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The optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells
Open accessAbstract
Perovskite photovoltaics offer a compelling combination of extremely low-cost, ease of processing and high device performance. The optoelectronic properties of the prototypical CH 3 NH 3 PbI 3 can be further adjusted by introducing other extrinsic ions. Specifically, chlorine incorporation has been shown to affect the morphological development of perovksite films, which results in improved optoelectronic characteristics for high efficiency. However, it requires a deep understanding to the role of extrinsic halide, especially in the absence of unpredictable morphological influence during film growth. Here we report an effective strategy to investigate the role of the extrinsic ion in the context of optoelectronic properties, in which the morphological factors that closely correlate to device performance are mostly decoupled. The chlorine incorporation is found to mainly improve the carrier transport across the heterojunction interfaces, rather than within the perovskite crystals. Further optimization according this protocol leads to solar cells achieving power conversion efficiency of 17.91%.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
Burschka, J., Pellet, N., Moon, S.-J., Humphry-Baker, R., Gao, P., Nazeeruddin, M. K., & Grätzel, M. (2013) · Nature · doi:10.1038/nature12340 · Cited by 9,547
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Efficient planar heterojunction perovskite solar cells by vapour deposition
Liu, M., Johnston, M. B., & Snaith, H. J. (2013) · Nature · doi:10.1038/nature12509 · Cited by 7,976
The emergence of perovskite solar cells
Green, M. A., Ho-Baillie, A., & Snaith, H. J. (2014) · Nature Photonics · doi:10.1038/nphoton.2014.134 · Cited by 7,432
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3
Xing, G., Mathews, N., Sun, S., Lim, S. S., Lam, Y. M., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2013) · Science · doi:10.1126/science.1243167 · Cited by 6,909
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Interface engineering of highly efficient perovskite solar cells
Zhou, H., Chen, Q., Li, G., Luo, S., Song, T.-B., Duan, H.-S., Hong, Z., You, J., Liu, Y., & Yang, Y. (2014) · Science · doi:10.1126/science.1254050 · Cited by 6,632
Self-citationNoh, J. H., Im, S. H., Heo, J. H., Mandal, T. N., & Seok, S. I. (2013) · Nano Letters · doi:10.1021/nl400349b · Cited by 4,829
Eperon, G. E., Stranks, S. D., Menelaou, C., Johnston, M. B., Herz, L. M., & Snaith, H. J. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43822h · Cited by 4,140
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
Snaith, H. J. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz4020162 · Cited by 3,042
Lead-free solid-state organic–inorganic halide perovskite solar cells
Hao, F., Stoumpos, C. C., Cao, D. H., Chang, R. P. H., & Kanatzidis, M. G. (2014) · Nature Photonics · doi:10.1038/nphoton.2014.82 · Cited by 3,026
Lead-free organic–inorganic tin halide perovskites for photovoltaic applications
Noel, N. K., Stranks, S. D., Abate, A., Wehrenfennig, C., Guarnera, S., Haghighirad, A.-A., Sadhanala, A., Eperon, G. E., Pathak, S. K., Johnston, M. B., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01076k · Cited by 2,746
Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process
Chen, Q., Zhou, H., Hong, Z., Luo, S., Duan, H.-S., Wang, H.-H., Liu, Y., Li, G., & Yang, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411509g · Cited by 2,306
Self-citationThe light and shade of perovskite solar cells
Grätzel, M. (2014) · Nature Materials · doi:10.1038/nmat4065 · Cited by 2,258
Perovskite solar cells: an emerging photovoltaic technology
Park, N.-G. (2015) · Materials Today · doi:10.1016/j.mattod.2014.07.007 · Cited by 2,097
Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells
Im, J.-H., Jang, I.-H., Pellet, N., Grätzel, M., & Park, N.-G. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.181 · Cited by 1,759
Xiao, Z., Dong, Q., Bi, C., Shao, Y., Yuan, Y., & Huang, J. (2014) · Advanced Materials · doi:10.1002/adma.201401685 · Cited by 1,703
Chen, Q., Zhou, H., Song, T.-B., Luo, S., Hong, Z., Duan, H.-S., Dou, L., Liu, Y., & Yang, Y. (2014) · Nano Letters · doi:10.1021/nl501838y · Cited by 1,543
Self-citationPark, N.-G. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400892a · Cited by 1,382
Anisotropy of the Electronic Work Function of Metals
Smoluchowski, R. (1941) · Physical Review · doi:10.1103/physrev.60.661 · Cited by 1,367
Mixed‐Organic‐Cation Perovskite Photovoltaics for Enhanced Solar‐Light Harvesting
Pellet, N., Gao, P., Gregori, G., Yang, T., Nazeeruddin, M. K., Maier, J., & Grätzel, M. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309361 · Cited by 1,306
Xiao, Z., Bi, C., Shao, Y., Dong, Q., Wang, Q., Yuan, Y., Wang, C., Gao, Y., & Huang, J. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01138d · Cited by 1,234
CH3NH3SnxPb(1–x)I3 Perovskite Solar Cells Covering up to 1060 nm
Ogomi, Y., Morita, A., Tsukamoto, S., Saitho, T., Fujikawa, N., Shen, Q., Toyoda, T., Yoshino, K., Pandey, S. S., Ma, T., et al. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz5002117 · Cited by 978
High‐Efficiency Perovskite Solar Cells Based on the Black Polymorph of HC(NH2)2PbI3
Lee, J., Seol, D., Cho, A., & Park, N. (2014) · Advanced Materials · doi:10.1002/adma.201401137 · Cited by 951
Colella, S., Mosconi, E., Fedeli, P., Listorti, A., Gazza, F., Orlandi, F., Ferro, P., Besagni, T., Rizzo, A., Calestani, G., et al. (2013) · Chemistry of Materials · doi:10.1021/cm402919x · Cited by 796
Koh, T. M., Fu, K., Fang, Y., Chen, S., Sum, T. C., Mathews, N., Mhaisalkar, S. G., Boix, P. P., & Baikie, T. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp411112k · Cited by 790
Self-citationHigh performance hybrid solar cells sensitized by organolead halide perovskites
Cai, B., Xing, Y., Yang, Z., Zhang, W.-H., & Qiu, J. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40343b · Cited by 655
NH2CH═NH2PbI3: An Alternative Organolead Iodide Perovskite Sensitizer for Mesoscopic Solar Cells
Pang, S., Hu, H., Zhang, J., Lv, S., Yu, Y., Wei, F., Qin, T., Xu, H., Liu, Z., & Cui, G. (2014) · Chemistry of Materials · doi:10.1021/cm404006p · Cited by 580
The Role of Chlorine in the Formation Process of “CH3NH3PbI3‐xClx” Perovskite
Yu, H., Wang, F., Xie, F., Li, W., Chen, J., & Zhao, N. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201401872 · Cited by 572
Edri, E., Kirmayer, S., Mukhopadhyay, S., Gartsman, K., Hodes, G., & Cahen, D. (2014) · Nature Communications · doi:10.1038/ncomms4461 · Cited by 566
Edri, E., Kirmayer, S., Henning, A., Mukhopadhyay, S., Gartsman, K., Rosenwaks, Y., Hodes, G., & Cahen, D. (2014) · Nano Letters · doi:10.1021/nl404454h · Cited by 564
Zhao, Y., & Zhu, K. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp502696w · Cited by 555
High Open-Circuit Voltage Solar Cells Based on Organic–Inorganic Lead Bromide Perovskite
Edri, E., Kirmayer, S., Cahen, D., & Hodes, G. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400348q · Cited by 541
Tidhar, Y., Edri, E., Weissman, H., Zohar, D., Hodes, G., Cahen, D., Rybtchinski, B., & Kirmayer, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505556s · Cited by 444
Recombination Study of Combined Halides (Cl, Br, I) Perovskite Solar Cells
Suarez, B., Gonzalez-Pedro, V., Ripolles, T. S., Sanchez, R. S., Otero, L., & Mora-Sero, I. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz5006797 · Cited by 428
Duan, H.-S., Zhou, H., Chen, Q., Sun, P., Luo, S., Song, T.-B., Bob, B., & Yang, Y. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp04479g · Cited by 395
Self-citationRole of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films
Williams, S. T., Zuo, F., Chueh, C.-C., Liao, C.-Y., Liang, P.-W., & Jen, A. K.-Y. (2014) · ACS Nano · doi:10.1021/nn5041922 · Cited by 385
Edri, E., Kirmayer, S., Kulbak, M., Hodes, G., & Cahen, D. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz402706q · Cited by 371
Binary‐Metal Perovskites Toward High‐Performance Planar‐Heterojunction Hybrid Solar Cells
Zuo, F., Williams, S. T., Liang, P., Chueh, C., Liao, C., & Jen, A. K. ‐. (2014) · Advanced Materials · doi:10.1002/adma.201401641 · Cited by 335
Depletion region effect of highly efficient hole conductor free CH3NH3PbI3perovskite solar cells
Aharon, S., Gamliel, S., Cohen, B. E., & Etgar, L. (2014) · Phys. Chem. Chem. Phys. · doi:10.1039/c4cp00460d · Cited by 285
Zhang, M., Yu, H., Lyu, M., Wang, Q., Yun, J.-H., & Wang, L. (2014) · Chem. Commun. · doi:10.1039/c4cc04973j · Cited by 248
Aharon, S., Cohen, B. E., & Etgar, L. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp5023407 · Cited by 227
New Light on an Old Story: Perovskites Go Solar
Lotsch, B. V. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309368 · Cited by 209
Elusive Presence of Chloride in Mixed Halide Perovskite Solar Cells
Colella, S., Mosconi, E., Pellegrino, G., Alberti, A., Guerra, V. L. P., Masi, S., Listorti, A., Rizzo, A., Condorelli, G. G., De Angelis, F., et al. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz501869f · Cited by 193
Ma, Y., Zheng, L., Chung, Y., Chu, S., Xiao, L., Chen, Z., Wang, S., Qu, B., Gong, Q., Wu, Z., et al. (2014) · Chemical Communications · doi:10.1039/c4cc01962h · Cited by 88
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Tan, H., Jain, A., Voznyy, O., Lan, X., García de Arquer, F. P., Fan, J. Z., Quintero-Bermudez, R., Yuan, M., Zhang, B., Zhao, Y., et al. (2017) · Science · doi:10.1126/science.aai9081 · Cited by 2,342
Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions
Ono, L. K., Juarez-Perez, E. J., & Qi, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06001 · Cited by 593
Lai, H., Kan, B., Liu, T., Zheng, N., Xie, Z., Zhou, T., Wan, X., Zhang, X., Liu, Y., & Chen, Y. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04604 · Cited by 477
Self-citationRecent Progress on the Long‐Term Stability of Perovskite Solar Cells
Fu, Q., Tang, X., Huang, B., Hu, T., Tan, L., Chen, L., & Chen, Y. (2018) · Advanced Science · doi:10.1002/advs.201700387 · Cited by 454
A Flexible UV–Vis–NIR Photodetector based on a Perovskite/Conjugated‐Polymer Composite
Chen, S., Teng, C., Zhang, M., Li, Y., Xie, D., & Shi, G. (2016) · Advanced Materials · doi:10.1002/adma.201600468 · Cited by 391
Metadata
- Authors
- Chen, Q., Zhou, H., Fang, Y., Stieg, A. Z., Song, T.-B., Wang, H.-H., Xu, X., Liu, Y., Lu, S., You, J., Sun, P., McKay, J., Goorsky, M. S., & Yang, Y.
- Venue
- Nature Communications
- Published
- 2015-06-12
- Volume
- 6
- Issue
- 1
- Pages
- 7269-7269
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2271355543
- Cited by
- 485
- References
- 46
- FWCI
- 33.52
- Type
- journal article
- Language
- en
- Open access
- gold
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