The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Synthesis of large single-crystal hexagonal boron nitride grains on Cu–Ni alloy
Open accessAbstract
Hexagonal boron nitride (h-BN) has attracted significant attention because of its superior properties as well as its potential as an ideal dielectric layer for graphene-based devices. The h-BN films obtained via chemical vapour deposition in earlier reports are always polycrystalline with small grains because of high nucleation density on substrates. Here we report the successful synthesis of large single-crystal h-BN grains on rational designed Cu–Ni alloy foils. It is found that the nucleation density can be greatly reduced to 60 per mm2 by optimizing Ni ratio in substrates. The strategy enables the growth of single-crystal h-BN grains up to 7,500 μm2, approximately two orders larger than that in previous reports. This work not only provides valuable information for understanding h-BN nucleation and growth mechanisms, but also gives an effective alternative to exfoliated h-BN as a high-quality dielectric layer for large-scale nanoelectronic applications. High nucleation density has thus far limited the quality and grain size of CVD-grown hexagonal boron nitride. Here, by optimizing the Ni ratio in Cu–Ni substrates, the authors successfully reduce nucleation density and report single-crystal hexagonal boron nitride grains up to 7500 μm2.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Raman Spectrum of Graphene and Graphene Layers
Ferrari, A. C., Meyer, J. C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K. S., Roth, S., et al. (2006) · Physical Review Letters · doi:10.1103/physrevlett.97.187401 · Cited by 15,047
Boron nitride substrates for high-quality graphene electronics
Dean, C. R., Young, A. F., Meric, I., Lee, C., Wang, L., Sorgenfrei, S., Watanabe, K., Taniguchi, T., Kim, P., Shepard, K. L., et al. (2010) · Nature Nanotechnology · doi:10.1038/nnano.2010.172 · Cited by 7,124
Large Scale Growth and Characterization of Atomic Hexagonal Boron Nitride Layers
Song, L., Ci, L., Lu, H., Sorokin, P. B., Jin, C., Ni, J., Kvashnin, A. G., Kvashnin, D. G., Lou, J., Yakobson, B. I., et al. (2010) · Nano Letters · doi:10.1021/nl1022139 · Cited by 2,689
Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures
Britnell, L., Gorbachev, R. V., Jalil, R., Belle, B. D., Schedin, F., Mishchenko, A., Georgiou, T., Katsnelson, M. I., Eaves, L., Morozov, S. V., et al. (2012) · Science · doi:10.1126/science.1218461 · Cited by 2,561
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
Graf, D., Molitor, F., Ensslin, K., Stampfer, C., Jungen, A., Hierold, C., & Wirtz, L. (2007) · Nano Letters · doi:10.1021/nl061702a · Cited by 2,540
Frictional Characteristics of Atomically Thin Sheets
Lee, C., Li, Q., Kalb, W., Liu, X.-Z., Berger, H., Carpick, R. W., & Hone, J. (2010) · Science · doi:10.1126/science.1184167 · Cited by 1,811
Synthesis of Monolayer Hexagonal Boron Nitride on Cu Foil Using Chemical Vapor Deposition
Kim, K. K., Hsu, A., Jia, X., Kim, S. M., Shi, Y., Hofmann, M., Nezich, D., Rodriguez-Nieva, J. F., Dresselhaus, M., Palacios, T., et al. (2012) · Nano Letters · doi:10.1021/nl203249a · Cited by 1,256
Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure
Kubota, Y., Watanabe, K., Tsuda, O., & Taniguchi, T. (2007) · Science · doi:10.1126/science.1144216 · Cited by 1,249
Synthesis of Few-Layer Hexagonal Boron Nitride Thin Film by Chemical Vapor Deposition
Shi, Y., Hamsen, C., Jia, X., Kim, K. K., Reina, A., Hofmann, M., Hsu, A., Zhang, K., Li, H., Juang, Z., et al. (2010) · Nano Letters · doi:10.1021/nl1023707 · Cited by 1,231
Hunting for Monolayer Boron Nitride: Optical and Raman Signatures
Gorbachev, R. V., Riaz, I., Nair, R. R., Jalil, R., Britnell, L., Belle, B. D., Hill, E. W., Novoselov, K. S., Watanabe, K., Taniguchi, T., et al. (2011) · Small · doi:10.1002/smll.201001628 · Cited by 1,151
The two-dimensional phase of boron nitride: Few-atomic-layer sheets and suspended membranes
Pacilé, D., Meyer, J. C., Girit, Ç. Ö., & Zettl, A. (2008) · Applied Physics Letters · doi:10.1063/1.2903702 · Cited by 1,059
Ultrathin high-temperature oxidation-resistant coatings of hexagonal boron nitride
Liu, Z., Gong, Y., Zhou, W., Ma, L., Yu, J., Idrobo, J. C., Jung, J., MacDonald, A. H., Vajtai, R., Lou, J., et al. (2013) · Nature Communications · doi:10.1038/ncomms3541 · Cited by 720
Resonant tunnelling and negative differential conductance in graphene transistors
Britnell, L., Gorbachev, R., Geim, A. K., Ponomarenko, L. A., Mishchenko, A., Greenaway, M. T., Fromhold, T. M., Novoselov, K. S., & Eaves, L. (2013) · Nature Communications · doi:10.1038/ncomms2817 · Cited by 661
Hexagonal boron nitride: Fabrication, properties and applications
Lipp, A., Schwetz, K. A., & Hunold, K. (1989) · Journal of the European Ceramic Society · doi:10.1016/0955-2219(89)90003-4 · Cited by 479
Calorimetric process monitoring of thermal decomposition of B–N–H compounds
Wolf, G., Baumann, J., Baitalow, F., & Hoffmann, F. P. (2000) · Thermochimica Acta · doi:10.1016/s0040-6031(99)00365-2 · Cited by 457
Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods
Baitalow, F., Baumann, J., Wolf, G., Jaenicke-Rößler, K., & Leitner, G. (2002) · Thermochimica Acta · doi:10.1016/s0040-6031(02)00173-9 · Cited by 440
Growth of High-Crystalline, Single-Layer Hexagonal Boron Nitride on Recyclable Platinum Foil
Kim, G., Jang, A.-R., Jeong, H. Y., Lee, Z., Kang, D. J., & Shin, H. S. (2013) · Nano Letters · doi:10.1021/nl400559s · Cited by 385
Toward the Controlled Synthesis of Hexagonal Boron Nitride Films
Ismach, A., Chou, H., Ferrer, D. A., Wu, Y., McDonnell, S., Floresca, H. C., Covacevich, A., Pope, C., Piner, R., Kim, M. J., et al. (2012) · ACS Nano · doi:10.1021/nn301940k · Cited by 346
Raman Spectroscopy of Single-Wall Boron Nitride Nanotubes
Arenal, R., Ferrari, A. C., Reich, S., Wirtz, L., Mevellec, J.-Y., Lefrant, S., Rubio, A., & Loiseau, A. (2006) · Nano Letters · doi:10.1021/nl0602544 · Cited by 330
Broken-symmetry states and divergent resistance in suspended bilayer graphene
Feldman, B. E., Martin, J., & Yacoby, A. (2009) · Nature Physics · doi:10.1038/nphys1406 · Cited by 323
Growth of Large Single-Crystalline Two-Dimensional Boron Nitride Hexagons on Electropolished Copper
Tay, R. Y., Griep, M. H., Mallick, G., Tsang, S. H., Singh, R. S., Tumlin, T., Teo, E. H. T., & Karna, S. P. (2014) · Nano Letters · doi:10.1021/nl404207f · Cited by 321
Gibb, A. L., Alem, N., Chen, J.-H., Erickson, K. J., Ciston, J., Gautam, A., Linck, M., & Zettl, A. (2013) · Journal of the American Chemical Society · doi:10.1021/ja400637n · Cited by 260
Thermal transport in hexagonal boron nitride nanoribbons
Ouyang, T., Chen, Y., Xie, Y., Yang, K., Bao, Z., & Zhong, J. (2010) · Nanotechnology · doi:10.1088/0957-4484/21/24/245701 · Cited by 253
Wang, L., Wu, B., Chen, J., Liu, H., Hu, P., & Liu, Y. (2014) · Advanced Materials · doi:10.1002/adma.201304937 · Cited by 248
Gao, Y., Ren, W., Ma, T., Liu, Z., Zhang, Y., Liu, W.-B., Ma, L.-P., Ma, X., & Cheng, H.-M. (2013) · ACS Nano · doi:10.1021/nn4009356 · Cited by 243
Thermal decomposition of polymeric aminoborane (H2BNH2)x under hydrogen release
Baumann, J., Baitalow, F., & Wolf, G. (2005) · Thermochimica Acta · doi:10.1016/j.tca.2004.12.002 · Cited by 182
Bresnehan, M. S., Hollander, M. J., Wetherington, M., et al. (2012) · ACS Nano · doi:10.1021/nn300996t · Cited by 149
Synthesis and characterization of poly(aminoborane) as a new boron nitride precursor
Kim, D., Moon, K., Kho, J., Economy, J., Gervais, C., & Babonneau, F. (1999) · Polymers for Advanced Technologies · doi:10.1002/(sici)1099-1581(199912)10:12<702::aid-pat931>3.0.co;2-q · Cited by 122
Lithographically defined uniform worm-shaped polymeric nanoparticles
Tao, L., Zhao, X., Gao, J., & Hu, W. W. (2010) · Nanotechnology · doi:10.1088/0957-4484/21/9/095301 · Cited by 43
Cited by
Structure, Properties and Applications of Two‐Dimensional Hexagonal Boron Nitride
Roy, S., Zhang, X., Puthirath, A. B., Meiyazhagan, A., Bhattacharyya, S., Rahman, M. M., Babu, G., Susarla, S., Saju, S. K., Tran, M. K., et al. (2021) · Advanced Materials · doi:10.1002/adma.202101589 · Cited by 871
Zeng, M., Xiao, Y., Liu, J., Yang, K., & Fu, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00633 · Cited by 574
Surface chemistry and catalysis confined under two-dimensional materials
Fu, Q., & Bao, X. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00424e · Cited by 532
A general printing approach for scalable growth of perovskite single-crystal films
Gu, Z., Huang, Z., Li, C., Li, M., & Song, Y. (2018) · Science Advances · doi:10.1126/sciadv.aat2390 · Cited by 214
High temperature thermal management with boron nitride nanosheets
Wang, Y., Xu, L., Yang, Z., Xie, H., Jiang, P., Dai, J., Luo, W., Yao, Y., Hitz, E., Yang, R., et al. (2018) · Nanoscale · doi:10.1039/c7nr07058f · Cited by 66
Metadata
- Authors
- Lu, G., Wu, T., Yuan, Q., Wang, H., Wang, H., Ding, F., Xie, X., & Jiang, M.
- Venue
- Nature Communications
- Published
- 2015-01-21
- Volume
- 6
- Issue
- 1
- Pages
- 6160-6160
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2002839444
- Cited by
- 377
- References
- 29
- FWCI
- 17.72
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
