Recent advances in metallo/organo-catalyzed immortal ring-opening polymerization of cyclic carbonates
Abstract
The ring-opening polymerization of cyclic carbonate monomers derived from biomass feedstocks constitutes an attractive way to prepare polycarbonates that are potentially useful as high-tech materials or commodity “bioplastics”. This process can be catalyzed by inherently different systems ranging from simple basic organocatalysts, simple Lewis acidic metallic salts such as triflates, or more sophisticated discrete metallo-organic complexes derived from oxophilic metals (zinc, yttrium). In this perspective, the most recent achievements in this chemistry are reviewed. The quite different performances within reach of those catalytic systems, which are assessed in terms of intrinsic reactivity, robustness and regioselectivity towards dissymmetric monomers, are highlighted.
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Initiators based on porphyrin complexes or related structures based on Al, Zn, Y, Lu, In have been used for polymerization of oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others.
“The initiators based on porphyrin complexes or complexes with related structures based on Al, Zn, Y, Lu, In have been used for the polymerization of e.g., oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others [147,149 -156].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [153]
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- Authors
- Guillaume, S. M., & Carpentier, J.-F.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Guillaume, Sophie M.
- Venue
- Catalysis Science & Technology
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 2
- Issue
- 5
- Pages
- 898
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2170769556
- Semantic Scholar
- c178858631f5ac4cdd3f3105fceca85caca7ff4c
- Cited by
- 102
- References
- 49
- Citations by year
- 2026: 1 · 2024: 4 · 2023: 2 · 2022: 5 · 2021: 2 · 2020: 2 · 2019: 6 · 2018: 10 · 2017: 7 · 2016: 6 · 2015: 15 · 2014: 13 · 2013: 19 · 2012: 10
- FWCI
- 8.72
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Science & Technology (publishedVersion)
- HAL (submittedVersion)
- Funders
- U.S. Department of Energy
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
- Institut Universitaire de France
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- organocatalysis, polycarbonate, bioplastics, biomass-derived monomers, zinc catalysis, Lewis acid catalysis, trifluoromethanesulfonate, regioselectivity
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