A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Design and synthesis of an exceptionally stable and highly porous metal-organic framework

Li, H., Eddaoudi, M., O’Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,582

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

Eddaoudi, M., Kim, J., Rosi, N. L., Vodak, D. T., Wachter, J., O’Keeffe, M., & Yaghi, O. M. (2002) · Science · doi:10.1126/science.1067208 · Cited by 8,228

TiO2 photocatalysis and related surface phenomena

FUJISHIMA, A., ZHANG, X., & TRYK, D. (2008) · Surface Science Reports · doi:10.1016/j.surfrep.2008.10.001 · Cited by 6,737

A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n

Chui, S. S.-Y., Lo, S. M. F., Charmant, J. P. H., Orpen, A. G., & Williams, I. D. (1999) · Science · doi:10.1126/science.283.5405.1148 · Cited by 6,071

Transformation of Carbon Dioxide

Sakakura, T., Choi, J., & Yasuda, H. Y. (2007) · Chemical Reviews · doi:10.1021/cr068357u · Cited by 3,891

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160

A route to high surface area, porosity and inclusion of large molecules in crystals

Materials Design and Discovery Group, Chae, H. K., Siberio-Pérez, D. Y., Kim, J., Go, Y., Eddaoudi, M., Matzger, A. J., O’Keeffe, M., & Yaghi, O. M. (2004) · Nature · doi:10.1038/nature02311 · Cited by 2,817

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media

Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140

Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels

Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2008) · Chemical Society Reviews · doi:10.1039/b804323j · Cited by 2,061

CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films

Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000

Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing

Song, C. (2006) · Catalysis Today · doi:10.1016/j.cattod.2006.02.029 · Cited by 1,832

Catalysis of the electrochemical reduction of carbon dioxide

Costentin, C., Robert, M., & Savéant, J. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35360a · Cited by 1,664

Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles

Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661

Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution

Hori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,644

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons

Olah, G. A., Goeppert, A., & Prakash, G. K. S. (2008) · The Journal of Organic Chemistry · doi:10.1021/jo801260f · Cited by 1,609

A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper

Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,482

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels

Centi, G., & Perathoner, S. (2009) · Catalysis Today · doi:10.1016/j.cattod.2009.07.075 · Cited by 1,477

Utilisation of CO2 as a chemical feedstock: opportunities and challenges

Aresta, M., & Dibenedetto, A. (2007) · Dalton Transactions · doi:10.1039/b700658f · Cited by 1,454

Prospects of CO 2 Utilization via Direct Heterogeneous Electrochemical Reduction

Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,419

Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrogencarbonate solution

Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401

Chemical approaches to artificial photosynthesis

Meyer, T. J. (1989) · Accounts of Chemical Research · doi:10.1021/ar00161a001 · Cited by 1,360

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst

Costentin, C., Drouet, S., Robert, M., & Savéant, J. (2012) · Science · doi:10.1126/science.1224581 · Cited by 1,319

Photoelectrochemical reduction of aqueous carbon dioxide on p-type gallium phosphide in liquid junction solar cells

Halmann, M. M. (1978) · Nature · doi:10.1038/275115a0 · Cited by 1,017

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

Savéant, J. (2008) · Chemical Reviews · doi:10.1021/cr068079z · Cited by 1,006

Tin Oxide Dependence of the CO 2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts

Chen, Y., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108799 · Cited by 982

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes

Schouten, K. J. P., Kwon, Y., van der Ham, C. J. M., Qin, Z., & Koper, M. T. M. (2011) · Chemical Science · doi:10.1039/c1sc00277e · Cited by 972

Chemical Approaches to Artificial Photosynthesis. 2

Alstrum-Acevedo, J. H., Brennaman, M. K., & Meyer, T. J. (2005) · Inorganic Chemistry · doi:10.1021/ic050904r · Cited by 948

Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes

Schouten, K. J. P., Qin, Z., Pérez‐Gallent, E., & Koper, M. T. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302668n · Cited by 904

Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation

DuBois, M. R., & DuBois, D. L. (2009) · Accounts of Chemical Research · doi:10.1021/ar900110c · Cited by 839

Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts

Schneider, J. D., Jia, H., Muckerman, J. T., & Fujita, E. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15278e · Cited by 771

Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes

Hori, Y., Takahashi, I., Koga, O., & Hoshi, N. (2003) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(03)00016-5 · Cited by 762

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO 2 Reduction to CO

Hansen, H. A., Varley, J. B., Peterson, A. A., & Nørskov, J. K. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz3021155 · Cited by 759

Recent advances in the homogeneous hydrogenation of carbon dioxide

Jessop, P. G., Joó, F., & Tai, C.-C. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.05.019 · Cited by 749

The Solubility of Carbon Dioxide in Water at Low Pressure

Carroll, J. J., Slupsky, J. D., & Mather, A. E. (1991) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555900 · Cited by 749

Selective Solar-Driven Reduction of CO2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell

Barton, E. E., Rampulla, D. M., & Bocarsly, A. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja0776327 · Cited by 732

Homogeneous catalytic hydrogenation of supercritical carbon dioxide

Jessop, P. G., Ikariya, T., & Noyori, R. (1994) · Nature · doi:10.1038/368231a0 · Cited by 726

Efficient photochemical reduction of CO 2 to CO by visible light irradiation of systems containing Re(bipy)(CO) 3 X or Ru(bipy) 3 2+ –Co 2+ combinations as homogeneous catalysts

Hawecker, J., Lehn, J., & Ziessel, R. F. (1983) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39830000536 · Cited by 713

The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction

Tang, W., Peterson, A. A., Varela, A. S., Jovanov, Z. P., Bech, L., Durand, W. J., Dahl, S., Nørskov, J. K., & Chorkendorff, I. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22700a · Cited by 697

Photochemical and Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (2,2′‐Bipyridine)tricarbonylchlororhenium(I) and Related Complexes as Homogeneous Catalysts

Hawecker, J., Lehn, J., & Ziessel, R. (1986) · Helvetica Chimica Acta · doi:10.1002/hlca.19860690824 · Cited by 690

PRODUCTION OF METHANE AND ETHYLENE IN ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE AT COPPER ELECTRODE IN AQUEOUS HYDROGENCARBONATE SOLUTION

Hori, Y., Kikuchi, K., Murata, A., & Suzuki, S. (1986) · Chemistry Letters · doi:10.1246/cl.1986.897 · Cited by 668

Standard potentials in aqueous solutions

Zuman, P. (1986) · Microchemical Journal · doi:10.1016/0026-265x(86)90041-x · Cited by 654

Recent developments in carbon dioxide utilization for the production of organic chemicals

Omae, I. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.03.017 · Cited by 608

Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO)3Cl (bipy = 2,2′-bipyridine)

Hawecker, J., Lehn, J., & Ziessel, R. F. (1984) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39840000328 · Cited by 601

Electrocatalytic CO 2 Conversion to Oxalate by a Copper Complex

Angamuthu, R., Byers, P. M., Lutz, M., Spek, A. L., & Bouwman, E. (2010) · Science · doi:10.1126/science.1177981 · Cited by 592

[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction

Bourrez, M., Molton, F., Chardon‐Noblat, S., & Deronzier, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103616 · Cited by 591

Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt

Fisher, B. J., & Eisenberg, R. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00544a035 · Cited by 579

The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility

Agarwal, A. S., Zhai, Y., Hill, D., & Sridhar, N. (2011) · ChemSusChem · doi:10.1002/cssc.201100220 · Cited by 573

Reversible interconversion of carbon dioxide and formate by an electroactive enzyme

Reda, T., Plugge, C. M., Abram, N. J., & Hirst, J. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0801290105 · Cited by 561

Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces

Durand, W. J., Peterson, A. A., Studt, F., Abild‐Pedersen, F., & Nørskov, J. K. (2011) · Surface Science · doi:10.1016/j.susc.2011.04.028 · Cited by 559

Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights

Cole, E. B., Lakkaraju, P. S., Rampulla, D. M., Morris, A. J., Abelev, E., & Bocarsly, A. B. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1023496 · Cited by 557

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO2 and CO at a Cu Electrode

Murata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544

The coordination chemistry of carbon dioxide and its relevance for catalysis: a critical survey

Leitner, W. (1996) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(95)01226-5 · Cited by 543

Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process

Beley, M., Collin, J. P., Ruppert, R., & Sauvage, J. (1986) · Journal of the American Chemical Society · doi:10.1021/ja00284a003 · Cited by 539

Re(bipy-tBu)(CO)3Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies

Smieja, J. M., & Kubiak, C. P. (2010) · Inorganic Chemistry · doi:10.1021/ic1008363 · Cited by 535

Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces

Le, M., Ren, M.-Y., Zhang, Z., Sprunger, P. T., Kurtz, R. L., & Flake, J. C. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3561636 · Cited by 500

Catalytic Reactions Involving C 1 Feedstocks: New High-Activity Zn(II)-Based Catalysts for the Alternating Copolymerization of Carbon Dioxide and Epoxides

Cheng, M. T., Lobkovsky, E. B., & Coates, G. W. (1998) · Journal of the American Chemical Society · doi:10.1021/ja982601k · Cited by 483

Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low‐Temperature Aqueous KHCO 3 Media

Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086796 · Cited by 482

Advances in molecular photocatalytic and electrocatalytic CO2 reduction

Windle, C. D., & Perutz, R. N. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.03.010 · Cited by 481

Reactions of carbon dioxide with carbon-carbon bond formation catalyzed by transition-metal complexes

Braunstein, P., Matt, D., & Nobel, D. (1988) · Chemical Reviews · doi:10.1021/cr00087a003 · Cited by 467

Experimental and Computational Investigation of Au 25 Clusters and CO 2 : A Unique Interaction and Enhanced Electrocatalytic Activity

Kauffman, D. R., Alfonso, D. R., Matranga, C., Qian, H., & Jin, R. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303259q · Cited by 450

Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability

Amatore, C. A., & Savéant, J. M. (1981) · Journal of the American Chemical Society · doi:10.1021/ja00407a008 · Cited by 441

“Deactivation of copper electrode” in electrochemical reduction of CO2

Hori, Y., Konishi, H., Futamura, T., Murata, A., Koga, O., Sakurai, H., & Oguma, K. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2005.03.015 · Cited by 432

Preparing to Capture Carbon

Schrag, D. P. (2007) · Science · doi:10.1126/science.1137632 · Cited by 413

Chemical approaches to artificial photosynthesis

Concepcion, J. J., House, R. L., Papanikolas, J. M., & Meyer, T. J. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1212254109 · Cited by 410

Life with Carbon Monoxide

Ragsdale, S. W. (2004) · Critical Reviews in Biochemistry and Molecular Biology · doi:10.1080/10409230490496577 · Cited by 405

Manganese as a Substitute for Rhenium in CO 2 Reduction Catalysts: The Importance of Acids

Smieja, J. M., Sampson, M. D., Grice, K. A., Benson, E. E., Froehlich, J. D., & Kubiak, C. P. (2013) · Inorganic Chemistry · doi:10.1021/ic302391u · Cited by 403

One- and two-electron pathways in the electrocatalytic reduction of CO 2 by fac-Re(bpy)(CO) 3 Cl (bpy = 2,2′-bipyridine)

Sullivan, B., Bolinger, C. M., Conrad, D. W., Vining, W. J., & Meyer, T. J. (1985) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39850001414 · Cited by 398

Electrochemical reduction of carbon dioxide on flat metallic cathodes

Jitaru, M., Löwy, D. A., Toma, M., Toma, B. C., & Oniciu, L. (1997) · Journal of Applied Electrochemistry · doi:10.1023/a:1018441316386 · Cited by 388

Reversibility and efficiency in electrocatalytic energy conversion and lessons from enzymes

Armstrong, F. A., & Hirst, J. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1103697108 · Cited by 378

Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins: Synergystic Effect of Weak Brönsted Acids

Bhugun, I., Lexa, D., & Savéant, J. (1996) · Journal of the American Chemical Society · doi:10.1021/ja9534462 · Cited by 375

Electrochemical and Surface Studies of Carbon Dioxide Reduction to Methane and Ethylene at Copper Electrodes in Aqueous Solutions

DeWulf, D. W., Jin, T., & Bard, A. J. (1989) · Journal of The Electrochemical Society · doi:10.1149/1.2096993 · Cited by 372

Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide

Ikeda, S., Takagi, T., & Ito, K. (1987) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.60.2517 · Cited by 369

Effect of Cations on the Electrochemical Conversion of CO2to CO

Thorson, M. R., Siil, K. I., & Kenis, P. J. A. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.052301jes · Cited by 365

Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water

Beley, M., Collin, J., Ruppert, R., & Sauvage, J. (1984) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39840001315 · Cited by 365

Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations

Hammouche, M., Lexa, D., Momenteau, M., & Savéant, J. M. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00022a038 · Cited by 355

Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO-

Ishida, H., Tanaka, K., & Tanaka, T. (1987) · Organometallics · doi:10.1021/om00144a033 · Cited by 341

Electrocatalytic Reduction of CO2 Using the Complexes [Re(bpy)(CO)3L]n (n = +1, L = P(OEt)3, CH3CN; n = 0, L = Cl-, Otf-; bpy = 2,2‘-Bipyridine; Otf- = CF3SO3) as Catalyst Precursors: Infrared Spectroelectrochemical Investigation

Johnson, F. P. A., George, M. W., Hartl, F., & Turner, J. J. (1996) · Organometallics · doi:10.1021/om960044+ · Cited by 338

Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes

Kang, P., Chen, C., Chen, Z., Schauer, C. K., Meyer, T. J., & Brookhart, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300543s · Cited by 330

CO2 Reduction on Transition Metal (Fe, Co, Ni, and Cu) Surfaces: In Comparison with Homogeneous Catalysis

Liu, C., Cundari, T. R., & Wilson, A. K. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp210480c · Cited by 329

Electrocatalytic properties of (tetraazacyclotetradecane)nickel(2+) and Ni2(biscyclam)4+ with respect to carbon dioxide and water reduction

Collin, J. P., Jouaiti, A., & Sauvage, J. (1988) · Inorganic Chemistry · doi:10.1021/ic00284a030 · Cited by 326

Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine

Lieber, C. M., & Lewis, N. S. (1984) · Journal of the American Chemical Society · doi:10.1021/ja00329a082 · Cited by 316

Highly selective electrochemical reduction of carbon dioxide using Cu based metal organic framework as an electrocatalyst

Kumar, R., Kumar, S. S., & Kulandainathan, M. A. (2012) · Electrochemistry Communications · doi:10.1016/j.elecom.2012.09.018 · Cited by 316

Recent progress in the electrochemical conversion and utilization of CO2

Spinner, N. S., Vega, J. A., & Mustain, W. E. (2011) · Catalysis Science & Technology · doi:10.1039/c1cy00314c · Cited by 311

Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode

Froehlich, J. D., & Kubiak, C. P. (2012) · Inorganic Chemistry · doi:10.1021/ic3001619 · Cited by 310

Electrochemical reduction of CO2 on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110)

Hoshi, N., Kato, M., & Hori, Y. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00447-6 · Cited by 308

Photocatalytic reduction of CO2 with H2O on various titanium oxide photocatalysts

Mori, K., Yamashita, H., & Anpo, M. (2012) · RSC Advances · doi:10.1039/c2ra01332k · Cited by 308

Electrocatalysis by metal phthalocyanines in the reduction of carbon dioxide

Meshitsuka, S., Ichikawa, M., & Tamaru, K. (1974) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39740000158 · Cited by 307

Towards Solar Fuels from Water and CO2

Centi, G., & Perathoner, S. (2010) · ChemSusChem · doi:10.1002/cssc.200900289 · Cited by 295

Molecular approaches to the electrochemical reduction of carbon dioxide

Finn, C., Schnittger, S., Yellowlees, L. J., & Love, J. B. (2011) · Chemical Communications · doi:10.1039/c1cc15393e · Cited by 294

Standard potential and kinetic parameters of the electrochemical reduction of carbon dioxide in dimethylformamide

Lamy, E., Nadjo, L., & Savéant, J. (1977) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(77)80143-5 · Cited by 293

Molybdenum, Molybdenum Oxides, and their Electrochemistry

Saji, V. S., & Lee, C. (2012) · ChemSusChem · doi:10.1002/cssc.201100660 · Cited by 291

Effects of process conditions and electrode material on reaction pathways for carbon dioxide electroreduction with particular reference to formate formation

Chaplin, R. P. S., & Wragg, A. A. (2003) · Journal of Applied Electrochemistry · doi:10.1023/b:jach.0000004018.57792.b8 · Cited by 290

Electrochemical Processing of Carbon Dioxide

Oloman, C. W., & Li, H. (2008) · ChemSusChem · doi:10.1002/cssc.200800015 · Cited by 288

Synthetic analogs of the active sites of iron-sulfur proteins. II. Synthesis and structure of the tetra[mercapto-.mu.3-sulfido-iron] clusters, [Fe4S4(SR)4]2-

Averill, B. A., Herskovitz, T., Holm, R. H., & Ibers, J. A. (1973) · Journal of the American Chemical Society · doi:10.1021/ja00792a013 · Cited by 277

Adsorption of CO accompanied with simultaneous charge transfer on copper single crystal electrodes related with electrochemical reduction of CO2 to hydrocarbons

Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1995) · Surface Science · doi:10.1016/0039-6028(95)00441-6 · Cited by 276

Organic molecules as mediators and catalysts for photocatalytic and electrocatalytic CO 2 reduction

Oh, Y., & Hu, X. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35276a · Cited by 273

A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential

Seshadri, G., Lin, C., & Bocarsly, A. B. (1994) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(94)03300-5 · Cited by 268

Cobalt Porphyrin Catalyzed Reduction of CO 2 . Radiation Chemical, Photochemical, and Electrochemical Studies

Behar, D., Dhanasekaran, T., Neta, P., Hosten, C. M., Ejeh, D., Hambright, P., & Fujita, E. (1998) · The Journal of Physical Chemistry A · doi:10.1021/jp9807017 · Cited by 264

Carbon Dioxide Recovery and Utilization

(2003) · Springer eBooks · doi:10.1007/978-94-017-0245-4 · Cited by 263

Photoelectrochemical pumping of enzymatic CO2 reduction

Parkinson, B. A., & Weaver, P. F. (1984) · Nature · doi:10.1038/309148a0 · Cited by 262

Electrochemical Reduction of Carbon Dioxide at Various Metal Electrodes in Aqueous Potassium Hydrogen Carbonate Solution

Noda, H., Ikeda, S., Oda, Y., IMAI, K., Maeda, M., & Ito, K. (1990) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.63.2459 · Cited by 257

Efficient electrosynthesis of highly active Cu3(BTC)2-MOF and its catalytic application to chemical reduction

Kumar, R., Kumar, S. S., & Kulandainathan, M. A. (2012) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2012.09.028 · Cited by 253

The Surface Trans Effect: Influence of Axial Ligands on the Surface Chemical Bonds of Adsorbed Metalloporphyrins

Hieringer, W., Flechtner, K., Kretschmann, A., Seufert, K., Auwärter, W., Barth, J. V., Görling, A., Steinrück, H., & Gottfried, J. M. (2011) · Journal of the American Chemical Society · doi:10.1021/ja1093502 · Cited by 243

Man-made Carbon Dioxide and the “Greenhouse” Effect

Sawyer, J. S. (1972) · Nature · doi:10.1038/239023a0 · Cited by 239

Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes

Chen, Z., Chen, C., Weinberg, D. R., Kang, P., Concepcion, J. J., Harrison, D. P., Brookhart, M., & Meyer, T. J. (2011) · Chemical Communications · doi:10.1039/c1cc15071e · Cited by 238

Reduction of Cobalt and Iron Corroles and Catalyzed Reduction of CO2

Grodkowski, J., Neta, P., Fujita, E., Mahammed, A., Simkhovich, L., & Gross, Z. (2002) · The Journal of Physical Chemistry A · doi:10.1021/jp013668o · Cited by 230

Electrochemical Reduction of Carbon Dioxide I. Effects of the Electrolyte on the Selectivity and Activity with Sn Electrode

Wu, J., Risalvato, F. G., Ke, F., Pellechia, P. J., & Zhou, X. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.049207jes · Cited by 223

Mechanism of the electrochemical reduction of carbon dioxide at inert electrodes in media of low proton availability

Gennaro, A., Isse, A. A., Severin, M.-G., Vianello, E., Bhugun, I., & Savéant, J. (1996) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9969203963 · Cited by 222

Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations

Bhugun, I., Lexa, D., & Savéant, J. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9618486 · Cited by 216

Electrochemical Reduction of Carbon Dioxide at a Platinum Electrode in Acetonitrile-Water Mixtures

Tomita, Y., Teruya, S., Koga, O., & Hori, Y. (2000) · Journal of The Electrochemical Society · doi:10.1149/1.1394035 · Cited by 216

Electrochemical Reduction of CO2 Catalyzed by Small Organophosphine Dendrimers Containing Palladium

Miedaner, A., Curtis, C. J., Barkley, R. M., & DuBois, D. L. (1994) · Inorganic Chemistry · doi:10.1021/ic00102a022 · Cited by 215

Enhanced formation of ethylene and alcohols at ambient temperature and pressure in electrochemical reduction of carbon dioxide at a copper electrode

Hori, Y., Murata, A., Takahashi, R., & Suzuki, S. (1988) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39880000017 · Cited by 214

Electrochemical reduction of CO2 on RuO2/TiO2 nanotubes composite modified Pt electrode

Jian-ping, Q., Zhang, X., Wang, Y., & Xie, C. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2004.11.061 · Cited by 213

Rapid and Efficient Electrocatalytic CO2/CO Interconversions by Carboxydothermus hydrogenoformans CO Dehydrogenase I on an Electrode

Parkin, A., Seravalli, J., Vincent, K. A., Ragsdale, S. W., & Armstrong, F. A. (2007) · Journal of the American Chemical Society · doi:10.1021/ja073643o · Cited by 213

Electrochemical reduction of CO2 at copper single crystal Cu(S)-[n(111)×(111)] and Cu(S)-[n(110)×(100)] electrodes

Takahashi, I., Koga, O., Hoshi, N., & Hori, Y. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)01081-1 · Cited by 212

Electrocatalytic reduction of carbon dioxide by 2,2'-bipyridine complexes of rhodium and iridium

Bolinger, C. M., Story, N., Sullivan, B. P., & Meyer, T. J. (1988) · Inorganic Chemistry · doi:10.1021/ic00298a016 · Cited by 212

Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst

Bhugun, I., Lexa, D., & Savéant, J. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00090a068 · Cited by 200

Kinetic studies of the electrolytic reduction of carbon dioxide on the mercury electrode

Paik, W., Andersen, T. N., & Eyring, H. B. (1969) · Electrochimica Acta · doi:10.1016/0013-4686(69)87019-2 · Cited by 197

Electrocatalytic conversion of CO2 to long carbon-chain hydrocarbons

Centi, G., Perathoner, S., Win, G., & Gangeri, M. (2007) · Green Chemistry · doi:10.1039/b615275a · Cited by 197

Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO 2 Reduction Using “Smart” Electrodes

Yao, S. A., Ruther, R. E., Zhang, L., Franking, R. A., Hamers, R. J., & Berry, J. F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja304783j · Cited by 197

Electroreduction of Carbon Dioxide on Copper-Based Electrodes: Activity of Copper Single Crystals and Copper–Gold Alloys

Christophe, J., Doneux, T., & Buess‐Herman, C. (2012) · Electrocatalysis · doi:10.1007/s12678-012-0095-0 · Cited by 195

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO

Schneider, J. D., Jia, H., Kobiro, K., Cabelli, D. E., Muckerman, J. T., & Fujita, E. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22528j · Cited by 195

Design of Alloy Electrocatalysts for CO 2 Reduction: III . The Selective and Reversible Reduction of on Cu Alloy Electrodes

Watanabe, M., Shibata, M., Kato, A., Azuma, M., & Sakata, T. (1991) · Journal of The Electrochemical Society · doi:10.1149/1.2085417 · Cited by 194

Formation of a metal-hydride bond and the insertion of carbon dioxide. Key steps in the electrocatalytic reduction of carbon dioxide to formate anion

Pugh, J. R., Bruce, M. R. M., Sullivan, B. P., & Meyer, T. J. (1991) · Inorganic Chemistry · doi:10.1021/ic00001a016 · Cited by 191

Electrochemical reduction of carbon dioxide catalyzed by [Pd(triphosphine)(solvent)](BF4)2 complexes: synthetic and mechanistic studies

DuBois, D. L., Miedaner, A., & Haltiwanger, R. C. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00023a023 · Cited by 189

Electro-reduction of carbon dioxide to formate on lead electrode in aqueous medium

Innocent, B., Liaigre, D., Pasquier, D., Ropital, F., ́GER, J.-M. L., & Kokoh, K. B. (2008) · Journal of Applied Electrochemistry · doi:10.1007/s10800-008-9658-4 · Cited by 187

High Rate Gas Phase CO 2 Reduction to Ethylene and Methane Using Gas Diffusion Electrodes

Cook, R. L., MacDuff, R. C., & Sammells, A. F. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086515 · Cited by 183

Reduction of CO2 and CO to methane on Cu foil electrodes

Kim, J. J., Summers, D. P., & Frese, K. W. (1988) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(88)80071-8 · Cited by 182

4-Vinyl-, 6-vinyl-, and 4'-vinyl-2,2':6',2"-terpyridinyl ligands: their synthesis and the electrochemistry of their transition-metal coordination complexes

POTTS, K. T., Usifer, D. A., Guadalupe, A. R., & Abruña, H. D. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00247a021 · Cited by 181

Electrochemicaland electrocatalytic reactions of carbon dioxide

Lintz, H. ‐. (1993) · Applied Catalysis A General · doi:10.1016/0926-860x(93)85112-3 · Cited by 180

Electrochemical reduction of high pressure CO2 at Pb, Hg and In electrodes in an aqueous KHCO3 solution

Todoroki, M., Hara, K., Kudo, A., & Sakata, T. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)04010-l · Cited by 178

Electrochemical reduction of CO2 over Sn-Nafion® coated electrode for a fuel-cell-like device

Prakash, G. K. S., Viva, F. A., & Olah, G. A. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.09.036 · Cited by 176

Multi-electron reduction of CO2 via RuCO2, C(O)OH, CO, CHO, and CH2OH species

Tanaka, K., & Ooyama, D. (2002) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(01)00434-9 · Cited by 174

Synthesis of solar fuels by a novel photoelectrocatalytic approach

Ampelli, C., Centi, G., Passalacqua, R., & Perathoner, S. (2010) · Energy & Environmental Science · doi:10.1039/b925470f · Cited by 174

Carbon Dioxide Reduction at a Metal Phthalocyanine Catalyzed Carbon Electrode

Kapusta, S., & Hackerman, N. (1984) · Journal of The Electrochemical Society · doi:10.1149/1.2115882 · Cited by 169

Mechanism of Homogeneous Reduction of CO2 by Pyridine: Proton Relay in Aqueous Solvent and Aromatic Stabilization

Lim, C., Holder, A. M., & Musgrave, C. B. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3064809 · Cited by 167

Structural investigations into the deactivation pathway of the CO2 reduction electrocatalyst Re(bpy)(CO)3Cl

Benson, E. E., & Kubiak, C. P. (2012) · Chemical Communications · doi:10.1039/c2cc32617e · Cited by 164

Electrocatalysis of CO2 Reduction in Aqueous Media at Electrodes Modified with Electropolymerized Films of Vinylterpyridine Complexes of Transition Metals

Sende, J. A. R., Arana, C. R., Hernandez, L., POTTS, K. T., Keshevarz-K, M., & Abruña, H. D. (1995) · Inorganic Chemistry · doi:10.1021/ic00116a028 · Cited by 163

A Surface Enhanced Roman Scattering Study of the Intermediate and Poisoning Species Formed during the Electrochemical Reduction of CO 2 on Copper

Smith, B. D., Irish, D. E., Kedzierzawski, P., & Augustyński, J. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1838180 · Cited by 162

Electrocatalytic Reduction of Carbon Dioxide with Mono(bipyridine)carbonylruthenium Complexes in Solution or as Polymeric Thin Films

Collomb, M., Deronzier, A., & Ziessel, R. (1994) · Inorganic Chemistry · doi:10.1021/ic00091a040 · Cited by 158

Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines

Furuya, N., & Matsui, K. (1989) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(89)80074-9 · Cited by 157

Electrocatalytic pathways towards sustainable fuel production from water and CO2

Inglis, J., MacLean, B. J., Pryce, M. T., & Vos, J. G. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.05.002 · Cited by 156

Electrochemical Reduction of Carbon Dioxide to Methane, Methanol, and CO on Ru Electrodes

Frese, K. W., & Leach, S. C. (1985) · Journal of The Electrochemical Society · doi:10.1149/1.2113780 · Cited by 155

Functional Role of Pyridinium during Aqueous Electrochemical Reduction of CO2 on Pt(111)

Ertem, M. Z., Konezny, S. J., Araujo, C. M., & Batista, V. S. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400183z · Cited by 154

Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides

Yano, H., Tanaka, T., Nakayama, M., & Ogura, K. (2003) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2003.10.021 · Cited by 153

The Electroreduction of Carbon Dioxide and Formic Acid on Tin and Indium Electrodes

Kapusta, S., & Hackerman, N. (1983) · Journal of The Electrochemical Society · doi:10.1149/1.2119761 · Cited by 153

Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex

Raebiger, J. W., Turner, J. W., Noll, B. C., Curtis, C. J., Miedaner, A., Cox, B., & DuBois, D. L. (2006) · Organometallics · doi:10.1021/om060228g · Cited by 152

Electrochemical Reduction of Carbon Dioxide in an MFC–MEC System with a Layer-by-Layer Self-Assembly Carbon Nanotube/Cobalt Phthalocyanine Modified Electrode

Zhao, H., Zhang, Y., Zhao, B., Chang, Y., & Li, Z. (2012) · Environmental Science & Technology · doi:10.1021/es300186f · Cited by 152

The electrochemical reduction of aqueous carbon dioxide to methanol at molybdenum electrodes with low overpotentials

Summers, D. P., Leach, S. C., & Frese, K. W. (1986) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(86)90233-0 · Cited by 151

Development of a continuous reactor for the electro-reduction of carbon dioxide to formate – Part 2: Scale-up

Li, H., & Oloman, C. W. (2007) · Journal of Applied Electrochemistry · doi:10.1007/s10800-007-9371-8 · Cited by 151

Electrochemical conversion of carbon dioxide to methanol with the assistance of formate dehydrogenase and methanol dehydrogenase as biocatalysts

Kuwabata, S., Tsuda, R., & Hiroshi Yoneyama, C. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00091a056 · Cited by 151

The Electro-Reduction of Carbon Dioxide in a Continuous Reactor

Li, H., & Oloman, C. W. (2005) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-7173-4 · Cited by 147

Cobalt−Porphyrin Catalyzed Electrochemical Reduction of Carbon Dioxide in Water. 2. Mechanism from First Principles

Leung, K., Nielsen, I. M. B., Sai, N., Medforth, C. J., & Shelnutt, J. A. (2010) · The Journal of Physical Chemistry A · doi:10.1021/jp1012335 · Cited by 147

Electrocatalytic activity of Cu electrode in electroreduction of CO2

Lee, J., & Tak, Y. (2001) · Electrochimica Acta · doi:10.1016/s0013-4686(01)00527-8 · Cited by 146

CO2 attraction by specifically adsorbed anions and subsequent accelerated electrochemical reduction

Ogura, K., Ferrell, J. R., Cugini, A. V., Smotkin, E. S., & Salazar-Villalpando, M. D. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.08.065 · Cited by 146

Chemical Fixation of Carbon DioxideMethods for Recycling CO2 into Useful Products

Halmann, M. M. (2018) · CRC Press eBooks · doi:10.1201/9781315139098 · Cited by 146

Electrochemical Conversion of Carbon Dioxide to Formate in Alkaline Polymer Electrolyte Membrane Cells

Narayanan, S. R., Haines, B., Soler, J., & Valdez, T. I. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3526312 · Cited by 145

Nickel N-heterocyclic carbene–pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water

Thoi, V. S., & Chang, C. J. (2011) · Chemical Communications · doi:10.1039/c1cc10449g · Cited by 143

Electrocatalytic reduction of carbon dioxide with iron, cobalt, and nickel complexes of terdentate ligands

Arana, C. R., Yan, S., Keshavarz-K, M., POTTS, K. T., & Abruña, H. D. (1992) · Inorganic Chemistry · doi:10.1021/ic00043a034 · Cited by 141

Mo and W bis-MGD enzymes: nitrate reductases and formate dehydrogenases

Moura, J. J. G., Brondino, C. D., Trinc�o, J., & Rom�o, M. J. (2004) · JBIC Journal of Biological Inorganic Chemistry · doi:10.1007/s00775-004-0573-9 · Cited by 141

Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution

Hori, Y., & Suzuki, S. (1982) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.55.660 · Cited by 140

Selective electroacatalysis for CO2 reduction in the aqueous phase using cobalt phthalocyanine/poly-4-vinylpyridine modified electrodes

Yoshida, T., Kamato, K., Tsukamoto, M., Takeaki, I. I. D. A., Schlettwein, D., Wöhrle, D., & Kaneko, M. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(94)03762-r · Cited by 140

Electrochemical reduction of carbon dioxide catalyzed by Rh(diphos)2Cl

Slater, S. J. E., & Wagenknecht, J. H. (1984) · Journal of the American Chemical Society · doi:10.1021/ja00330a064 · Cited by 140

Cu3(BTC)2: CO oxidation over MOF based catalysts

Ye, J., & Liu, C. (2011) · Chemical Communications · doi:10.1039/c0cc04944a · Cited by 139

Acceleration of the reduction of carbon dioxide in the presence of multivalent cations

Schizodimou, A., & Kyriacou, G. (2012) · Electrochimica Acta · doi:10.1016/j.electacta.2012.05.118 · Cited by 138

Electrocatalysis of CO2 reduction at surface modified metallic and semiconducting electrodes

Cabrera, C. R., & Abruña, H. D. (1986) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(86)80189-9 · Cited by 134

Factors affecting selective electrocatalytic co2 reduction with cobalt phthalocyanine incorporated in a polyvinylpyridine membrane coated on a graphite electrode

Abe, T., Yoshida, T., Tokita, S., Taguchi, F., Imaya, H., & Kaneko, M. (1996) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(96)04631-1 · Cited by 133

Electrocatalytic reduction of CO2 at a chemically modified electrode

O’Toole, T. R., Margerum, L. D., Westmoreland, T. D., Vining, W. J., Murray, R. W., & Meyer, T. J. (1985) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39850001416 · Cited by 132

Reduction of Carbon Dioxide to Methanol on n ‐ and p ‐ GaAs and p ‐ InP . Effect of Crystal Face, Electrolyte and Current Density

Canfield, D., & Frese, K. W. (1983) · Journal of The Electrochemical Society · doi:10.1149/1.2120090 · Cited by 130

Macrocyclic [N42-] Coordinated Nickel Complexes as Catalysts for the Formation of Oxalate by Electrochemical Reduction of Carbon Dioxide

Rudolph, M., Dautz, S., & Jäger, E. ‐. (2000) · Journal of the American Chemical Society · doi:10.1021/ja001254n · Cited by 129

Electrochemical reduction of CO2 at metal-porphyrin supported gas diffusion electrodes under high pressure CO2

Sonoyama, N., Kirii, M., & Sakata, T. (1999) · Electrochemistry Communications · doi:10.1016/s1388-2481(99)00041-7 · Cited by 127

Development of a continuous reactor for the electro-reduction of carbon dioxide to formate – Part 1: Process variables

Li, H., & Oloman, C. W. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-006-9194-z · Cited by 127

Electrochemical reduction of carbon dioxide to ethylene with high Faradaic efficiency at a Cu electrode in CsOH/methanol

Kaneco, S., Iiba, K., Hiei, N.-H., Ohta, K., Mizuno, T., & Suzuki, T. (1999) · Electrochimica Acta · doi:10.1016/s0013-4686(99)00262-5 · Cited by 126

Electrochemical reduction of CO2 in methanol with aid of CuO and Cu2O

Ohya, S., Kaneco, S., Katsumata, H., Suzuki, T., & Ohta, K. (2009) · Catalysis Today · doi:10.1016/j.cattod.2009.07.077 · Cited by 126

Electrochemical Reduction of Carbon Dioxide on Conductive Metallic Oxides

Bandi, A. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086903 · Cited by 125

Homogeneous Electron Transfer Catalysis of the Electrochemical Reduction of Carbon Dioxide. Do Aromatic Anion Radicals React in an Outer-Sphere Manner?

Gennaro, A., Isse, A. A., Savéant, J., Severin, M.-G., & Vianello, E. (1996) · Journal of the American Chemical Society · doi:10.1021/ja960605o · Cited by 124

Electrocatalytic reduction of CO2 by a complex of rhenium in thin polymeric films

O’Toole, T. R., Sullivan, B. P., Bruce, M. R. M., Margerum, L. D., Murray, R. W., & Meyer, T. J. (1989) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(89)80049-x · Cited by 123

Electrocatalytic Reduction of Carbon Dioxide by the Binuclear Copper Complex [Cu2(6-(diphenylphosphino-2,2'-bipyridyl)2(MeCN)2][PF6]2

Haines, R. J., Wittrig, R. E., & Kubiak, C. P. (1994) · Inorganic Chemistry · doi:10.1021/ic00099a024 · Cited by 122

Influence CO2 partial pressure and the supporting electrolyte cation on the product distribution in CO2 electroreduction

Kyriacou, G., & Anagnostopoulos, A. (1993) · Journal of Applied Electrochemistry · doi:10.1007/bf00707626 · Cited by 121

Directing the Reactivity of [HFe 4 N(CO) 12 ] − toward H + or CO 2 Reduction by Understanding the Electrocatalytic Mechanism

Rail, M. D., & Berben, L. A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja208312t · Cited by 121

Electrochemical Reduction of High Pressure CO 2 on Ni Electrodes

Kudo, A., Nakagawa, S., Tsuneto, A., & Sakata, T. (1993) · Journal of The Electrochemical Society · doi:10.1149/1.2221599 · Cited by 120

Dinuclear Nickel Complexes as Catalysts for Electrochemical Reduction of Carbon Dioxide

Simón-Manso, E., & Kubiak, C. P. (2004) · Organometallics · doi:10.1021/om0494723 · Cited by 120

Reduction of carbon dioxide to methane and ethene—an on-line MS study with rotating electrodes

Wasmus, S., Cattaneo, E., & Vielstich, W. (1990) · Electrochimica Acta · doi:10.1016/0013-4686(90)90014-q · Cited by 120

Electrochemical Reduction of CO2 to Methane at the Cu Electrode in Methanol with Sodium Supporting Salts and Its Comparison with Other Alkaline Salts

Kaneco, S., Katsumata, H., Suzuki, T., & Ohta, K. (2005) · Energy & Fuels · doi:10.1021/ef050274d · Cited by 118

Electrochemical reactivities of pyridinium in solution: consequences for CO2 reduction mechanisms

Keith, J. A., & Carter, E. A. (2013) · Chemical Science · doi:10.1039/c3sc22296a · Cited by 118

Electrochemical Synthesis of Urea at Gas‐Diffusion Electrodes: IV. Simultaneous Reduction of Carbon Dioxide and Nitrate Ions with Various Metal Catalysts

Shibata, M., Yoshida, K., & Furuya, N. (1998) · Journal of The Electrochemical Society · doi:10.1149/1.1838641 · Cited by 118

Highly Selective Electrocatalytic Conversion of CO2 to CO at −0.57 V (NHE) by Carbon Monoxide Dehydrogenase from Moorella thermoacetica

Shin, W., Lee, S. H., Shin, J. W., Lee, S. P., & Kim, Y. (2003) · Journal of the American Chemical Society · doi:10.1021/ja037370i · Cited by 118

Electrochemical reduction of CO2 by Cu2O-catalyzed carbon clothes

Chang, T.-Y., Liang, R.-M., Wu, P., Chen, J.-Y., & Hsieh, Y.-C. (2009) · Materials Letters · doi:10.1016/j.matlet.2009.01.067 · Cited by 117

Electrocatalytic reduction of CO2 based on polypyridyl complexes of rhodium and ruthenium

Bolinger, C. M., Sullivan, B. P., Conrad, D. W., Gilbert, J. A., Story, N., & Meyer, T. J. (1985) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39850000796 · Cited by 116

Two W‐containing formate dehydrogenases (CO2‐reductases) involved in syntrophic propionate oxidation by Syntrophobacter fumaroxidans

de Bok, F. A. M., Hagedoorn, P., Silva, P. J., Hagen, W. R., Schiltz, E., Fritsche, K., & Stams, A. J. M. (2003) · European Journal of Biochemistry · doi:10.1046/j.1432-1033.2003.03619.x · Cited by 116

Electroreduction of CO2 on differently prepared copper electrodes

Kyriacou, G., & Anagnostopoulos, A. N. (1992) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(92)80079-j · Cited by 115

Electrochemistry of carbon dioxide in dimethyl sulfoxide at gold and mercury electrodes

Haynes, L. V., & Sawyer, D. T. (1967) · Analytical Chemistry · doi:10.1021/ac60247a013 · Cited by 115

Electrochemical coating of a platinum electrode by a poly(pyrrole) film containing the fac-Re(2,2′-bipyridine)(CO)3Cl system application to electrocatalytic reduction of CO2

Cosnier, S., Deronzier, A., & Moutet, J. (1986) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(86)87080-2 · Cited by 115

The effect of weak Brönsted acids on the electrocatalytic reduction of carbon dioxide by a rhenium tricarbonyl bipyridyl complex

Wong, K., Chung, W.-H., & Lau, C. P. (1998) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(98)00116-8 · Cited by 114

Selective formation of HCOO – in the electrochemical CO 2 reduction catalysed by [Ru(bpy) 2 (CO) 2 ] 2+ (bpy = 2,2′-bipyridine)

Ishida, H., Tanaka, H., Tanaka, K., & Tanaka, T. (1987) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39870000131 · Cited by 114

Mediated electrochemical reduction of CO2. Preparation and comparison of an isoelectronic series of complexes

DuBois, D. L., & Miedaner, A. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00235a019 · Cited by 113

Fe and Pt carbon nanotubes for the electrocatalytic conversion of carbon dioxide to oxygenates

Gangeri, M., Perathoner, S., Caudo, S., Centi, G., Amadou, J., Bégin, D., Pham-Huu, C., Ledoux, M. J., Tessonnier, J.-P., & Su, D. S. (2009) · Catalysis Today · doi:10.1016/j.cattod.2008.11.001 · Cited by 112

On the Electrochemical Reduction of Carbon Dioxide at In Situ Electrodeposited Copper

Cook, R. L., MacDuff, R. C., & Sammells, A. F. (1988) · Journal of The Electrochemical Society · doi:10.1149/1.2095972 · Cited by 110

Novel chemical pathways and charge-transport dynamics of electrodes modified with electropolymerized layers of [Co(v-terpy)2]2+

Guadalupe, A. R., Usifer, D. A., POTTS, K. T., Hurrell, H. C., MOGSTAD, A. ‐., & Abruña, H. D. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00219a020 · Cited by 110

Reduction of CO2 under high pressure and high temperature on Pb-granule electrodes in a fixed-bed reactor in aqueous medium

Köleli, F., & Kayan, D. B. (2004) · Applied Catalysis A General · doi:10.1016/j.apcata.2004.07.006 · Cited by 109

Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte

Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223

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Chu, S., Cui, Y., & Liu, N. (2016) · Nature Materials · doi:10.1038/nmat4834 · Cited by 4,826

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De Luna, P., Hahn, C., Higgins, D., Jaffer, S. A., Jaramillo, T. F., & Sargent, E. H. (2019) · Science · doi:10.1126/science.aav3506 · Cited by 3,052

Cocatalysts for Selective Photoreduction of CO 2 into Solar Fuels

Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,321

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Jin, H., Guo, C., Liu, X., Liu, J., Vasileff, A., Jiao, Y., Zheng, Y., & Qiao, S. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00689 · Cited by 2,039

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