Electrochemical generation of syngas from water and carbon dioxide at industrially important rates
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Increasing the PTFE content of the microporous layer can prevent flooding but comes at the expense of electrical conductivity and gas permeability.
“To prevent flooding, especially in liquid phase electrolyzers, the PTFE content of the microporous layer can be increased at the expense of electrical conductivity and gas permeability.[178]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [178]
Kim et al. found notably higher current densities towards CO formation at a fixed cell voltage when using a thin, 60 μm macroporous substrate in a liquid phase CO2 electrolyzer.
“Using a liquid phase CO2 electrolyzer, Kim et al. studied the effect of macroporous substrate thickness where notably higher current densities towards CO formation were achieved at a fixed cell voltage when using a thin, 60 µm substrate.[178]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [178]
Kim et al. obtained the highest currents for CO production using a PTFE loading of 20% at the same cell voltage.
“while Kim et al. obtained the highest currents for CO production using a PTFE loading of 20% at the same cell voltage.[178]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [178]
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- Authors
- Liu, Z., Masel, R. I., Chen, Q., Kutz, R., Yang, H., Lewinski, K., Kaplun, M., Luopa, S., & Lutz, D. R.
- Affiliations
- Dioxide Materials (United States) (US)
- 3M (United States) (US)
- Corresponding author
- Lutz, Dale R.
- Venue
- Journal of CO2 Utilization
- Publisher
- Elsevier BV
- Published
- 2016-09
- Volume
- 15
- Pages
- 50-56
- ISSN
- 2212-9820 (ISSN-L)
- OpenAlex
- W2346867913
- Cited by
- 93
- References
- 62
- Citations by year
- 2026: 5 · 2025: 5 · 2024: 6 · 2023: 9 · 2022: 13 · 2021: 10 · 2020: 15 · 2019: 15 · 2018: 7 · 2017: 6 · 2016: 2
- FWCI
- 2.72
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Journal of CO2 Utilization (acceptedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- U.S. Air Force (FA8650-14-C-2417, DE-AR0000345, NNX12CE73P, DE-SC0004192, DE-SC0007471)
- ARPA-E
- NASA
- DOE
- 3M Company
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- syngas production, electrochemical CO2 reduction, water electrolysis, co-electrolysis, CO2 utilization, renewable energy, electrolyzer stability, turnover frequency
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