Multicomponent polymer coating to block photocatalytic activity of TiO2 nanoparticles

The potential risks of nanomaterials: a review carried out for ECETOC.

Borm, P. J. A., Robbins, D. J., Haubold, S., Kuhlbusch, T. A. J., Fissan, H. J., Donaldson, K., Schins, R. P. F., Stone, V., Kreyling, W. G., Lademann, J. M., et al. (2006) · Particle and Fibre Toxicology · doi:10.1186/1743-8977-3-11 · Cited by 1,344 · see citing works

Toxic effects of ultraviolet radiation on the skin

Matsumura, Y., & Ananthaswamy, H. N. (2004) · Toxicology and Applied Pharmacology · doi:10.1016/j.taap.2003.08.019 · Cited by 1,270 · see citing works

<i>Grey Goo</i>on the Skin? Nanotechnology, Cosmetic and Sunscreen Safety

Nohynek, G. J., Lademann, J., Ribaud, C., & Roberts, M. S. (2007) · Critical Reviews in Toxicology · doi:10.1080/10408440601177780 · Cited by 644 · see citing works

Chemical oxidation and DNA damage catalysed by inorganic sunscreen ingredients

Dunford, R., Salinaro, A., Cai, L., Serpone, N., Horikoshi, S., Hidaka, H., & Knowland, J. (1997) · FEBS Letters · doi:10.1016/s0014-5793(97)01356-2 · Cited by 540 · see citing works

Visible Light Absorption by Various Titanium Dioxide Specimens

Kuznetsov, V. N., & Serpone, N. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp064253b · Cited by 236 · see citing works

In vitro photochemical damage to DNA, RNA and their bases by an inorganic sunscreen agent on exposure to UVA and UVB radiation

Hidaka, H., Horikoshi, S., Serpone, N., & Knowland, J. (1997) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/s1010-6030(97)00229-3 · Cited by 135 · see citing works

Beneficial effects of photo-inactive titanium dioxide specimens on plasmid DNA, human cells and yeast cells exposed to UVA/UVB simulated sunlight

Serpone, N., Salinaro, A., Horikoshi, S., & Hidaka, H. (2005) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/j.jphotochem.2005.08.017 · Cited by 53 · see citing works

Antioxidant Oligomeric Proanthocyanidins from Sea Buckthorn (Hippophaë rhamnoides) Pomace

Rösch, D., Mügge, C., Fogliano, V., & Kroh, L. W. (2004) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf040241g · Cited by 49 · see citing works

Mechanistic study of the TiO2-assisted photodegradation of squarylium cyanine dye in methanolic suspensions exposed to visible light

Wu, T., Liu, G., Zhao, J., Hidaka, H., & Serpone, N. (2000) · New Journal of Chemistry · doi:10.1039/a908647a · Cited by 31 · see citing works

Understanding biophysicochemical interactions at the nano–bio interface

Nel, A. E., Mädler, L., Velegol, D., Xia, T., Hoek, E. M. V., Somasundaran, P., Klaessig, F., Castranova, V., & Thompson, M. (2009) · Nature Materials · doi:10.1038/nmat2442 · Cited by 7,083 · see citing works

Protein−Nanoparticle Interactions: Opportunities and Challenges

Mahmoudi, M., Lynch, I., Ejtehadi, M. R., Monopoli, M. P., Bombelli, F. B., & Laurent, S. (2011) · Chemical Reviews · doi:10.1021/cr100440g · Cited by 1,425 · see citing works

Gold Nanoparticles of Diameter 1.4 nm Trigger Necrosis by Oxidative Stress and Mitochondrial Damage

Pan, Y., Leifert, A., Ruau, D., Neuß, S., Bornemann, J., Schmid, G., Brandau, W., Simon, U., & Jahnen‐Dechent, W. (2009) · Small · doi:10.1002/smll.200900466 · Cited by 802 · see citing works

Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications

Yan, J., Bockstaller, M. R., & Matyjaszewski, K. A. (2019) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2019.101180 · Cited by 208 · see citing works

Sustainable hybrid photocatalysts: titania immobilized on carbon materials derived from renewable and biodegradable resources

Colmenares, J. C., Varma, R. S., & Lisowski, P. (2016) · Green Chemistry · doi:10.1039/c6gc02477g · Cited by 197 · see citing works

Adverse Effects of Titanium Dioxide Nanoparticles on Human Dermal Fibroblasts and How to Protect Cells

Pan, Z., Lee, W., Slutsky, L., Clark, R. A. F., Pernodet, N., & Rafailovich, M. H. (2009) · Small · doi:10.1002/smll.200800798 · Cited by 197 · see citing works

TiO2-based nanoparticles released in water from commercialized sunscreens in a life-cycle perspective: Structures and quantities

Botta, C., Labille, J., Auffan, M., Borschneck, D., Miche, H., Cabié, M., Masion, A., Rose, J., & Bottero, J. (2011) · Environmental Pollution · doi:10.1016/j.envpol.2011.03.003 · Cited by 188 · see citing works

Physicochemical Origin for Free Radical Generation of Iron Oxide Nanoparticles in Biomicroenvironment: Catalytic Activities Mediated by Surface Chemical States

Wang, B., Yin, J., Zhou, X., Kurash, I., Chai, Z., Zhao, Y., & Feng, W. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3101392 · Cited by 155 · see citing works

Polymer/TiO2 Hybrid Nanoparticles with Highly Effective UV-Screening but Eliminated Photocatalytic Activity

Xiao, J., Chen, W., Wang, F., & Du, J. (2013) · Macromolecules · doi:10.1021/ma3022019 · Cited by 92 · see citing works

Photoprotection in the Era of Nanotechnology

Wang, S. Q., & Tooley, I. R. (2011) · Seminars in Cutaneous Medicine and Surgery · doi:10.1016/j.sder.2011.07.006 · Cited by 88 · see citing works

Role of particle coating in controlling skin damage photoinduced by titania nanoparticles

Carlotti, M. E., Ugazio, E., Sapino, S., Fenoglio, I., Greco, G., & Fubini, B. (2009) · Free Radical Research · doi:10.1080/10715760802716633 · Cited by 81 · see citing works

Lysosome-controlled efficient ROS overproduction against cancer cells with a high pH-responsive catalytic nanosystem

Fu, J., Shao, Y., Wang, L., & Zhu, Y. (2015) · Nanoscale · doi:10.1039/c5nr00706b · Cited by 72 · see citing works

Singlet oxygen generation in the presence of titanium dioxide materials used as sunscreens in suntan lotions

Buchalska, M., Kras, G., Oszajca, M., Łasocha, W., & Macyk, W. (2010) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/j.jphotochem.2010.05.019 · Cited by 68 · see citing works

Potential photocarcinogenic effects of nanoparticle sunscreens

Tran, D. T., & Salmon, R. (2010) · Australasian Journal of Dermatology · doi:10.1111/j.1440-0960.2010.00677.x · Cited by 66 · see citing works

Lignin coating to quench photocatalytic activity of titanium dioxide nanoparticles for potential skin care applications

Morsella, M., Giammatteo, M., Arrizza, L., Tonucci, L., Bressan, M., & d’Alessandro, N. (2015) · RSC Advances · doi:10.1039/c5ra05232g · Cited by 49 · see citing works

Ultrafast sonochemistry-based approach to coat TiO2 commercial particles for sunscreen formulation

Barbosa, J., Neto, D. M. A., Freire, R. M., Rocha, J. S., Fechine, L. M. U. D., Denardin, J. C., Valentini, A., de Araújo, T. G., Mazzetto, S. E., & Fechine, P. B. A. (2018) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2018.06.015 · Cited by 49 · see citing works

Fabrication of Nanostructured Self‐Detoxifying Nanofiber Membranes that Contain Active Polymeric Functional Groups

Sundarrajan, S., Venkatesan, A., & Ramakrishna, S. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200900208 · Cited by 47 · see citing works

Decreasing the oxidative potential of TiO2 nanoparticles through modification of the surface with carbon: a new strategy for the production of safe UV filters

Livraghi, S., Corazzari, I., Paganini, M. C., Ceccone, G., Giamello, E., Fubini, B., & Fenoglio, I. (2010) · Chemical Communications · doi:10.1039/c0cc02537b · Cited by 46 · see citing works

Nanoparticles: Characteristics, Mechanisms and Modulation of Biotoxicity

Somasundaran, P., Fang, X., Ponnurangam, S., & Li, B. (2010) · KONA Powder and Particle Journal · doi:10.14356/kona.2010007 · Cited by 46 · see citing works

Nanotechnology Environmental, Health, and Safety Issues

Nel, A. E., Grainger, D. W., Alvarez, P. J. J., Badesha, S. S., Castranova, V., Mauro Ferrari, B., Godwin, H. A., Grodzinski, P. A., Morris, J., Savage, N., et al. (2011) · Springer eBooks · doi:10.1007/978-94-007-1168-6_5 · Cited by 41 · see citing works

Preparation of highly stable superhydrophobic TiO2 surfaces with completely suppressed photocatalytic activity

Kim, K.-D., Seo, H. O., Sim, C. W., Jeong, M., Kim, Y. D., & Lim, D. C. (2012) · Progress in Organic Coatings · doi:10.1016/j.porgcoat.2012.11.010 · Cited by 39 · see citing works

Effects of coating materials on antibacterial properties of industrial and sunscreen-derived titanium-dioxide nanoparticles on Escherichia coli

Baek, S., Joo, S. H., Blackwelder, P. L., & Toborek, M. J. (2018) · Chemosphere · doi:10.1016/j.chemosphere.2018.05.167 · Cited by 31 · see citing works

Light and latex: advances in the photochemistry of polymer colloids

Scott, P. J., Kasprzak, C. R., Feller, K. D., Meenakshisundaram, V., Williams, C. B., & Long, T. E. (2020) · Polymer Chemistry · doi:10.1039/d0py00349b · Cited by 30 · see citing works

Inactivation of TiO2 nano-powders for the preparation of photo-stable sunscreens via carbon-based surface modification

Corazzari, I., Livraghi, S., Ferrero, S., Giamello, E., Fubini, B., & Fenoglio, I. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm32876c · Cited by 28 · see citing works

Rapid fabrication of TiO2@carboxymethyl cellulose coatings capable of shielding UV, antifog and delaying support aging

Li, X., Lv, J., Li, D., & Wang, L. (2017) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2017.04.045 · Cited by 28 · see citing works

The quenching effect of chitosan crosslinking on ZnO nanoparticles photocatalytic activity

Regiel-Futyra, A., Kus‐Liśkiewicz, M., Wojtyła, S., Stochel, G., & Macyk, W. (2015) · RSC Advances · doi:10.1039/c5ra12667c · Cited by 24 · see citing works

Carboxymethyl chitosan coating to block photocatalytic activity of TiO2 nanoparticles

Chen, X., Liu, Y., Shi, H., Wang, X., Qi, K., Zhou, X., & Xin, J. H. (2010) · Textile Research Journal · doi:10.1177/0040517510376265 · Cited by 24 · see citing works

Inhibition of the ROS-mediated cytotoxicity and genotoxicity of nano-TiO2 toward human keratinocyte cells by iron doping

Ghiazza, M., Alloa, E., Oliaro‐Bosso, S., Viola, F., Livraghi, S., Rembges, D., Capomaccio, R. B., Rossi, F., Ponti, J., & Fenoglio, I. (2014) · Journal of Nanoparticle Research · doi:10.1007/s11051-014-2263-z · Cited by 20 · see citing works

Physical UV-blocker TiO2 nanocomposites elevated toxicity of chemical sunscreen BP-1 under UV irradiation

Guo, Q., Wei, D., Zhao, C., Wang, C., Ma, H., & Du, Y. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.143899 · Cited by 19 · see citing works

Toxicity Associated with the Photo Catalytic and Photo Stable Forms of Titanium Dioxide Nanoparticles Used in Sunscreen lotion

Pulvin, S. (2015) · MOJ Toxicology · doi:10.15406/mojt.2015.01.00011 · Cited by 20 · see citing works

Proteomic profiling of protein corona formed on the surface of nanomaterial

Zhang, H., & Wu, R. (2015) · Science China Chemistry · doi:10.1007/s11426-015-5395-9 · Cited by 16 · see citing works

Sub-nanoscale Surface Engineering of TiO2 Nanoparticles by Molecular Layer Deposition of Poly(ethylene terephthalate) for Suppressing Photoactivity and Enhancing Dispersibility

Zara, D. L., Bailey, M. R., Hagedoorn, P., Benz, D., Quayle, M. J., Folestad, S., & van Ommen, J. R. (2020) · ACS Applied Nano Materials · doi:10.1021/acsanm.0c01158 · Cited by 16 · see citing works

IMMOBILIZATION AND STABILIZATION OF TiO 2 NANOPARTICLES IN ALKALINE- SOLIDIFICATED CHITOSAN SPHERES WITHOUT CROSS-LINKING AGENT

Huang, K., Grumezescu, A. M., Chang, C.-Y., Yang, C.-H., & Wang, C.-Y. (2014) · Cited by 10 · see citing works

Hydrophobic Magnetite Nanoparticles for Bioseparation: Green Synthesis, Functionalization, and Characterization

Alimohammadi, V., Ebrahimi, S. A. S., Kashanian, F., Lalegani, Z., Habibi-Rezaei, M., & Hamawandi, B. (2022) · Magnetochemistry · doi:10.3390/magnetochemistry8110143 · Cited by 9 · see citing works

Hyaluronic acid-grafted titanium dioxide nanoparticles for moisture-retentive and non-cytotoxic sunscreen creams

Gui, H., Liu, H., Cai, Y. Q., Nian, J., Liu, L., Song, Y., Kye, S.-B., Zuo, S., & Yao, C. (2025) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2025.143957 · Cited by 9 · see citing works

Enhancing bioactivity and stability of polymer-based material-tissue interface through coupling multiscale interfacial interactions with atomic-thin TiO2 nanosheets

Xu, R., Mu, X., Hu, Z., Jia, C., Yang, Z., Yang, Z., Fan, Y., Wang, X., Wu, Y., Lu, X., et al. (2022) · Nano Research · doi:10.1007/s12274-022-5153-1 · Cited by 9 · see citing works

UV protection afforded by gel-trapped TiO2 particles

Sojka, M. F., Cummins, P. G., Declercq, L., Fthenakis, C. G., Ionita-Manzatu, M. C., Lee, W. A., Maes, D. H., McKeever-Alfieri, M., Najdek, L. J., Pernodet, N., et al. (2011) · Photochemical & Photobiological Sciences · doi:10.1039/c0pp00327a · Cited by 6 · see citing works

Toxicity Associated with the Photo Catalytic and Photo Stable Forms of Titanium Dioxide Nanoparticles Used in Sunscreen lotion

Pulvin, S. (2015) · MOJ Toxicology · doi:10.15406/mojt.2015.02.00011 · Cited by 3 · see citing works

Preparation of ZnO/Chitosan Nanocomposite and Its Applications to Durable Antibacterial, UV-Blocking, and Textile Properties

Dutta, T., Khan, A. A., Baildya, N., Mondal, P., & Ghosh, N. N. (2022) · Advanced structured materials · doi:10.1007/978-3-031-13343-5_6 · Cited by 3 · see citing works

Titanium, zirconium and hafnium

Cotton, S. A. (2008) · Annual Reports Section A (Inorganic Chemistry) · doi:10.1039/b716569m · Cited by 2 · see citing works

Positive Suppression of the Photocatalytic Activity of Metal-doped Titanium Dioxide Nanosheets

Muraguchi, R., Okamoto, M., Hsu, C., Hatakeyama, K., & Ida, S. (2021) · Chemistry Letters · doi:10.1246/cl.210182 · Cited by 1 · see citing works

ZnO tetrapod/poly[ε]caprolactone fibre nanocomposite photocatalysts for water purification

Tichonovas, M., Mockutė, E., Puzerė, D., Prasauskas, T., Martuzevičius, D., Tamulevičius, T., Peckus, D., & Račkauskas, S. (2026) · Materials Science and Engineering B · doi:10.1016/j.mseb.2026.119271 · Cited by 1 · see citing works

Impacts and Physico-Chemical Behavior of Inorganic Nanoparticles in the Environment

Auffan, M., Rose, J., Masion, A., Labille, J., Chanéac, C., Wiesner, M. R., & Bottero, J. (2012) · Springer eBooks · doi:10.1007/978-1-4471-4213-3_10 · Cited by 1 · see citing works

Sunscreen: A catch-22

Blum, C., & Larsen, S. (2009) · Young Scientists Journal · doi:10.4103/0974-6102.68738 · Cited by 1 · see citing works

Titanium dioxide as a safe additive to sunscreen emulsions

Janczarek, M., & Szaferski, W. (2023) · Chemical and Process Engineering New Frontiers · doi:10.24425/cpe.2022.142288 · Cited by 1 · see citing works

Study on Preparation and Performance of the Compositon Coating of Polyurethane Added with Y~(3+),n-doping TiO_2

Huai-bao, C. (2012) · Guangzhou Chemical Industry

Enhanced photochemical stability of hydrophobic TiO2 via covalently anchoring near-monolayer octadecyl brushes and its robust superhydrophobic photocatalytic coatings

Gu, A., Qiu, X., Zhang, R., Tang, W., Zou, Q., Liu, Y., & Yu, Z. (2026) · Materials & Design · doi:10.1016/j.matdes.2026.116398 · Cited by 1 · see citing works

Polymer/TiO2 Hybrid Nanoparticles with Highly Effective UV-Screening but Eliminated Photocatalytic Activity

Xiao, J., Chen, W., Wang, F., & Du, J. (2013) · Macromolecules · doi:10.1021/ma3022019 · Cited by 92 · see citing works

Ultrafast sonochemistry-based approach to coat TiO2 commercial particles for sunscreen formulation

Barbosa, J., Neto, D. M. A., Freire, R. M., Rocha, J. S., Fechine, L. M. U. D., Denardin, J. C., Valentini, A., de Araújo, T. G., Mazzetto, S. E., & Fechine, P. B. A. (2018) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2018.06.015 · Cited by 49 · see citing works

Interactions of titania based nanoparticles with silica and green-tea: Photo-degradation and -luminescence \n

Verma, R., Awasthi, A., Singh, P., Srivastava, R., Sheng, H., Wen, J., Miller, D. J., & Srivastava, A. K. (2016) · IR@NPL (CSIR-The National Physical Laboratory(NPL))