Cited by 2,990CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingCarbon dioxide utilization in catalysis

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A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Qiao, Jinli, Liu, Yuyu, Hong, Feng, Zhang, Jiujun·2014·Chem. Soc. Rev.

DOI 10.1039/c3cs60323g

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Abstract

This paper reviews recent progress made in identifying electrocatalysts for carbon dioxide (CO2) reduction to produce low-carbon fuels, including CO, HCOOH/HCOO(-), CH2O, CH4, H2C2O4/HC2O4(-), C2H4, CH3OH, CH3CH2OH and others. The electrocatalysts are classified into several categories, including metals, metal alloys, metal oxides, metal complexes, polymers/clusters, enzymes and organic molecules. The catalyts' activity, product selectivity, Faradaic efficiency, catalytic stability and reduction mechanisms during CO2 electroreduction have received detailed treatment. In particular, we review the effects of electrode potential, solution-electrolyte type and composition, temperature, pressure, and other conditions on these catalyst properties. The challenges in achieving highly active and stable CO2 reduction electrocatalysts are analyzed, and several research directions for practical applications are proposed, with the aim of mitigating performance degradation, overcoming additional challenges, and facilitating research and development in this area.

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Self-citation

Authors: Qiao, J., Liu, Y., Hong, F., & Zhang, J.
Affiliations: Donghua University (CN)
Tohoku University (JP)
Corresponding author: Liu, Yuyu
Hong, Feng
Zhang, Jiujun
ORCID: Qiao, Jinli
Liu, Yuyu
Hong, Feng
Zhang, Jiujun
Venue: Chem. Soc. Rev.
Publisher: Royal Society of Chemistry (RSC)
Published: 2014
Volume: 43
Issue: 2
Pages: 631-675
ISSN: 0306-0012 (ISSN-L)
1460-4744
DOI: 10.1039/c3cs60323g
OpenAlex: W1992591486
Cited by: 2,990
References: 391
Citations by year: 2026: 142 · 2025: 203 · 2024: 269 · 2023: 255 · 2022: 292 · 2021: 312 · 2020: 350 · 2019: 328 · 2018: 289 · 2017: 221 · 2016: 159 · 2015: 119 · 2014: 51
FWCI: 6.20
Type: journal article
Language: en
Open access: closed
Locations: Chemical Society Reviews (publishedVersion)
PubMed (publishedVersion)
NPARC (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords: electrochemical CO2 reduction, electrocatalysts, low-carbon fuels, co-production, formate production, methanol synthesis, ethanol production, ethylene production, methane production, hydrogen production, Faradaic efficiency, catalyst stability, reduction mechanism, electrode potential effects, electrolyte composition, metal oxides, metal complexes, enzyme catalysts, alloys

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A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

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