the Spatioactivity of Gas Diffusion Electrodes at High Conversions during CO2 Electroreduction

Kaş, R., Star, A. G., Yang, K., Cleve, T. V., Neyerlin, K. C., & Smith, W. A. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c07694 · Cited by 95 · see citing works

Effects of Electrolyte Ionic Species on Electrocatalytic Reactions: Advances, Challenges, and Perspectives

Lu, X., Tu, W., Zhou, Y. L., & Zou, Z. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300628 · Cited by 93 · see citing works

Reduced Ion Crossover in Bipolar Membrane Electrolysis via Increased Current Density, Molecular Size, and Valence

Blommaert, M. A., Verdonk, J. A. H., Blommaert, H., Smith, W. A., & Vermaas, D. A. (2020) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c00687 · Cited by 90 · see citing works

The Importance of Acid–Base Equilibria in Bicarbonate Electrolytes for CO2 Electrochemical Reduction and CO Reoxidation Studied on Au(hkl) Electrodes

Marcandalli, G., Villalba, M. A., & Koper, M. T. M. (2021) · Langmuir · doi:10.1021/acs.langmuir.1c00703 · Cited by 89 · see citing works

CO2 Electroreduction in Ionic Liquids

Faggion, D., Gonçalves, W. D. G., & Dupont, J. (2019) · Frontiers in Chemistry · doi:10.3389/fchem.2019.00102 · Cited by 88 · see citing works

Catalyst–electrolyte interface engineering propels progress in acidic CO 2 electroreduction

Jiang, Y., Huang, L., chen, C., Zheng, Y., & Qiao, S. (2025) · Energy & Environmental Science · doi:10.1039/d4ee05715e · Cited by 86 · see citing works

Role of H 2 O in CO 2 Electrochemical Reduction As Studied in a Water-in-Salt System

Dong, Q., Zhang, X., He, D., Lang, C., & Wang, D. (2019) · ACS Central Science · doi:10.1021/acscentsci.9b00519 · Cited by 82 · see citing works

Nickel as Electrocatalyst for CO (2) Reduction: Effect of Temperature, Potential, Partial Pressure, and Electrolyte Composition

Vos, R. E., & Koper, M. T. M. (2024) · ACS Catalysis · doi:10.1021/acscatal.4c00009 · Cited by 84 · see citing works

Disclosing CO2 Activation Mechanism by Hydroxyl-Induced Crystalline Structure Transformation in Electrocatalytic Process

Huang, Q., Li, Q., Liu, J., Wang, Y., Wang, R., Dong, L., Xia, Y., Wang, J., & Lan, Y. (2019) · Matter · doi:10.1016/j.matt.2019.07.003 · Cited by 83 · see citing works

Unraveling the Structural Sensitivity of CO2 Electroreduction at Facet-Defined Nanocrystals via Correlative Single-Entity and Macroelectrode Measurements

Jeong, S., Choi, M.-H., Jagdale, G. S., Zhong, Y., Siepser, N. P., Wang, Y., Zhan, X., Baker, L. A., & Ye, X. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c02001 · Cited by 83 · see citing works

The Role of Organic Promoters in the Electroreduction of Carbon Dioxide

Vasilyev, D., & Dyson, P. J. (2021) · ACS Catalysis · doi:10.1021/acscatal.0c04283 · Cited by 82 · see citing works

Chemical Modifications of Ag Catalyst Surfaces with Imidazolium Ionomers Modulate H2 Evolution Rates during Electrochemical CO2 Reduction

Koshy, D. M., Akhade, S. A., Shugar, A., Abiose, K., Shi, J., Liang, S., Oakdale, J. S., Weitzner, S. E., Varley, J. B., Duoss, E. B., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c06212 · Cited by 80 · see citing works

The Predominance of Hydrogen Evolution on Transition Metal Sulfides and Phosphides under CO2 Reduction Conditions: An Experimental and Theoretical Study

Landers, A. T., Fields, M. G., Torelli, D. A., Xiao, J., Hellstern, T. R., Francis, S. A., Tsai, C., Kibsgaard, J., Lewis, N. S., Chan, K., et al. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00237 · Cited by 79 · see citing works

Toward Engineering of Solution Microenvironments for the CO 2 Reduction Reaction: Unraveling pH and Voltage Effects from a Combined Density-Functional–Continuum Theory

Weitzner, S. E., Akhade, S. A., Varley, J. B., Wood, B. C., Otani, M., Baker, S. E., & Duoss, E. B. (2020) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.0c00957 · Cited by 77 · see citing works

How to enhance the C2 products selectivity of copper-based catalysts towards electrochemical CO2 reduction?—A review

Li, M., Hu, Y., Wu, T., Sumboja, A., & Geng, D. (2023) · Materials Today · doi:10.1016/j.mattod.2023.05.028 · Cited by 75 · see citing works

Strategies for efficient CO2 electroreduction in acidic conditions

Zou, X., & Gu, J. (2023) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(23)64511-5 · Cited by 84 · see citing works

Steering CO2 electrolysis selectivity by modulating the local reaction environment: An online DEMS approach for Cu electrodes

Ye, K., Zhang, G., Ni, B., Guo, L., Deng, C., Zhuang, X., Zhao, C., Cai, W., & Jiang, K. P. (2023) · eScience · doi:10.1016/j.esci.2023.100143 · Cited by 76 · see citing works

Electrochemical conversion of CO2 to formic acid using a Sn based electrode: A critical review on the state-of-the-art technologies and their potential

Proietto, F., Patel, U., Galia, A., & Scialdone, O. (2021) · Electrochimica Acta · doi:10.1016/j.electacta.2021.138753 · Cited by 75 · see citing works

Rational design of copper-based electrocatalysts and electrochemical systems for CO2 reduction: From active sites engineering to mass transfer dynamics

Zhong, Y., Wang, S., Li, M., Ma, J., Song, S., Kumar, A., Duan, H., Kuang, Y., & Sun, X. (2021) · Materials Today Physics · doi:10.1016/j.mtphys.2021.100354 · Cited by 73 · see citing works

Reactive capture of CO2 via amino acid

Xiao, Y. C., Sun, S. S., Zhao, Y. S., Miao, R. K., Fan, M., Lee, G., Chen, Y., Gabardo, C. M., Yu, Y., Qiu, C., et al. (2024) · Nature Communications · doi:10.1038/s41467-024-51908-3 · Cited by 74 · see citing works

Mechanism in pH effects of electrochemical reactions: a mini-review

Liu, S., Wang, Z., Qiu, S., & Deng, F. (2024) · Carbon letters · doi:10.1007/s42823-024-00724-2 · Cited by 75 · see citing works

The Effect of Temperature on the Cation‐Promoted Electrochemical CO 2 Reduction on Gold

Vos, R. E., & Koper, M. T. M. (2022) · ChemElectroChem · doi:10.1002/celc.202200239 · Cited by 71 · see citing works

Strong effect-correlated electrochemical CO 2 reduction

Tang, Y., Liu, L., Yu, M., Liu, S., Sui, P., Sun, W., Fu, X., Luo, J., & Liu, S. (2024) · Chemical Society Reviews · doi:10.1039/d4cs00229f · Cited by 68 · see citing works

The effect of specific adsorption of halide ions on electrochemical CO 2 reduction

Yuan, T., Wang, T., Zhang, G., Deng, W., Cheng, D., Gao, H., Zhao, J., Yu, J., Zhang, P., & Gong, J. (2022) · Chemical Science · doi:10.1039/d2sc02689a · Cited by 66 · see citing works

Selective Enhancement of Methane Formation in Electrochemical CO 2 Reduction Enabled by a Raman-Inactive Oxygen-Containing Species on Cu

He, M. S., Chang, X., Chao, T., Li, C., Goddard, W. A., Cheng, M., Xu, B., & Lu, Q. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c00087 · Cited by 64 · see citing works

Toward Unifying the Mechanistic Concepts in Electrochemical CO2 Reduction from an Integrated Material Design and Catalytic Perspective

Bagchi, D., Roy, S., Sarma, S. C., & Peter, S. C. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202209023 · Cited by 65 · see citing works

Electrochemically deposited Sn catalysts with dense tips on a gas diffusion electrode for electrochemical CO 2 reduction

Lim, J., Kang, P. W., Jeon, S. S., & Lee, H. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta00569j · Cited by 63 · see citing works

Enigma of Sustainable CO 2 Conversion to Renewable Fuels and Chemicals Through Photocatalysis, Electrocatalysis, and Photoelectrocatalysis: Design Strategies and Atomic Level Insights

Suri, D., Das, S., Choudhary, S., Venkanna, G., Sharma, B., Afroz, M. A., Tailor, N. K., Joshi, R. K., Satapathi, S., & Tripathi, K. (2025) · Small · doi:10.1002/smll.202408981 · Cited by 65 · see citing works

Electrochemical Carbon Dioxide Reduction in Acidic Media

Yao, Z., He, X., & Lin, R. (2024) · Electrochemical Energy Reviews · doi:10.1007/s41918-024-00210-3 · Cited by 66 · see citing works

Anionic Surfactant-Tuned Interfacial Water Reactivity Promoting Electrocatalytic CO 2 Reduction

Ge, W., Zhu, Y., Wang, H., Jiang, H., & Li, C. (2024) · ACS Catalysis · doi:10.1021/acscatal.4c05541 · Cited by 61 · see citing works

The Nature of Carbon Dioxide in Bare Ionic Liquids

Zanatta, M., Simon, N. M., & Dupont, J. (2020) · ChemSusChem · doi:10.1002/cssc.202000574 · Cited by 60 · see citing works

Pitfalls and Protocols: Evaluating Catalysts for CO2 Reduction in Electrolyzers Based on Gas Diffusion Electrodes

Tan, Y. C., Quek, W. K., Kim, B., Sugiarto, S., Oh, J., & Kai, D. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.2c00763 · Cited by 58 · see citing works

Modeling the Local Environment within Porous Electrode during Electrochemical Reduction of Bicarbonate

Kaş, R., Yang, K., Yewale, G. P., Crow, A. M., Burdyny, T., & Smith, W. A. (2022) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.2c00352 · Cited by 55 · see citing works

Electrochemical reduction of CO 2 to value added products

Mahankali, S. K., Furqan, A., Banoth, U. C., Mekala, M., & Ramesh, G. V. (2026) · Chemical Product and Process Modeling · doi:10.1515/cppm-2025-0126

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH

Varela, A. S., Kroschel, M., Reier, T., & Strasser, P. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.06.009 · Cited by 542 · see citing works

Electrolyte Dependence for the Electrochemical CO2 Reduction Activity on Cu(111) Electrodes

Yoshihara, N., Arita, M., & Noda, M. (2016) · Chemistry Letters · doi:10.1246/cl.160888 · Cited by 9 · see citing works

Effects of Electrolyte Buffer Capacity on Surface Reactant Species and the Reaction Rate of CO 2 in Electrochemical CO 2 Reduction

Hashiba, H., Weng, L., Chen, Y., Sato, H., Yotsuhashi, S., Xiang, C., & Weber, A. Z. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b11316 · Cited by 145 · see citing works

Effect of Electrolyte on the Electrochemical Reduction of CO2

Salazar-Villalpando, M. D. (2011) · ECS Transactions · doi:10.1149/1.3565504 · Cited by 23 · see citing works