Cited by 2,990CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingCarbon dioxide utilization in catalysis

The DOI matches its Crossref record; 390 of the 391 references it cites were found in a registry or an index.

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Qiao, Jinli, Liu, Yuyu, Hong, Feng, Zhang, Jiujun·2014·Chem. Soc. Rev.

DOI 10.1039/c3cs60323g

Open this paper in CoChat — free account

Abstract

This paper reviews recent progress made in identifying electrocatalysts for carbon dioxide (CO2) reduction to produce low-carbon fuels, including CO, HCOOH/HCOO(-), CH2O, CH4, H2C2O4/HC2O4(-), C2H4, CH3OH, CH3CH2OH and others. The electrocatalysts are classified into several categories, including metals, metal alloys, metal oxides, metal complexes, polymers/clusters, enzymes and organic molecules. The catalyts' activity, product selectivity, Faradaic efficiency, catalytic stability and reduction mechanisms during CO2 electroreduction have received detailed treatment. In particular, we review the effects of electrode potential, solution-electrolyte type and composition, temperature, pressure, and other conditions on these catalyst properties. The challenges in achieving highly active and stable CO2 reduction electrocatalysts are analyzed, and several research directions for practical applications are proposed, with the aim of mitigating performance degradation, overcoming additional challenges, and facilitating research and development in this area.

Integrity signals

Registry

Crossref · 10.1039/c3cs60323g

Cites

390 of 390 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

We couldn’t retrieve this paper’s full text, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Li, H., Eddaoudi, M., O’Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,582
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Eddaoudi, M., Kim, J., Rosi, N. L., Vodak, D. T., Wachter, J., O’Keeffe, M., & Yaghi, O. M. (2002) · Science · doi:10.1126/science.1067208 · Cited by 8,228
TiO2 photocatalysis and related surface phenomena
FUJISHIMA, A., ZHANG, X., & TRYK, D. (2008) · Surface Science Reports · doi:10.1016/j.surfrep.2008.10.001 · Cited by 6,737
A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n
Chui, S. S.-Y., Lo, S. M. F., Charmant, J. P. H., Orpen, A. G., & Williams, I. D. (1999) · Science · doi:10.1126/science.283.5405.1148 · Cited by 6,071
Transformation of Carbon Dioxide
Sakakura, T., Choi, J., & Yasuda, H. Y. (2007) · Chemical Reviews · doi:10.1021/cr068357u · Cited by 3,891
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
A route to high surface area, porosity and inclusion of large molecules in crystals
Materials Design and Discovery Group, Chae, H. K., Siberio-Pérez, D. Y., Kim, J., Go, Y., Eddaoudi, M., Matzger, A. J., O’Keeffe, M., & Yaghi, O. M. (2004) · Nature · doi:10.1038/nature02311 · Cited by 2,817
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2008) · Chemical Society Reviews · doi:10.1039/b804323j · Cited by 2,061
CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000

Show all 391 references

Research works printed but not linked: 7

Nakayama, 1997, J. Electroanal. Chem., 440, 251
Hori, 1998, Abstr. Pap. Am. Chem. Soc., 215, U405
Cheng, 1996, Inorg. Chem., 35, 7704, 10.1021/ic9512385 · DOI
Haines, 1994, Inorg. Chem., 33, 4723, 10.1021/ic00099a024 · DOI
Royer, 1870, Compt. Rend., 731
Senthil Kumar, 2012, Electrochem. Commun., 25, 70, 10.1016/j.elecom.2012.09.018 · DOI
Beley, 1984, J. Chem. Soc., Chem. Commun., 1315, 10.1039/c39840001315 · DOI

Sorted by citations

Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
The path towards sustainable energy
Chu, S., Cui, Y., & Liu, N. (2016) · Nature Materials · doi:10.1038/nmat4834 · Cited by 4,826
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
De Luna, P., Hahn, C., Higgins, D., Jaffer, S. A., Jaramillo, T. F., & Sargent, E. H. (2019) · Science · doi:10.1126/science.aav3506 · Cited by 3,052
Cocatalysts for Selective Photoreduction of CO 2 into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,321
Emerging Two-Dimensional Nanomaterials for Electrocatalysis
Jin, H., Guo, C., Liu, X., Liu, J., Vasileff, A., Jiao, Y., Zheng, Y., & Qiao, S. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00689 · Cited by 2,039
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Perovskites in catalysis and electrocatalysis
Hwang, J., Rao, R. R., Giordano, L., Katayama, Y., Yu, Y., & Shao‐Horn, Y. (2017) · Science · doi:10.1126/science.aam7092 · Cited by 1,817
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
White, J. L., Baruch, M. F., Pander, J. E., Hu, Y., Fortmeyer, I. C., Park, J. E., Zhang, T., Liao, K., Gu, J. H., Yan, Y. S., et al. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00370 · Cited by 1,698
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis
Jiang, X., Nie, X., Guo, X., Song, C., & Chen, J. G. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00723 · Cited by 1,596
Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C-C coupling over fluorine-modified copper
Ma, W., Xie, S., Liu, T., Fan, Q., Ye, J., Sun, F., Jiang, Z., Zhang, Q., Cheng, J., & Wang, Y. (2020) · Nature Catalysis · doi:10.1038/s41929-020-0450-0 · Cited by 1,468
Catalytic reduction of CO 2 by H 2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities
Porosoff, M. D., Yan, B., & Chen, J. G. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02657a · Cited by 1,370
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Plasma technology – a novel solution for CO 2 conversion?
Snoeckx, R., & Bogaerts, A. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00066e · Cited by 1,302
Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface
Kattel, S. P., Liu, P., & Chen, J. G. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05362 · Cited by 1,283
A review of mineral carbonation technologies to sequester CO 2
Sanna, A., Uibu, M., Caramanna, G., Kuusik, R., & Maroto-Valer, M. M. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00035h · Cited by 1,258
Metal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y., Zhang, M., Zou, R., & Xü, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,243
Covalent organic frameworks (COFs) for electrochemical applications
Zhao, X., Pachfule, P., & Thomas, A. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01569e · Cited by 1,199
Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts
Francke, R., Schille, B., & Roemelt, M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00459 · Cited by 1,195
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08212 · Cited by 1,174
Bulk COFs and COF nanosheets for electrochemical energy storage and conversion
Li, J., Jing, X., Li, Q., Li, S., Gao, X., Feng, X., & Wang, B. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00017e · Cited by 1,155
Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles
Gao, D., Zhou, H., Wang, J., Miao, S., Yang, F., Wang, G., Wang, J., & Bao, X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00046 · Cited by 1,107
Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products
Möhle, S., Zirbes, M., Rodrigo, E., Gieshoff, T., Wiebe, A., & Waldvogel, S. R. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712732 · Cited by 1,115
Electrolytic CO2 Reduction in a Flow Cell
Weekes, D. M., Salvatore, D. A., Reyes, A., Huang, A., & Berlinguette, C. P. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00010 · Cited by 1,098
Nanostructured Materials for Heterogeneous Electrocatalytic CO2 Reduction and their Related Reaction Mechanisms
Zhang, L., Zhao, Z., & Gong, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612214 · Cited by 1,048
Visible-light-driven methane formation from CO2 with a molecular iron catalyst
Rao, H., Schmidt, L. C., Bonin, J., & Robert, M. (2017) · Nature · doi:10.1038/nature23016 · Cited by 1,062
Noble metal–metal oxide nanohybrids with tailored nanostructures for efficient solar energy conversion, photocatalysis and environmental remediation
Liu, X., Iocozzia, J., Wang, Y., Cui, X., Chen, Y., Zhao, S., Li, Z., & Lin, Z. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02265k · Cited by 1,034
High-entropy energy materials: challenges and new opportunities
Ma, Y., Ma, Y., Wang, Q., Schweidler, S., Botros, M., Fu, T., Hahn, H., Brezesinski, T., & Breitung, B. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00505g · Cited by 963
Progress and Perspective of Electrocatalytic CO 2 Reduction for Renewable Carbonaceous Fuels and Chemicals
Zhang, W., Hu, Y. T., Ma, L., Zhu, G., Wang, Y., Xue, X., Chen, R., Yang, S., & Jin, Z. (2017) · Advanced Science · doi:10.1002/advs.201700275 · Cited by 973
Heteroatom-Doped Graphene-Based Materials for Energy-Relevant Electrocatalytic Processes
Duan, J., Chen, S., Jaroniec, M., & Qiao, S. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00991 · Cited by 949
CO 2 Reduction: From the Electrochemical to Photochemical Approach
Wu, J., Huang, Y., Ye, W., & Li, Y. (2017) · Advanced Science · doi:10.1002/advs.201700194 · Cited by 958
Exclusive Ni–N4 Sites Realize Near-Unity CO Selectivity for Electrochemical CO2 Reduction
Li, X., Bi, W., Chen, M., Sun, Y., Ju, H., Yan, W., Zhu, J., Wu, X., Chu, W., Wu, C., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b09074 · Cited by 942
Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate
Han, N., Wang, Y., Yang, H., Deng, J., Wu, J., Li, Y., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03712-z · Cited by 924
Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures
Zhang, X., Wu, Z., Zhang, X., Li, L., Li, Y., Xu, H., Li, X., Yu, X., Zhang, Z., Liang, Y., et al. (2017) · Nature Communications · doi:10.1038/ncomms14675 · Cited by 932
Core–shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO 2
Das, S., Pérez‐Ramírez, J., Gong, J., Dewangan, N., Hidajat, K., Gates, B. C., & Kawi, S. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00713j · Cited by 893
Direct Observation on Reaction Intermediates and the Role of Bicarbonate Anions in CO 2 Electrochemical Reduction Reaction on Cu Surfaces
Zhu, S., Jiang, B., Cai, W., & Shao, M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10462 · Cited by 861
Low-dimensional catalysts for hydrogen evolution and CO2 reduction
Voiry, D., Shin, H. S., Loh, K. P., & Chhowalla, M. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-017-0105 · Cited by 861
Bio-inspired hydrophobicity promotes CO2 reduction on a Cu surface
Wakerley, D., Lamaison, S., Ozanam, F., Menguy, N., Mercier, D., Marcus, P., Fontecave, M., & Mougel, V. (2019) · Nature Materials · doi:10.1038/s41563-019-0445-x · Cited by 879
CO 2 -fixation into cyclic and polymeric carbonates: principles and applications
Kamphuis, A. J., Picchioni, F., & Pescarmona, P. P. (2019) · Green Chemistry · doi:10.1039/c8gc03086c · Cited by 848
Co-electrolysis of CO2 and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption
Verma, S., Lu, S., & Kenis, P. J. A. (2019) · Nature Energy · doi:10.1038/s41560-019-0374-6 · Cited by 844
The Green ChemisTREE: 20 years after taking root with the 12 principles
Erythropel, H. C., Zimmerman, J. B., de Winter, T. M., Petitjean, L., Melnikov, F., Lam, J. C., Lounsbury, A. W., Mellor, K. E., Janković, N. Z., Tu, Q., et al. (2018) · Green Chemistry · doi:10.1039/c8gc00482j · Cited by 848
Toward Active-Site Tailoring in Heterogeneous Catalysis by Atomically Precise Metal Nanoclusters with Crystallographic Structures
Jin, R. M., Li, G., Sharma, S., Li, Y., & Du, X. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00495 · Cited by 812
A review of high temperature co-electrolysis of H 2 O and CO 2 to produce sustainable fuels using solid oxide electrolysis cells (SOECs): advanced materials and technology
Zheng, Y. H., Wang, J., Yu, B. H., Zhang, W., Chen, J., Qiao, J., & Zhang, J. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00403b · Cited by 789
Self-citation
Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst
Morales‐Guio, C. G., Cave, E. R., Nitopi, S. A., Feaster, J. T., Wang, L., Kuhl, K. P., Jackson, A., Johnson, N. C., Abram, D. N., Hatsukade, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0139-9 · Cited by 790
Polymer photocatalysts for solar-to-chemical energy conversion
Banerjee, T., Podjaski, F., Kröger, J., Biswal, B. P., & Lotsch, B. V. (2020) · Nature Reviews Materials · doi:10.1038/s41578-020-00254-z · Cited by 779
Metal‐Free Carbon Materials for CO2 Electrochemical Reduction
Duan, X., Xu, J., Wei, Z., Ma, J., Guo, S., Wang, S., Liu, H., & Dou, S. (2017) · Advanced Materials · doi:10.1002/adma.201701784 · Cited by 754
Molecular enhancement of heterogeneous CO2 reduction
Nam, D., Luna, P. D., Rosas‐Hernández, A., Thevenon, A., Li, F., Agapie, T., Peters, J. C., Shekhah, O., Eddaoudi, M., & Sargent, E. H. (2020) · Nature Materials · doi:10.1038/s41563-020-0610-2 · Cited by 762
Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction
Chen, C., Kotyk, J. F. K., & Sheehan, S. W. (2018) · Chem · doi:10.1016/j.chempr.2018.08.019 · Cited by 776
Shape-Dependent Electrocatalytic Reduction of CO2 to CO on Triangular Silver Nanoplates
Liu, S., Tao, H., Zeng, L., Liu, Q., Xu, Z., Liu, Q., & Luo, J. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12103 · Cited by 703
Promoting electrocatalytic CO2 reduction to formate via sulfur-boosting water activation on indium surfaces
Ma, W., Xie, S., Zhang, X., Sun, F., Kang, J., Jiang, Z. R., Zhang, Q., Wu, D., & Wang, Y. (2019) · Nature Communications · doi:10.1038/s41467-019-08805-x · Cited by 720
Heterogeneous Single‐Atom Catalysts for Electrochemical CO2 Reduction Reaction
Li, M., Wang, H., Luo, W. D., Sherrell, P. C., Chen, J., & Yang, J. (2020) · Advanced Materials · doi:10.1002/adma.202001848 · Cited by 699
Surface chemistry of porphyrins and phthalocyanines
Gottfried, J. M. (2015) · Surface Science Reports · doi:10.1016/j.surfrep.2015.04.001 · Cited by 683
Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction
Gong, Q., Ding, P., Xu, M., Zhu, X., Wang, M., Deng, J., Ma, Q., Han, N., Zhu, Y. S., Lu, J. B., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10819-4 · Cited by 682
Tuning Sn-Catalysis for Electrochemical Reduction of CO 2 to CO via the Core/Shell Cu/SnO 2 Structure
Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lü, G., Zhu, J., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00261 · Cited by 682
Efficient electrically powered CO2-to-ethanol via suppression of deoxygenation
Wang, X., Wang, Z., de Arquer, F. P. G., Dinh, C., Ozden, A., Li, Y., Nam, D., Li, J., Liu, Y., Wicks, J., et al. (2020) · Nature Energy · doi:10.1038/s41560-020-0607-8 · Cited by 701
Self-citation
A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates
Wu, J., Ma, S., Sun, J., Gold, J. I., Tiwary, C., Kim, B., Zhu, L., Chopra, N., Odeh, I. N., Vajtai, R., et al. (2016) · Nature Communications · doi:10.1038/ncomms13869 · Cited by 658
Artificial Photosynthesis for Sustainable Fuel and Chemical Production
Kim, D., Sakimoto, K. K., Hong, D., & Yang, P. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409116 · Cited by 663
Photocatalytic and photoelectrocatalytic reduction of CO 2 using heterogeneous catalysts with controlled nanostructures
Xie, S., Zhang, Q., Liu, G., & Wang, Y. (2015) · Chemical Communications · doi:10.1039/c5cc07613g · Cited by 670
Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO2 Reduction to Formate
Han, N., Ding, P., He, L., Li, Y., & Li, Y. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201902338 · Cited by 668
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays
Ma, M., Djanashvili, K., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601282 · Cited by 648
Hierarchical Mesoporous SnO2 Nanosheets on Carbon Cloth: A Robust and Flexible Electrocatalyst for CO2 Reduction with High Efficiency and Selectivity
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201608279 · Cited by 637
Self-citation
Power to Gas projects review: Lab, pilot and demo plants for storing renewable energy and CO2
Bailera, M., Lisbona, P., Romeo, L. M., & Espatolero, S. (2016) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2016.11.130 · Cited by 656
Metal–Organic‐Framework‐Derived Hollow N‐Doped Porous Carbon with Ultrahigh Concentrations of Single Zn Atoms for Efficient Carbon Dioxide Conversion
Yang, Q., Yang, C., Lin, C., & Jiang, H. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201813494 · Cited by 623
Metal‐Doped Nitrogenated Carbon as an Efficient Catalyst for Direct CO 2 Electroreduction to CO and Hydrocarbons
Varela, A. S., Sahraie, N. R., Steinberg, J., Ju, W., Oh, H., & Strasser, P. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502099 · Cited by 619
Mechanistic Insights into the Electrochemical Reduction of CO2 to CO on Nanostructured Ag Surfaces
Rosen, J., Hutchings, G. S., Lu, Q., Rivera, S., Zhou, Y., Vlachos, D. G., & Jiao, F. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00840 · Cited by 616
Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
Shen, J., Kortlever, R., Kaş, R., Birdja, Y. Y., Díaz‐Morales, O., Kwon, Y., Ledezma‐Yanez, I., Schouten, K. J. P., Mul, G., & Koper, M. T. M. (2015) · Nature Communications · doi:10.1038/ncomms9177 · Cited by 612
Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond
Liu, Y., Chen, S., Quan, X., & Yu, H. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02975 · Cited by 602
Self-citation
Highly active and stable stepped Cu surface for enhanced electrochemical CO2 reduction to C2H4
Choi, C., Kwon, S., Cheng, T., Xu, M., Tieu, P., Lee, C., Cai, J. H., Lee, H. M., Pan, X. Q., Duan, X., et al. (2020) · Nature Catalysis · doi:10.1038/s41929-020-00504-x · Cited by 613
Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling
Wang, P., Yang, H., Tang, C., Wu, Y. S., Zheng, Y., Cheng, T., Davey, K. R., Huang, X., & Qiao, S. (2022) · Nature Communications · doi:10.1038/s41467-022-31427-9 · Cited by 626
Electrochemical CO 2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution
Weng, Z., Jiang, J., Wu, Y., Wu, Z., Guo, X., Materna, K. L., Liu, W., Batista, V. S., Brudvig, G. W., & Wang, H. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04746 · Cited by 586
Sacrificial electron donor reagents for solar fuel production
Pellegrin, Y., & Odobel, F. (2016) · Comptes Rendus Chimie · doi:10.1016/j.crci.2015.11.026 · Cited by 587
Cu-based nanocatalysts for electrochemical reduction of CO2
Xie, H., Wang, T., Liang, J., Li, Q., & Sun, S. (2018) · Nano Today · doi:10.1016/j.nantod.2018.05.001 · Cited by 573
Supported Cobalt Polyphthalocyanine for High-Performance Electrocatalytic CO2 Reduction
Han, N., Wang, Y., Ma, L., Wen, J., Li, J., Zheng, H., Nie, K., Wang, X., Zhao, F., Li, Y., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.08.002 · Cited by 567
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO 2
Elgrishi, N., Chambers, M. B., Wang, X., & Fontecave, M. (2017) · Chemical Society Reviews · doi:10.1039/c5cs00391a · Cited by 574
Unifying views on catalyst deactivation
Martín, A. J., Mitchell, S. J., Mondelli, C., Jaydev, S. D., & Pérez‐Ramírez, J. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00842-y · Cited by 556
Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH
Varela, A. S., Kroschel, M., Reier, T., & Strasser, P. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.06.009 · Cited by 542
Thermodynamic Hydricity of Transition Metal Hydrides
Wiedner, E. S., Chambers, M. B., Pitman, C. L., Bullock, R. M., Miller, A. J. M., & Appel, A. M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00168 · Cited by 555
Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway
Min, X., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511890h · Cited by 541
Solar conversion of CO2 to CO using Earth-abundant electrocatalysts prepared by atomic layer modification of CuO
Schreier, M., Héroguel, F., Steier, L., Ahmad, S., Luterbacher, J. S., Mayer, M. T., Luo, J., & Grätzel, M. (2017) · Nature Energy · doi:10.1038/nenergy.2017.87 · Cited by 546
Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials
Franco, F., Rettenmaier, C., Jeon, H. S., & Cuenya, B. R. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00835d · Cited by 554
Noble-Metal Based Random Alloy and Intermetallic Nanocrystals: Syntheses and Applications
Zhou, M. Y., Li, C., & Fang, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00436 · Cited by 541
Selective Photocatalytic CO 2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals
Kuehnel, M. F., Orchard, K. L., Dalle, K. E., & Reisner, E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00369 · Cited by 540
Towards the electrochemical conversion of carbon dioxide into methanol
Albo, J., Álvarez-Guerra, M., Castaño, P., & Irabien, Á. (2015) · Green Chemistry · doi:10.1039/c4gc02453b · Cited by 545
Cerium Metal–Organic Framework for Photocatalysis
Wu, X., Gagliardi, L., & Truhlar, D. G. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b03613 · Cited by 539
Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide‐Derived Nanostructured Silver Electrocatalysts
Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530
Insights into the carbon balance for CO 2 electroreduction on Cu using gas diffusion electrode reactor designs
Ma, M., Clark, E. L., Therkildsen, K. T., Dalsgaard, S., Chorkendorff, I., & Seger, B. J. (2020) · Energy & Environmental Science · doi:10.1039/d0ee00047g · Cited by 532
Insights into the Low Overpotential Electroreduction of CO2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer
Verma, S., Hamasaki, Y., Kim, C., Huang, W., Lu, S., Jhong, H.-R. M., Gewirth, A. A., Fujigaya, T., Nakashima, N., & Kenis, P. J. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01096 · Cited by 521
Subsurface oxide plays a critical role in CO 2 activation by Cu(111) surfaces to form chemisorbed CO 2 , the first step in reduction of CO 2
Favaro, M., Xiao, H. Y., Cheng, T., Goddard, W. A., Yano, J., & Crumlin, E. J. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1701405114 · Cited by 527
Thermochemical CO2 Hydrogenation to Single Carbon Products: Scientific and Technological Challenges
Roy, S., Cherevotan, A., & Peter, S. C. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00740 · Cited by 522
Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage
Indra, A., Song, T., & Paik, U. (2018) · Advanced Materials · doi:10.1002/adma.201705146 · Cited by 508
CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine
Wang, M., Torbensen, K., Salvatore, D. A., Ren, S., Joulié, D., Dumoulin, F., Mendoza, D., Lassalle‐Kaiser, B., İşçi, Ü., Berlinguette, C. P., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-11542-w · Cited by 527
A comparative technoeconomic analysis of pathways for commercial electrochemical CO 2 reduction to liquid products
Spurgeon, J. M., & Kumar, B. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00097b · Cited by 523
A Review of Non-Thermal Plasma Technology: A novel solution for CO2 conversion and utilization
Adwek, G., Shen, B., Craven, M., Wang, Y., Kang, D., Wu, C., & Tu, X. (2020) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2020.109702 · Cited by 514
A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction
Lv, J., Jouny, M., Luc, W., Zhu, W., Zhu, J., & Jiao, F. (2018) · Advanced Materials · doi:10.1002/adma.201803111 · Cited by 514
The effect of electrolyte composition on the electroreduction of CO 2 to CO on Ag based gas diffusion electrodes
Verma, S., Lu, X., Ma, S., Masel, R. I., & Kenis, P. J. A. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp05665a · Cited by 497
Doping graphene with boron: a review of synthesis methods, physicochemical characterization, and emerging applications
Agnoli, S., & Favaro, M. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta10599d · Cited by 492
Semiconductor Quantum Dots: An Emerging Candidate for CO2 Photoreduction
Wu, H., Li, X., Tung, C., & Wu, L. (2019) · Advanced Materials · doi:10.1002/adma.201900709 · Cited by 489
Covalent Organic Frameworks Linked by Amine Bonding for Concerted Electrochemical Reduction of CO2
Liu, H., Chu, J. H., Yin, Z., Cai, X. Q., Zhuang, L., & Deng, H. (2018) · Chem · doi:10.1016/j.chempr.2018.05.003 · Cited by 484

Authors: Qiao, J., Liu, Y., Hong, F., & Zhang, J.
Affiliations: Donghua University (CN)
Tohoku University (JP)
Corresponding author: Liu, Yuyu
Hong, Feng
Zhang, Jiujun
ORCID: Qiao, Jinli
Liu, Yuyu
Hong, Feng
Zhang, Jiujun
Venue: Chem. Soc. Rev.
Publisher: Royal Society of Chemistry (RSC)
Published: 2014
Volume: 43
Issue: 2
Pages: 631-675
ISSN: 0306-0012 (ISSN-L)
1460-4744
DOI: 10.1039/c3cs60323g
OpenAlex: W1992591486
Cited by: 2,990
References: 391
Citations by year: 2026: 142 · 2025: 203 · 2024: 269 · 2023: 255 · 2022: 292 · 2021: 312 · 2020: 350 · 2019: 328 · 2018: 289 · 2017: 221 · 2016: 159 · 2015: 119 · 2014: 51
FWCI: 6.20
Type: journal article
Language: en
Open access: closed
Locations: Chemical Society Reviews (publishedVersion)
PubMed (publishedVersion)
NPARC (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords: electrochemical CO2 reduction, electrocatalysts, low-carbon fuels, co-production, formate production, methanol synthesis, ethanol production, ethylene production, methane production, hydrogen production, Faradaic efficiency, catalyst stability, reduction mechanism, electrode potential effects, electrolyte composition, metal oxides, metal complexes, enzyme catalysts, alloys

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks