Cited by 102Carbon dioxide utilization in catalysisbiodegradable polymer synthesis and propertiesAdvanced Polymer Synthesis and Characterization

Recent advances in metallo/organo-catalyzed immortal ring-opening polymerization of cyclic carbonates

Guillaume, Sophie M., Carpentier, Jean-François·2012·Catalysis Science & Technology

Abstract

The ring-opening polymerization of cyclic carbonate monomers derived from biomass feedstocks constitutes an attractive way to prepare polycarbonates that are potentially useful as high-tech materials or commodity “bioplastics”. This process can be catalyzed by inherently different systems ranging from simple basic organocatalysts, simple Lewis acidic metallic salts such as triflates, or more sophisticated discrete metallo-organic complexes derived from oxophilic metals (zinc, yttrium). In this perspective, the most recent achievements in this chemistry are reviewed. The quite different performances within reach of those catalytic systems, which are assessed in terms of intrinsic reactivity, robustness and regioselectivity towards dissymmetric monomers, are highlighted.

Integrity signals

Registry

Crossref · 10.1039/c2cy00507g

Cites

49 of 49 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

  • Initiators based on porphyrin complexes or related structures based on Al, Zn, Y, Lu, In have been used for polymerization of oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others.

    “The initiators based on porphyrin complexes or complexes with related structures based on Al, Zn, Y, Lu, In have been used for the polymerization of e.g., oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others [147,149 -156].”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [153]

Cites

Flagged first, then by citations

Cited by

Sorted by citations

Authors
Guillaume, S. M., & Carpentier, J.-F.
Affiliations
Centre National de la Recherche Scientifique (FR)
Corresponding author
Guillaume, Sophie M.
Venue
Catalysis Science & Technology
Published
2012
Volume
2
Issue
5
Pages
898
ISSN
  • 2044-4753 (ISSN-L)
  • 2044-4761
OpenAlex
W2170769556
Cited by
102
References
49
Citations by year
2026: 1 · 2024: 4 · 2023: 2 · 2022: 5 · 2021: 2 · 2020: 2 · 2019: 6 · 2018: 10 · 2017: 7 · 2016: 6 · 2015: 15 · 2014: 13 · 2013: 19 · 2012: 10
FWCI
8.72
Type
journal article
Language
en
Open access
closed
Locations
  • Catalysis Science & Technology (publishedVersion)
  • HAL (submittedVersion)
Funders
  • U.S. Department of Energy
  • Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
  • Institut Universitaire de France
Topics
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
organocatalysis, polycarbonate, bioplastics, biomass-derived monomers, zinc catalysis, Lewis acid catalysis, trifluoromethanesulfonate, regioselectivity

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review