Circular olefin copolymers made de novo from ethylene and α-olefins
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Abstract
Ethylene/α-olefin copolymers are produced in huge scale and widely used, but their after-use disposal has caused plastic pollution problems. Their chemical inertness made chemical re/upcycling difficult. Ideally, PE materials should be made de novo to have a circular closed-loop lifecycle. However, synthesis of circular ethylene/α-olefin copolymers, including high-volume, linear low-density PE as well as high-value olefin elastomers and block copolymers, presents a particular challenge due to difficulties in introducing branches while simultaneously installing chemical recyclability and directly using industrial ethylene and α-olefin feedstocks. Here we show that coupling of industrial coordination copolymerization of ethylene and α-olefins with a designed functionalized chain-transfer agent, followed by modular assembly of the resulting AB telechelic polyolefin building blocks by polycondensation, affords a series of ester-linked PE-based copolymers. These new materials not only retain thermomechanical properties of PE-based materials but also exhibit full chemical circularity via simple transesterification and markedly enhanced adhesion to polar surfaces.
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- Authors
- Han, X.-W., Zhang, X., Zhou, Y., Maimaitiming, A., Sun, X.-L., Gao, Y., Li, P., Zhu, B., Chen, E. Y.-X., Kuang, X., & Tang, Y.
- Affiliations
- Southern University of Science and Technology (CN)
- Chinese Academy of Sciences (CN)
- Colorado State University (US)
- Corresponding author
- Gao, Yanshan
- Chen, Eugene Y.-X.
- Tang, Yong
- ORCID
- Venue
- Nature Communications
- Published
- 2024-02-17
- Volume
- 15
- Issue
- 1
- Pages
- 1462-1462
- ISSN
- 2041-1723 (ISSN-L)
- PMC
- PMC10874424
- OpenAlex
- W4391899270
- Cited by
- 85
- References
- 44
- Citations by year
- 2026: 28 · 2025: 45 · 2024: 12
- FWCI
- 8.98
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Nature Communications (publishedVersion, cc-by)
- ChemRxiv (acceptedVersion, cc-by-nc)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion, cc-by)
- RePEc: Research Papers in Economics (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- U.S. Department of Energy (DESC0022290)
- Colorado State University
- Innovative Research Group Project of the National Natural Science Foundation of China
- National Natural Science Foundation of China (U19B6001, SPST-AIC10112914)
- Chinese Academy of Sciences (XDB0610000)
- Shenzhen University
- Southern University of Science and Technology (2020B121201002)
- ShanghaiTech University (SPST-AIC10112914, AIC10112914)
- Office of Science (DESC0022290)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- ethylene/α-olefin copolymers, polyethylene, chemical recycling, polycondensation, transesterification, linear low-density polyethylene, block copolymers, plastic pollution
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