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Powering denitrification: the perspectives of electrocatalytic nitrate reduction
Abstract
Imbalances in the nitrogen cycle caused by human activities (combustion, fertiliser-intensive agriculture) have resulted in alarmingly increased levels of nitrate in groundwater and other water bodies, with potentially health-threatening consequences. The electrocatalytic removal of nitrate from polluted water is a promising alternative to bacterial denitrification, provided that full selectivity to harmless N2, which can be returned to the atmosphere, is achieved. This perspective article discusses the state-of-the-art of research on electrocatalytic denitrification, critically evaluating the obstacles still hampering large-scale application of this technique. The milestones of fundamental research focussing on the cathode reaction will first be dealt with, followed by their translation into electrochemical reactors of practical interest. Finally, a short foray into the novel field of bioelectrochemical reactors will close the article. Challenges and opportunities pertaining to these three topics will be analysed.
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Metadata
- Authors
- Duca, M., & Koper, M. T. M.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 12
- Pages
- 9726
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2147592121
- Cited by
- 699
- References
- 104
- FWCI
- 7.80
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
