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Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates
Abstract
This Perspective article summarizes efforts paid in our group to develop efficient metal-based catalysts for the immortal ring-opening polymerization (iROP) of cyclic esters in the presence of large amounts of alcohols (ROH) as chain transfer agents. The catalyst systems reviewed include discrete organometallic complexes based on rare earths, magnesium, calcium and more specifically zinc, as well as simple systems employing metal triflate salts, notably Al(OTf)(3), for the (stereo)controlled iROP of lactide (LA), beta-butyrolactone (BBL) and trimethylenecarbonate (TMC). Special emphasis is given to systems that allow the use of minute amounts of metal catalysts and large loadings of both monomer and alcohol for the rapid and productive formation of functional polyesters (H-Pol-OR) with controlled molecular features.
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“The initiators based on porphyrin complexes or complexes with related structures based on Al, Zn, Y, Lu, In have been used for the polymerization of e.g., oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others [147,149 -156].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [152]
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“For example, a zinc catalyst with bdiiminate amido ligand ((BDI i Pr)Zn[N(SiMe3)2] exhibits excellent reactivity and selectivity for the ROP of a variety of lactones and cyclic carbonates.296”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [296]
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Metadata
- Authors
- Ajellal, N., Carpentier, J.-F., Guillaume, C., Guillaume, S. M., Helou, M., Poirier, V., Sarazin, Y., & Trifonov, A.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Russian Academy of Sciences (RU)
- Corresponding author
- Carpentier, Jean-François
- Guillaume, Sophie M.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 39
- Issue
- 36
- Pages
- 8363
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2009027332
- Cited by
- 494
- References
- 101
- Citations by year
- 2026: 8 · 2025: 15 · 2024: 15 · 2023: 22 · 2022: 24 · 2021: 17 · 2020: 23 · 2019: 26 · 2018: 37 · 2017: 48 · 2016: 39 · 2015: 52 · 2014: 36 · 2013: 55 · 2012: 41
- FWCI
- 17.31
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Dalton Transactions (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- metal-catalyzed polymerization, cyclic esters, lactones, lactide, β-butyrolactone, cyclic carbonates, chain transfer agent, rare earth complexes, zinc catalyst, magnesium catalyst, calcium catalyst, aluminum triflate, functional polyesters, molecular weight control
- MeSH terms
- Alcohols, Carbonates, Catalysis, Dioxanes, Metals, Organometallic Compounds, 4-Butyrolactone, Coordination Complexes, Polymerization
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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