Cited by 2,990CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingCarbon dioxide utilization in catalysis

The DOI matches its Crossref record; 390 of the 391 references it cites were found in a registry or an index.

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Qiao, Jinli, Liu, Yuyu, Hong, Feng, Zhang, Jiujun·2014·Chem. Soc. Rev.

DOI 10.1039/c3cs60323g

Open this paper in CoChat — free account

Abstract

This paper reviews recent progress made in identifying electrocatalysts for carbon dioxide (CO2) reduction to produce low-carbon fuels, including CO, HCOOH/HCOO(-), CH2O, CH4, H2C2O4/HC2O4(-), C2H4, CH3OH, CH3CH2OH and others. The electrocatalysts are classified into several categories, including metals, metal alloys, metal oxides, metal complexes, polymers/clusters, enzymes and organic molecules. The catalyts' activity, product selectivity, Faradaic efficiency, catalytic stability and reduction mechanisms during CO2 electroreduction have received detailed treatment. In particular, we review the effects of electrode potential, solution-electrolyte type and composition, temperature, pressure, and other conditions on these catalyst properties. The challenges in achieving highly active and stable CO2 reduction electrocatalysts are analyzed, and several research directions for practical applications are proposed, with the aim of mitigating performance degradation, overcoming additional challenges, and facilitating research and development in this area.

Integrity signals

Registry

Crossref · 10.1039/c3cs60323g

Cites

390 of 390 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

We couldn’t retrieve this paper’s full text, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Li, H., Eddaoudi, M., O’Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,582
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Eddaoudi, M., Kim, J., Rosi, N. L., Vodak, D. T., Wachter, J., O’Keeffe, M., & Yaghi, O. M. (2002) · Science · doi:10.1126/science.1067208 · Cited by 8,228
TiO2 photocatalysis and related surface phenomena
FUJISHIMA, A., ZHANG, X., & TRYK, D. (2008) · Surface Science Reports · doi:10.1016/j.surfrep.2008.10.001 · Cited by 6,737
A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n
Chui, S. S.-Y., Lo, S. M. F., Charmant, J. P. H., Orpen, A. G., & Williams, I. D. (1999) · Science · doi:10.1126/science.283.5405.1148 · Cited by 6,071
Transformation of Carbon Dioxide
Sakakura, T., Choi, J., & Yasuda, H. Y. (2007) · Chemical Reviews · doi:10.1021/cr068357u · Cited by 3,891
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
A route to high surface area, porosity and inclusion of large molecules in crystals
Materials Design and Discovery Group, Chae, H. K., Siberio-Pérez, D. Y., Kim, J., Go, Y., Eddaoudi, M., Matzger, A. J., O’Keeffe, M., & Yaghi, O. M. (2004) · Nature · doi:10.1038/nature02311 · Cited by 2,817
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2008) · Chemical Society Reviews · doi:10.1039/b804323j · Cited by 2,061
CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000

Flagged first, then by citations

Show all 391 references

1 of the 391 references couldn’t be matched to a known paper.

Research works printed but not linked: 7

Nakayama, 1997, J. Electroanal. Chem., 440, 251
Hori, 1998, Abstr. Pap. Am. Chem. Soc., 215, U405
Cheng, 1996, Inorg. Chem., 35, 7704, 10.1021/ic9512385 · DOI
Haines, 1994, Inorg. Chem., 33, 4723, 10.1021/ic00099a024 · DOI
Royer, 1870, Compt. Rend., 731
Senthil Kumar, 2012, Electrochem. Commun., 25, 70, 10.1016/j.elecom.2012.09.018 · DOI
Beley, 1984, J. Chem. Soc., Chem. Commun., 1315, 10.1039/c39840001315 · DOI

Sorted by citations

Items 301–400 of 1,005

Electrochemical CO 2 -to-CO conversion: electrocatalysts, electrolytes, and electrolyzers
Gao, F., Bao, R., Gao, M., & Yu, S. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta03525d · Cited by 212
Pulse check: Potential opportunities in pulsed electrochemical CO2 reduction
Casebolt, R., Levine, K., Suntivich, J., & Hanrath, T. (2021) · Joule · doi:10.1016/j.joule.2021.05.014 · Cited by 217
Defect engineering: A versatile tool for tuning the activation of key molecules in photocatalytic reactions
Zhang, N., Gao, C., & Xiong, Y. (2018) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2018.09.010 · Cited by 208
Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry
Machan, C. W., Sampson, M. D., Chabolla, S. A., Dang, T., & Kubiak, C. P. (2014) · Organometallics · doi:10.1021/om500044a · Cited by 206
Carbon Dioxide Hydrogenation into Higher Hydrocarbons and Oxygenates: Thermodynamic and Kinetic Bounds and Progress with Heterogeneous and Homogeneous Catalysis
Prieto, G. (2017) · ChemSusChem · doi:10.1002/cssc.201601591 · Cited by 208
Constructing Conductive Interfaces between Nickel Oxide Nanocrystals and Polymer Carbon Nitride for Efficient Electrocatalytic Oxygen Evolution Reaction
Liao, C., Yang, B., Zhang, N., Liu, M., Chen, G., Jiang, X., Chen, G., Yang, J., Liu, X., Chan, T., et al. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201904020 · Cited by 207
Terpyridine complexes of first row transition metals and electrochemical reduction of CO 2 to CO
Elgrishi, N., Chambers, M. B., Artero, V., & Fontecave, M. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00451e · Cited by 205
Electroreduction of CO2 Catalyzed by a Heterogenized Zn–Porphyrin Complex with a Redox-Innocent Metal Center
Wu, Y., Jiang, J., Weng, Z., Wang, M., Broere, D. L. J., Zhong, Y., Brudvig, G. W., Feng, Z., & Wang, H. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00160 · Cited by 207
Catalysts design for higher alcohols synthesis by CO2 hydrogenation: Trends and future perspectives
Zeng, F., Mebrahtu, C., Xi, X., Liao, L., Ren, J., Xie, J., Heeres, H. J., & Palkovits, R. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120073 · Cited by 202
Synthesis of emerging two-dimensional (2D) materials – Advances, challenges and prospects
Alam, S., Chowdhury, M. A., Shahid, A., Alam, M. R., & Rahim, A. (2021) · FlatChem · doi:10.1016/j.flatc.2021.100305 · Cited by 202
Switching between C 2+ Products and CH 4 in CO 2 Electrolysis by Tuning the Composition and Structure of Rare-Earth/Copper Catalysts
Liu, J., Li, P., Bi, J., Jia, S., Wang, Y., Kang, X., Sun, X., Zhu, Q., & Han, B. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c05562 · Cited by 205
Conversion of CO 2 in a cylindrical dielectric barrier discharge reactor: Effects of plasma processing parameters and reactor design
Mei, D., & Tu, X. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.02.015 · Cited by 203
Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts
Sung, S., Kumar, D., Gil‐Sepulcre, M., & Nippe, M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b07709 · Cited by 202
Electrocatalytic CO2 Reduction to Fuels: Progress and Opportunities
Resasco, J., & Bell, A. T. (2020) · Trends in Chemistry · doi:10.1016/j.trechm.2020.06.007 · Cited by 207
Selective Heterogeneous CO2 Electroreduction to Methanol
Back, S., Kim, H., & Jung, Y. (2015) · ACS Catalysis · doi:10.1021/cs501600x · Cited by 201
Ionic liquids in the electrochemical valorisation of CO 2
Álvarez-Guerra, M., Albo, J., Alvarez‐Guerra, E., & Irabien, Á. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01486g · Cited by 205
Influence of Atomic-Level Morphology on Catalysis: The Case of Sphere and Rod-Like Gold Nanoclusters for CO 2 Electroreduction
Zhao, S., Austin, N., Li, M., Song, Y., House, S. D., Bernhard, S., Yang, J. C., Mpourmpakis, G., & Jin, R. M. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00365 · Cited by 199
High-Density Nanosharp Microstructures Enable Efficient CO 2 Electroreduction
Safaei, T. S., Mepham, A. H., Zheng, X. R., Pang, Y., Dinh, C., Liu, M., Sinton, D. A., Kelley, S. O., & Burdyny, T. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03615 · Cited by 198
1D SnO2 with Wire‐in‐Tube Architectures for Highly Selective Electrochemical Reduction of CO2 to C1 Products
Fan, L., Zheng, X., Xu, M., Lü, Y., & Li, Z. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201706289 · Cited by 201
Supported Single Atoms as New Class of Catalysts for Electrochemical Reduction of Carbon Dioxide
Cheng, Y., Yang, S., Jiang, S. P., & Wang, S. (2019) · Small Methods · doi:10.1002/smtd.201800440 · Cited by 202
Recent Advances in Bipolar Membrane Design and Applications
Giesbrecht, P. K., & Freund, M. S. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c02829 · Cited by 201
CO 2 Electrochemical Reduction to Methane and Methanol on Copper-Based Alloys: Theoretical Insight
Hirunsit, P., Soodsawang, W., & Limtrakul, J. P. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b01574 · Cited by 204
Electrochemical Reduction of CO 2 over Heterogeneous Catalysts in Aqueous Solution: Recent Progress and Perspectives
Long, C., Li, X., Guo, J. M., Shi, Y., Liu, S., & Tang, Z. (2018) · Small Methods · doi:10.1002/smtd.201800369 · Cited by 201
Electrochemical reduction of CO2 into formate/formic acid: A review of cell design and operation
Ewis, D., Arsalan, M., Khaled, M. M., Pant, D., Ba-Abbad, M. M., Amhamed, A. I., & El‐Naas, M. H. (2023) · Separation and Purification Technology · doi:10.1016/j.seppur.2023.123811 · Cited by 206
Electrochemical carbon capture processes for mitigation of CO 2 emissions
Rahimi, M., Khurram, A., Hatton, T. A., & Gallant, B. M. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00443g · Cited by 207
Unlocking the Electrocatalytic Activity of Antimony for CO2 Reduction by Two‐Dimensional Engineering of the Bulk Material
Li, F., Xue, M., Li, J., Ma, X., Chen, L., Zhang, X., MacFarlane, D. R., & Zhang, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201710038 · Cited by 199
Self-citation
Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron‐ and Nitrogen‐Co‐doped Nanodiamond
Liu, Y., Zhang, Y., Cheng, K. F., Quan, X., Fan, X., Su, Y., Chen, S., Zhao, H., Zhang, Y., Yu, H., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201706311 · Cited by 196
Self-citation
Unlocking direct CO2 electrolysis to C3 products via electrolyte supersaturation
Qi, K., Zhang, Y., Onofrio, N., Eddy Petit, A., Cui, X., Ma, J., Fan, J., Wu, H., Wang, W., Li, J., et al. (2023) · Nature Catalysis · doi:10.1038/s41929-023-00938-z · Cited by 216
Electrochemical Reduction of Carbon Dioxide to Formate on Tin–Lead Alloys
Choi, S. Y., Jeong, S. K., Kim, H. J., Baek, I. H., & Park, K. T. (2015) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.5b01336 · Cited by 195
Covalent triazine framework modified with coordinatively-unsaturated Co or Ni atoms for CO 2 electrochemical reduction
Su, P., Iwase, K., Harada, T., Kamiya, K., & Nakanishi, S. (2018) · Chemical Science · doi:10.1039/c8sc00604k · Cited by 194
Identifying systematic DFT errors in catalytic reactions
Christensen, R., Hansen, H. A., & Vegge, T. (2015) · Catalysis Science & Technology · doi:10.1039/c5cy01332a · Cited by 198
Role of a Hydroxide Layer on Cu Electrodes in Electrochemical CO2 Reduction
Iijima, G., Inomata, T., Yamaguchi, H., Ito, M., & Masuda, H. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00896 · Cited by 199
Highly Selective Molecular Catalysts for the CO 2 -to-CO Electrochemical Conversion at Very Low Overpotential. Contrasting Fe vs Co Quaterpyridine Complexes upon Mechanistic Studies
Cometto, C., Chen, L., Lo, P., Guo, Z., Lau, K., Anxolabéhère‐Mallart, E., Fave, C., Lau, T., & Robert, M. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b04412 · Cited by 192
Recent progress in conjugated microporous polymers for clean energy: Synthesis, modification, computer simulations, and applications
Luo, S., Zeng, Z., Wang, H., Xiong, W., Song, B., Zhou, C., Duan, A., Tan, X., He, Q., Zeng, G., et al. (2021) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2021.101374 · Cited by 193
Polyethylenimine promoted electrocatalytic reduction of CO 2 to CO in aqueous medium by graphene-supported amorphous molybdenum sulphide
Li, F., Zhao, S., Chen, L., Khan, A. A., MacFarlane, D. R., & Zhang, J. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02879e · Cited by 195
Self-citation
In Situ Fabrication and Reactivation of Highly Selective and Stable Ag Catalysts for Electrochemical CO2 Conversion
Ma, M., Liu, K., Shen, J., Kaş, R., & Smith, W. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00472 · Cited by 192
Current achievements and the future direction of electrochemical CO 2 reduction: A short review
Lee, M., Park, K. T., Lee, W., Lim, H., Kwon, Y., & Kang, S. (2019) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2019.1631991 · Cited by 193
Linkage Effect in the Heterogenization of Cobalt Complexes by Doped Graphene for Electrocatalytic CO2 Reduction
Wang, J., Huang, X., Xi, S., Lee, J., Wang, C., Du, Y., & Wang, X. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201906475 · Cited by 190
Recent Advances in Electrochemical Carboxylation with CO 2
Sun, G., Liao, L., Ran, C., Ye, J., & Yu, D. (2024) · Accounts of Chemical Research · doi:10.1021/acs.accounts.4c00417 · Cited by 190
Sn nanoparticles on gas diffusion electrodes: Synthesis, characterization and use for continuous CO 2 electroreduction to formate
Del Castillo, A., Alvarez-Guerra, M., Solla-Gullón, J., Sáez, A., Montiel, V., & Irabien, A. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.01.021 · Cited by 189
Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO 2 -to-CO Conversion Catalyzed by Iron Porphyrins
Azcarate, I., Costentin, C., Robert, M., & Savéant, J. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b09947 · Cited by 197
The Role of the Copper Oxidation State in the Electrocatalytic Reduction of CO 2 into Valuable Hydrocarbons
Velasco‐Vélez, J., Jones, T. E., Gao, D., Carbonio, E. A., Arrigo, R., Hsu, C.-J., Huang, Y., Dong, C., Chen, J., Lee, J., et al. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05106 · Cited by 189
Conductive Phthalocyanine‐Based Covalent Organic Framework for Highly Efficient Electroreduction of Carbon Dioxide
Zhang, M., Si, D., Yi, J., Zhao, S., Huang, Y., & Cao, R. (2020) · Small · doi:10.1002/smll.202005254 · Cited by 186
Electrochemical reduction of CO2 to formate in aqueous solution using electro-deposited Sn catalysts
Zhao, C., & Wang, J. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.02.084 · Cited by 194
Benchmarking of Homogeneous Electrocatalysts: Overpotential, Turnover Frequency, Limiting Turnover Number
Costentin, C., Passard, G., & Savéant, J. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00914 · Cited by 201
Microbial electrolysis cell platform for simultaneous waste biorefinery and clean electrofuels generation: Current situation, challenges and future perspectives
Zhen, G., Lü, X., Kumar, G., Bakonyi, P., Xu, K., & Zhao, Y. (2017) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2017.07.003 · Cited by 191
Sustainable chemistry: how to produce better and more from less?
Marion, P., Bernela, B., Piccirilli, A., Estrine, B., Patouillard, N., Guilbot, J., & Jérôme, F. (2017) · Green Chemistry · doi:10.1039/c7gc02006f · Cited by 200
Nanostructured Copper‐Based Electrocatalysts for CO 2 Reduction
Gu, Z., Shen, H. F., Shang, L., Lv, X., Qian, L., & Zheng, G. (2018) · Small Methods · doi:10.1002/smtd.201800121 · Cited by 190
P-block metal-based (Sn, In, Bi, Pb) electrocatalysts for selective reduction of CO2 to formate
Yang, Z., Oropeza, F. E., & Zhang, K. H. L. (2020) · APL Materials · doi:10.1063/5.0004194 · Cited by 195
Asymmetric Low-Frequency Pulsed Strategy Enables Ultralong CO 2 Reduction Stability and Controllable Product Selectivity
Zhang, X., Liu, T., Liu, C., Zheng, D., Huang, J.-M., Liu, Q., Yuan, W.-W., Yin, Y., Huang, L., Xu, M., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c09501 · Cited by 189
The Holy Grail: Chemistry Enabling an Economically Viable CO2 Capture, Utilization, and Storage Strategy
Senftle, T. P., & Carter, E. A. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00479 · Cited by 184
Efficient Electroconversion of Carbon Dioxide to Formate by a Reconstructed Amino‐Functionalized Indium–Organic Framework Electrocatalyst
Wang, Z., Zhou, Y., Xia, C., Guo, W., You, B., & Xia, B. Y. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202107523 · Cited by 184
Photoelectrochemical CO2-to-fuel conversion with simultaneous plastic reforming
Bhattacharjee, S., Rahaman, M., Andrei, V., Miller, M., Rodríguez‐Jiménez, S., Lam, E., Pornrungroj, C., & Reisner, E. (2023) · Nature Synthesis · doi:10.1038/s44160-022-00196-0 · Cited by 191
Three‐Dimensional Smart Catalyst Electrode for Oxygen Evolution Reaction
Chen, S., Duan, J., Bian, P., Tang, Y., Zheng, R., & Qiao, S. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500936 · Cited by 182
Selective electrochemical reduction of CO 2 to CO on CuO-derived Cu nanowires
Ma, M., Djanashvili, K., & Smith, W. A. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03559g · Cited by 185
Thermocatalytic Conversion of CO 2 to Valuable Products Activated by Noble‐Metal‐Free Metal‐Organic Frameworks
Hou, S., Dong, J., Zhao, X., Li, X., Ren, F., Zhao, J. Q., & Zhao, B. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202305213 · Cited by 182
Electrochemical CO2 reduction to CO on dendritic Ag–Cu electrocatalysts prepared by electrodeposition
Choi, J., Kim, M. J., Ahn, ‪. H., Choi, I., Jang, J. H., Ham, Y. S., Kim, J. J., & Kim, S. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.04.037 · Cited by 182
Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers
Shao, P. H., Yi, L., Chen, S., Zhou, T., & Zhang, J. (2019) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.04.013 · Cited by 186
Self-citation
Tuning Structural and Compositional Effects in Pd–Au Nanowires for Highly Selective and Active CO2 Electrochemical Reduction Reaction
Zhu, S., Wang, Q., Qin, X., Gu, M. D., Tao, R., Lee, B. P., Zhang, L., Yao, Y., Li, T., & Shao, M. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201802238 · Cited by 180
High-Yield and Selective Photoelectrocatalytic Reduction of CO2 to Formate by Metallic Copper Decorated Co3O4 Nanotube Arrays
Shen, Q., Chen, Z., Huang, X., Liu, M., & Zhao, G. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b00066 · Cited by 179
Visible-light-switched electron transfer over single porphyrin-metal atom center for highly selective electroreduction of carbon dioxide
Yang, D., Yu, H., He, T., Zuo, S., Liu, X., Yang, H., Ni, B., Li, H., Gu, L., Wang, D., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-11817-2 · Cited by 177
Atom vacancies induced electron-rich surface of ultrathin Bi nanosheet for efficient electrochemical CO2 reduction
Zhao, M., Gu, Y., Gao, W., Cui, P., Tang, H., Wei, X., Zhu, H., Li, G., Yan, S., Zhang, X., et al. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.118625 · Cited by 177
Covalently anchoring covalent organic framework on carbon nanotubes for highly efficient electrocatalytic CO2 reduction
Dong, H. Y., Lu, M., Wang, Y., Tang, H., Wu, D., Sun, X., & Zhang, F. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120897 · Cited by 180
Template-Sacrificing Synthesis of Well-Defined Asymmetrically Coordinated Single-Atom Catalysts for Highly Efficient CO2 Electrocatalytic Reduction
Huang, M. Y., Deng, B., Zhao, X., Zhang, Z., Li, F., Li, K., Cui, Z., Kong, L., Lu, J., Dong, F., et al. (2022) · ACS Nano · doi:10.1021/acsnano.1c07746 · Cited by 178
Hydronium-Induced Switching between CO2 Electroreduction Pathways
Seifitokaldani, A., Gabardo, C. M., Burdyny, T., Dinh, C.-T., Edwards, J. P., Kibria, M. G., Bushuyev, O. S., Kelley, S. O., Sinton, D., & Sargent, E. H. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13542 · Cited by 179
Recent Trends, Benchmarking, and Challenges of Electrochemical Reduction of CO 2 by Molecular Catalysts
Elouarzaki, K., Kannan, V., Jose, V. K., Sabharwal, H. S., & Lee, J. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201900090 · Cited by 178
Building Blocks for High Performance in Electrocatalytic CO2 Reduction: Materials, Optimization Strategies, and Device Engineering
Larrazábal, G. O., Martín, A. J., & Pérez-Ramírez, J. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01380 · Cited by 176
Electrochemical Reduction of CO2 to CO by a Heterogeneous Catalyst of Fe–Porphyrin-Based Metal–Organic Framework
Dong, B., Qian, S.-L., Bu, F.-Y., Wu, Y.-C., Feng, L.-G., Teng, Y., Liu, W., & Li, Z. (2018) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b00797 · Cited by 176
Design of Lewis Pair-Functionalized Metal Organic Frameworks for CO 2 Hydrogenation
Ye, J., & Johnson, J. K. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00396 · Cited by 178
Recent advances in the nanoengineering of electrocatalysts for CO 2 reduction
Li, F., MacFarlane, D. R., & Zhang, J. (2018) · Nanoscale · doi:10.1039/c7nr09620h · Cited by 179
Self-citation
Heteroatom-doped carbon materials and their composites as electrocatalysts for CO 2 reduction
Cui, H., Guo, Y., Guo, L., Wang, L., Zhou, Z. P., & Peng, Z. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta07430e · Cited by 177
Effect of CO2 Bubbling into Aqueous Solutions Used for Electrochemical Reduction of CO2 for Energy Conversion and Storage
Zhong, H., Fujii, K., Nakano, Y., & Jin, F. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp509043h · Cited by 184
Nanoporous Au Thin Films on Si Photoelectrodes for Selective and Efficient Photoelectrochemical CO 2 Reduction
Song, J. T., Ryoo, H., Cho, M., Kim, J., Kim, J., Chung, S., & Oh, J. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201601103 · Cited by 179
Comprehensive Mechanism of CO 2 Electroreduction toward Ethylene and Ethanol: The Solvent Effect from Explicit Water–Cu(100) Interface Models
Santatiwongchai, J., Faungnawakij, K., & Hirunsit, P. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01486 · Cited by 173
Thermodynamic and kinetic hydricities of metal-free hydrides
Ilić, S., Alherz, A. W., Musgrave, C. B., & Glusac, K. D. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00171a · Cited by 173
Graphdiyne/Graphene Heterostructure: A Universal 2D Scaffold Anchoring Monodispersed Transition-Metal Phthalocyanines for Selective and Durable CO2 Electroreduction
Gu, H., Zhong, L., Shi, G., Li, J., Yu, K. X., Li, J., Zhang, S., Zhu, C., Chen, S., Yang, C., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c02326 · Cited by 173
Self-citation
In Situ Halogen‐Ion Leaching Regulates Multiple Sites on Tandem Catalysts for Efficient CO 2 Electroreduction to C 2+ Products
Yang, R., Duan, J., Dong, P., Wen, Q., Wu, M., Liu, Y., Liu, Y., Li, H., & Zhai, T. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202116706 · Cited by 176
Self-citation
Convergent reductive depolymerization of wood lignin to isolated phenol derivatives by metal-free catalytic hydrosilylation
Féghali, E., Carrot, G., Thuéry, P., Genre, C., & Cantat, T. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01304f · Cited by 176
Revealing the Origin of Activity in Nitrogen‐Doped Nanocarbons towards Electrocatalytic Reduction of Carbon Dioxide
Xu, J., Kan, Y., Huang, R., Zhang, B., Wang, B., Wu, K., Lin, Y., Sun, X., Li, Q., Centi, G., et al. (2016) · ChemSusChem · doi:10.1002/cssc.201600202 · Cited by 175
A Disquisition on the Active Sites of Heterogeneous Catalysts for Electrochemical Reduction of CO2 to Value‐Added Chemicals and Fuel
Daiyan, R., Saputera, W. H., Masood, H., Leverett, J., Lu, X., & Amal, R. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902106 · Cited by 174
A local proton source in a [Mn(bpy-R)(CO) 3 Br]-type redox catalyst enables CO 2 reduction even in the absence of Brønsted acids
Franco, F., Cometto, C., Vallana, F. M. F., Sordello, F., Priola, E., Minero, C., Nervi, C., & Gobetto, R. (2014) · Chemical Communications · doi:10.1039/c4cc05563b · Cited by 171
Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO 2 reduction electrocatalysts
Lobaccaro, P., Singh, M. R., Clark, E. L., Kwon, Y., Bell, A. T., & Ager, J. W. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp05287h · Cited by 177
Charge-transfer regulated visible light driven photocatalytic H2 production and CO2 reduction in tetrathiafulvalene based coordination polymer gel
Verma, P., Singh, A. K., Rahimi, F. A., Sarkar, P., Nath, S., Pati, S. K., & Maji, T. K. (2021) · Nature Communications · doi:10.1038/s41467-021-27457-4 · Cited by 170
Enhancing Activity and Reducing Cost for Electrochemical Reduction of CO2 by Supporting Palladium on Metal Carbides
Wang, J., Kattel, S. P., Hawxhurst, C. J., Lee, J. H., Tackett, B. M., Chang, K., Rui, N., Liu, C., & Chen, J. G. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201900781 · Cited by 171
Low‐Coordinated Edge Sites on Ultrathin Palladium Nanosheets Boost Carbon Dioxide Electroreduction Performance
Zhu, W., Zhang, L., Yang, P., Hu, C., Luo, Z., Chang, X., Zhao, Z., & Gong, J. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806432 · Cited by 169
Exploring dopant effects in stannic oxide nanoparticles for CO2 electro-reduction to formate
Ko, Y., Kim, J.-Y., Lee, W. H., Kim, M. G., Seong, T., Park, J., Jeong, Y., Min, B. K., Lee, W., Lee, D. K., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-29783-7 · Cited by 185
Selective CO2 Reduction on Zinc Electrocatalyst: The Effect of Zinc Oxidation State Induced by Pretreatment Environment
Nguyen, D. L. T., Jee, M. S., Won, D. H., Jung, H., Oh, H., Min, B. K., & Hwang, Y. J. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b02460 · Cited by 169
Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts
Grills, D. C., Ertem, M. Z., McKinnon, M. E., Ngo, K. T., & Rochford, J. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.05.022 · Cited by 167
Catalysts in electro-, photo- and photoelectrocatalytic CO2 reduction reactions
Wang, Y., He, D., Chen, H., & Wang, D. (2019) · Journal of Photochemistry and Photobiology C Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2019.02.002 · Cited by 169
Two‐Dimensional Metal–Organic Frameworks and Covalent–Organic Frameworks for Electrocatalysis: Distinct Merits by the Reduced Dimension
Lee, M. K., Shokouhimehr, M., Kim, S. Y., & Jang, H. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202003990 · Cited by 167
The Mechanism of Homogeneous CO2 Reduction by Ni(cyclam): Product Selectivity, Concerted Proton–Electron Transfer and C–O Bond Cleavage
Song, J., Klein, E. L., Neese, F., & Ye, S. (2014) · Inorganic Chemistry · doi:10.1021/ic500829p · Cited by 172
Trace Levels of Copper in Carbon Materials Show Significant Electrochemical CO2 Reduction Activity
Lum, Y., Kwon, Y., Lobaccaro, P., Chen, L., Clark, E. L., Bell, A. T., & Ager, J. W. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02399 · Cited by 170
Recent Improvements in the Production of Solar Fuels: From CO2 Reduction to Water Splitting and Artificial Photosynthesis
Roy, N., Suzuki, N., Terashima, C., & Fujishima, A. (2019) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20180250 · Cited by 165
Tethering of Nicotinamide Adenine Dinucleotide Inside Hollow Nanofibers for High-Yield Synthesis of Methanol from Carbon Dioxide Catalyzed by Coencapsulated Multienzymes
Ji, X., Su, Z. G., Wang, P., Ma, G., & Zhang, S. (2015) · ACS Nano · doi:10.1021/acsnano.5b01278 · Cited by 164
Porous dendritic copper: an electrocatalyst for highly selective CO 2 reduction to formate in water/ionic liquid electrolyte
Huan, T. N., Simon, P., Rousse, G., Génois, I., Artero, V., & Fontecave, M. (2016) · Chemical Science · doi:10.1039/c6sc03194c · Cited by 170
Carbon Dioxide Reduction by Iron Hangman Porphyrins
Margarit, C. G., Schnedermann, C., Asimow, N. G., & Nocera, D. G. (2018) · Organometallics · doi:10.1021/acs.organomet.8b00334 · Cited by 165
Laser-Prepared CuZn Alloy Catalyst for Selective Electrochemical Reduction of CO2 to Ethylene
Feng, Y., Li, Z., Liu, H., Dong, C., Wang, J., Kulinich, S. A., & Du, X. (2018) · Langmuir · doi:10.1021/acs.langmuir.8b02837 · Cited by 164
Simultaneous electrocatalytic reduction of dinitrogen and carbon dioxide on conducting polymer electrodes
Kayan, D. B., & Köleli, F. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.07.045 · Cited by 164
Exceptional Visible-Light Activities of TiO2-Coupled N-Doped Porous Perovskite LaFeO3 for 2,4-Dichlorophenol Decomposition and CO2 Conversion
Humayun, M., Qu, Y., Raziq, F., Yan, R., Li, Z., Zhang, X., & Jing, L. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b04958 · Cited by 164
Black reduced porous SnO2 nanosheets for CO2 electroreduction with high formate selectivity and low overpotential
Liu, G., Li, Z., Shi, J., Sun, K., Ji, Y., Wang, Z., Qiu, Y., Liu, Y., Wang, Z., & Hu, P. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118134 · Cited by 164
Self-citation

Authors: Qiao, J., Liu, Y., Hong, F., & Zhang, J.
Affiliations: Donghua University (CN)
Tohoku University (JP)
Corresponding author: Liu, Yuyu
Hong, Feng
Zhang, Jiujun
ORCID: Qiao, Jinli
Liu, Yuyu
Hong, Feng
Zhang, Jiujun
Venue: Chem. Soc. Rev.
Publisher: Royal Society of Chemistry (RSC)
Published: 2014
Volume: 43
Issue: 2
Pages: 631-675
ISSN: 0306-0012 (ISSN-L)
1460-4744
DOI: 10.1039/c3cs60323g
OpenAlex: W1992591486
Cited by: 2,990
References: 391
Citations by year: 2026: 142 · 2025: 203 · 2024: 269 · 2023: 255 · 2022: 292 · 2021: 312 · 2020: 350 · 2019: 328 · 2018: 289 · 2017: 221 · 2016: 159 · 2015: 119 · 2014: 51
FWCI: 6.20
Type: journal article
Language: en
Open access: closed
Locations: Chemical Society Reviews (publishedVersion)
PubMed (publishedVersion)
NPARC (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords: electrochemical CO2 reduction, electrocatalysts, low-carbon fuels, co-production, formate production, methanol synthesis, ethanol production, ethylene production, methane production, hydrogen production, Faradaic efficiency, catalyst stability, reduction mechanism, electrode potential effects, electrolyte composition, metal oxides, metal complexes, enzyme catalysts, alloys

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks