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Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis

Wang, Jing, Gao, Dunfeng, Wang, Guoxiong, Miao, Shu, Wu, Haihua, Li, Jiayuan, Bao, Xinhe·2014·J. Mater. Chem. A

Abstract

The hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are important electrocatalytic processes in water electrolyzers. Identifying efficient non-precious metal catalysts for HER and OER remains a great challenge for applications in different kinds of electrolyzers. Herein, we report that cobalt nanoparticles encapsulated in nitrogen-doped carbon (Co@N–C) show high activity and durability for HER in a wide pH range and for OER in alkaline medium as a bifunctional catalyst. The HER and OER activities of Co@N–C are higher than those of multiwall carbon nanotube and iron nanoparticles encapsulated in nitrogen-doped carbon with a similar content of nitrogen. Electrolyzer prototypes using Nafion NRE-212 as electrolyte membrane and Co@N–C as cathode or anode catalyst are constructed, showing potential practical applications in water splitting.

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Metadata

Authors
Wang, J., Gao, D., Wang, G., Miao, S., Wu, H., Li, J., & Bao, X.
Venue
J. Mater. Chem. A
Published
2014-10-16
Volume
2
Issue
47
Pages
20067-20074
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W1987651047
Cited by
256
References
10
FWCI
8.84
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis. https://app.cochat.ai/papers/10.1039/c4ta04337e
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Wang, J., Gao, D., Wang, G., Miao, S., Wu, H., Li, J., & Bao, X. (2014). Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis. J. Mater. Chem. A. https://doi.org/10.1039/c4ta04337e

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