General Formation of M–MoS 3 (M = Co, Ni) Hollow Structures with Enhanced Electrocatalytic Activity for Hydrogen Evolution
Abstract
Complex molybdenum-based ternary or multinary sulfides hollow structures are developed via a fast precipitation process, together with a subsequent annealing treatment. Benefiting from the merits of high-curvature surfaces with excellent intrinsic catalytic activity, the obtained unique hollow structures exhibit enhanced performance as electrocatalysts for hydrogen production in acidic media.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
B-Os aerogels have Tafel slopes of approximately 26.8 and 44.7 mV dec−1 in 0.5 M H2SO4 and 1 M PBS, indicating more beneficial HER kinetics than Os NPs and Pt/C.
“The Tafel slopes of B-Os aerogels in 0.5 M H2SO4 and 1 M PBS were approximately 26.8 and 44.7 mV dec−1, indicating that the B-Os aerogel has the more beneficial HER kinetics than Os NPs and Pt/C”
From Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution (2022) · cites this paper as [51]
Cites
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,316 · see citing works
Trends in the exchange current for hydrogen evolution
Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121 · see citing works
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100 · see citing works
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885 · see citing works
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001 · see citing works
Formation of hollow nanocrystals through the nanoscale kirkendall \neffect
Yin, Y., Rioux, R. M., Erdonmez, C. K., Hughes, S. M., Somorjai, G. A., & Alivisatos, A. P. (2004) · eScholarship (California Digital Library) · Cited by 3,537 · see citing works
Lukowski, M. A., Daniel, A. S., Meng, F., Forticaux, A., Li, L., & Jin, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja404523s · Cited by 3,341 · see citing works
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234 · see citing works
Xie, J., Zhang, H., Li, S., Wang, R., Sun, X., Zhou, M., Zhou, J., Lou, X. W. (., & Xie, Y. (2013) · Advanced Materials · doi:10.1002/adma.201302685 · Cited by 3,079 · see citing works
Self-citationNanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911 · see citing works
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437 · see citing works
Synthesis of MoS <sub>2</sub> and MoSe <sub>2</sub> Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250 · see citing works
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236 · see citing works
Metal dichalcogenide nanosheets: preparation, properties and applications
Huang, X., Zeng, Z., & Zhang, H. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35387c · Cited by 2,030 · see citing works
Faber, M. S., Dziedzic, R., Lukowski, M. A., Kaiser, N. S., Ding, Q., & Jin, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504099w · Cited by 1,372 · see citing works
Laursen, A. B., Kegnæs, S., Dahl, S., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02618j · Cited by 1,348 · see citing works
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153 · see citing works
Benck, J. D., Chen, Z., Kuritzky, L. Y., Forman, A. J., & Jaramillo, T. F. (2012) · ACS Catalysis · doi:10.1021/cs300451q · Cited by 1,091 · see citing works
A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction
Liao, L., Wang, S., Xiao, J., Bian, X., Zhang, Y., Scanlon, M. D., Hu, X., Tang, Y. D., Liu, B., & Girault, H. H. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42441c · Cited by 1,044 · see citing works
Xia, X., Wang, Y., Ruditskiy, A., & Younan Xia, A. (2013) · Advanced Materials · doi:10.1002/adma.201302820 · Cited by 1,020 · see citing works
Wang, H., Lu, Z., Xu, S., Kong, D., Cha, J. J., Zheng, G. W., Hsu, P., Yan, K., Bradshaw, D., Prinz, F. B., et al. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1316792110 · Cited by 985 · see citing works
Merki, D., Vrubel, H., Rovelli, L., Fierro, S., & Hu, X. (2012) · Chemical Science · doi:10.1039/c2sc20539d · Cited by 941 · see citing works
Yan, Y., Xia, B., Xu, Z., & Wang, X. (2014) · ACS Catalysis · doi:10.1021/cs500070x · Cited by 868 · see citing works
Self-citationXing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Advanced Materials · doi:10.1002/adma.201401692 · Cited by 835 · see citing works
Hydrogen evolution on nano-particulate transition metal sulfides
Bonde, J., Moses, P. G., Jaramillo, T. F., Nørskov, J. K., & Chorkendorff, I. (2008) · Faraday Discussions · doi:10.1039/b803857k · Cited by 805 · see citing works
Hydrogen evolution catalyzed by MoS3 and MoS2 particles
Vrubel, H., Merki, D., & Hu, X. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02835b · Cited by 726 · see citing works
Ultrathin WS2 Nanoflakes as a High‐Performance Electrocatalyst for the Hydrogen Evolution Reaction
Cheng, L., Huang, W., Gong, Q., Liu, C., Liu, Z., Li, Y., & Dai, H. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402315 · Cited by 690 · see citing works
Wang, H., Lu, Z., Kong, D., Sun, J., Hymel, T. M., & Cui, Y. (2014) · ACS Nano · doi:10.1021/nn500959v · Cited by 611 · see citing works
General Synthesis and Gas‐Sensing Properties of Multiple‐Shell Metal Oxide Hollow Microspheres
Lai, X., Li, J., Korgel, B. A., et al. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201004900 · Cited by 583 · see citing works
Galvanic Replacement Reactions in Metal Oxide Nanocrystals
Oh, M. H., Yu, T., Yu, S., Lim, B., Ko, K., Willinger, M., Seo, D., Kim, B. H., Cho, M. G., Park, J., et al. (2013) · Science · doi:10.1126/science.1234751 · Cited by 542 · see citing works
Wu, R. F., Zhang, J., Shi, Y., Liu, D., & Zhang, B. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01330 · Cited by 517 · see citing works
Zhang, L., Wu, H. B., Yan, Y., Wang, X., & Lou, X. W. (. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01932f · Cited by 493 · see citing works
Self-citationFormation of Ni x Co 3− x S 4 Hollow Nanoprisms with Enhanced Pseudocapacitive Properties
Yu, L., Zhang, L., Wu, H. B., et al. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201400226 · Cited by 481 · see citing works
Self-citationNai, J., Tian, Y., Guan, X., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja402751r · Cited by 315 · see citing works
Yu, X., Yu, L., Shen, L., Song, X., Chen, H., & Lou, X. W. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201402560 · Cited by 298 · see citing works
Self-citationCopper molybdenum sulfide: a new efficient electrocatalyst for hydrogen production from water
Tran, P. D., Nguyen, M., Pramana, S., Bhattacharjee, A., Chiam, S. Y., Fize, J., Field, M., Artero, V., Wong, L., Loo, J., et al. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22611a · Cited by 298 · see citing works
Zhang, G., & Lou, X. W. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201404604 · Cited by 266 · see citing works
Self-citationGe, X., Chen, L., Zhang, L., Wen, Y., Hirata, A., & Chen, M. W. (2014) · Advanced Materials · doi:10.1002/adma.201305678 · Cited by 212 · see citing works
Zhuo, S., Xu, Y., Zhao, W., Zhang, J., & Zhang, B. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201303480 · Cited by 203 · see citing works
Serial Ionic Exchange for the Synthesis of Multishelled Copper Sulfide Hollow Spheres
Xiong, S. L., & Zeng, H. C. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201106826 · Cited by 196 · see citing works
Albu‐Yaron, A., Levy, M., Tenne, R., Popovitz‐Biro, R., Weidenbach, M., Bar‐Sadan, M., Houben, L., Enyashin, A. N., Seifert, G., Feuermann, D., et al. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201006719 · Cited by 71 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133 · see citing works
Li, Y., Peng, C.-K., Hu, H., Chen, S.-Y., Choi, J.-H., Lin, Y.-G., & Lee, J.-M. (2022) · Nature Communications · doi:10.1038/s41467-022-28805-8 · Cited by 291 · see citing works
Ray, C., Lee, S. C., Sankar, K. V., Jin, B., Lee, J., Park, J. H., & Jun, S. C. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b11192 · Cited by 142 · see citing works
Djire, A., Wang, X., Xiao, C., Nwamba, O. C., Mirkin, M. V., & Neale, N. R. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202001136 · Cited by 104 · see citing works
Self-citationYao, X., Zhu, J., Wang, H., Yang, K., Shu, Y., & He, J. (2022) · Applied Surface Science · doi:10.1016/j.apsusc.2022.152842 · Cited by 36 · see citing works
- Authors
- Yu, L., Xia, B. Y., Wang, X., & Lou, X. W.
- Affiliations
- Nanyang Technological University (SG)
- Corresponding author
- Wang, Xin
- Lou, Xiong Wen
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2015-11-05
- Volume
- 28
- Issue
- 1
- Pages
- 92-97
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2151668528
- Cited by
- 383
- References
- 41
- Citations by year
- 2026: 5 · 2025: 8 · 2024: 7 · 2023: 17 · 2022: 25 · 2021: 31 · 2020: 37 · 2019: 74 · 2018: 70 · 2017: 67 · 2016: 42
- FWCI
- 17.64
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Metalloenzymes and iron-sulfur proteins
- Keywords
- hollow structures, molybdenum sulfide, cobalt molybdenum sulfide, nickel molybdenum sulfide, ternary sulfides, hydrogen evolution reaction, electrocatalysts, acidic media, annealing, high-curvature surfaces
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review