Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145

Effective ionic radii in oxides and fluorides

Shannon, R. D., & Prewitt, C. T. (1969) · Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry · doi:10.1107/s0567740869003220 · Cited by 8,627

Heteropoly and Isopoly Oxometalates

Pope, M. T. (1983) · Inorganic chemistry concepts · doi:10.1007/978-3-662-12004-0 · Cited by 4,749

Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

Pope, M. T., & Müller, A. (1991) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199100341 · Cited by 3,645

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries

Reddy, M. V., Subba Rao, G. V., & Chowdari, B. V. R. (2013) · Chemical Reviews · doi:10.1021/cr3001884 · Cited by 2,921

Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions

Kozhevnikov, I. V. (1998) · Chemical Reviews · doi:10.1021/cr960400y · Cited by 2,758

Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage

Jiang, J., Li, Y., Liu, J., Huang, X., Yuan, C., & Lou, X. W. (. (2012) · Advanced Materials · doi:10.1002/adma.201202146 · Cited by 2,473

Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations

Ma, Y., Wang, X., Jia, Y., Chen, X., Han, H., & Li, C. (2014) · Chemical Reviews · doi:10.1021/cr500008u · Cited by 2,411

Mixed Transition‐Metal Oxides: Design, Synthesis, and Energy‐Related Applications

Yuan, C., Wu, H. B., Xie, Y., & Lou, X. W. (. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201303971 · Cited by 2,304

Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices

Long, D.-L., Burkholder, E., & Cronin, L. (2007) · Chem. Soc. Rev. · doi:10.1039/b502666k · Cited by 2,174

Recent Advances in Polyoxometalate-Catalyzed Reactions

Wang, S.-S., & Yang, G.-Y. (2015) · Chemical Reviews · doi:10.1021/cr500390v · Cited by 2,160

Polyoxometalates in Medicine

Rhule, J. T., Hill, C. L., Judd, D. A., & Schinazi, R. F. (1998) · Chemical Reviews · doi:10.1021/cr960396q · Cited by 1,892

Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

Dolbecq, A., Dumas, E., Mayer, C. R., & Mialane, P. (2010) · Chemical Reviews · doi:10.1021/cr1000578 · Cited by 1,755

The Artificial Leaf

Nocera, D. G. (2012) · Accounts of Chemical Research · doi:10.1021/ar2003013 · Cited by 1,682

Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices

Gao, M.-R., Xu, Y.-F., Jiang, J., & Yu, S.-H. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35310e · Cited by 1,610

Heterogeneous visible light photocatalysis for selective organic transformations

Lang, X., Chen, X., & Zhao, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60188a · Cited by 1,545

Photoelectrocatalytic materials for environmental applications

Zhang, H., Chen, G., & Bahnemann, D. W. (2009) · Journal of Materials Chemistry · doi:10.1039/b821991e · Cited by 960

Strongly Coupled Inorganic/Nanocarbon Hybrid Materials for Advanced Electrocatalysis

Liang, Y., Li, Y., Wang, H., & Dai, H. (2013) · Journal of the American Chemical Society · doi:10.1021/ja3089923 · Cited by 937

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

Proust, A., Thouvenot, R., & Gouzerh, P. (2008) · Chemical Communications · doi:10.1039/b715502f · Cited by 898

Magnetic polyoxometalates: from molecular magnetism to molecular spintronics and quantum computing

Clemente-Juan, J. M., Coronado, E., & Gaita-Ariño, A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35205b · Cited by 765

Synthesis, structures and applications of electron-rich polyoxometalates

Gumerova, N. I., & Rompel, A. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0112 · Cited by 688

Oxygen electrocatalysts for water electrolyzers and reversible fuel cells: status and perspective

Park, S., Shao, Y., Liu, J., & Wang, Y. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22554a · Cited by 578

Structure, properties and reactivity of polyoxometalates: a theoretical perspective

López, X., Carbó, J. J., Bó, C., & Poblet, J. M. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35168d · Cited by 509

Noble Metals in Polyoxometalates

Izarova, N. V., Pope, M. T., & Kortz, U. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201202750 · Cited by 404

Hybrid polyoxometalate materials for photo(electro-) chemical applications

Walsh, J. J., Bond, A. M., Forster, R. J., & Keyes, T. E. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.06.016 · Cited by 384

The Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows “Bio-POM”

Blazevic, A., & Rompel, A. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.07.001 · Cited by 320

Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups

Zhang, J., Song, Y.-F., Cronin, L., & Liu, T. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805644a · Cited by 305

Semimetal-functionalised polyoxovanadates

Monakhov, K. Y., Bensch, W., & Kögerler, P. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00531k · Cited by 290

A Coordination Network That Catalyzes O2-Based Oxidations

Han, J. W., & Hill, C. L. (2007) · Journal of the American Chemical Society · doi:10.1021/ja069319v · Cited by 269

The use of polyoxometalates in protein crystallography – An attempt to widen a well-known bottleneck

Bijelic, A., & Rompel, A. (2015) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.03.018 · Cited by 254

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring‐Opening Polymerization of Cyclic Esters

Guillaume, S. M., Kirillov, E., Sarazin, Y., & Carpentier, J. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500613 · Cited by 251

Polyoxometalate – conductive polymer composites for energy conversion, energy storage and nanostructured sensors

Herrmann, S., Ritchie, C., & Streb, C. (2015) · Dalton Transactions · doi:10.1039/c4dt03763d · Cited by 246

Polyoxometalates containing late transition and noble metal atoms

Putaj, P., & Lefebvre, F. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2011.01.030 · Cited by 217

Developing Remote Metal Binding Sites in Heteropolymolybdates

Marcoux, P. R., Hasenknopf, B., Vaissermann, J., & Gouzerh, P. (2003) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200200677 · Cited by 196

Inorganic–Organic Hybrid Vesicles with Counterion- and pH-Controlled Fluorescent Properties

Li, D., Song, J., Yin, P., Simotwo, S., Bassler, A. J., Aung, Y., Roberts, J. E., Hardcastle, K. I., Hill, C. L., & Liu, T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja204034g · Cited by 194

Coordination compounds of polyoxovanadates with a hexametalate core. Chemical and structural characterization of [VV6O13[(OCH2)3CR]2]2-, [VV6O11(OH)2[(OCH2)3CR]2], [VIV4VV2O9(OH)4[(OCH2)3CR]2]2-, and [VIV6O7(OH)6](OCH2)3CR]2]2-

Chen, Q., Goshorn, D. P., Scholes, C. P., Tan, X. L., & Zubieta, J. A. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00038a033 · Cited by 193

Inorganic–organic hybrid polymer with multiple redox for high-density data storage

Hu, B., Wang, C., Wang, J., Gao, J., Wang, K., Wu, J., Zhang, G., Cheng, W., Venkateswarlu, B., Wang, M., et al. (2014) · Chem. Sci. · doi:10.1039/c4sc00823e · Cited by 183

Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion

Song, Y., McMillan, N., Long, D., Kane, S., Malm, J., Riehle, M. O., Pradeep, C. P., Gadegaard, N., & Cronin, L. (2009) · Journal of the American Chemical Society · doi:10.1021/ja807091v · Cited by 171

Direct Synthesis of Ordered Macroporous Silica Materials Functionalized with Polyoxometalate Clusters

Schroden, R. C., Blanford, C. F., Melde, B. J., Johnson, B. J. S., & Stein, A. (2001) · Chemistry of Materials · doi:10.1021/cm000830b · Cited by 161

Smart Self‐Assemblies Based on a Surfactant‐Encapsulated Photoresponsive Polyoxometalate Complex

Yan, Y., Wang, H., Li, B., Hou, G., Yin, Z., Wu, L., & Yam, V. W. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004143 · Cited by 142

Synthesis and properties of polyoxometalates based inorganic-organic polymers

Judeinstein, P. (1992) · Chemistry of Materials · doi:10.1021/cm00019a002 · Cited by 141

Coupled Sensitizer–Catalyst Dyads: Electron‐Transfer Reactions in a Perylene–Polyoxometalate Conjugate

Odobel, F., Séverac, M., Pellegrin, Y., Blart, E., Fosse, C., Cannizzo, C., Mayer, C. R., Elliott, K. J., & Harriman, A. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200801880 · Cited by 140

Palladium(II) Containing γ-Keggin Silicodecatungstate That Efficiently Catalyzes Hydration of Nitriles

Hirano, T., Uehara, K., Kamata, K., & Mizuno, N. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3006012 · Cited by 140

Incorporation of Magnetic Nanoparticles in New Hybrid Networks Based on Heteropolyanions and Polyacrylamide

Mayer, C. R., Cabuil, V., Lalot, T., & Thouvenot, R. (1999) · Angewandte Chemie International Edition · Cited by 139

Redox properties of polyoxometalates: new insights on the anion charge effect

López, X., Fernández, J. A., & Poblet, J. M. (2005) · Dalton Transactions · doi:10.1039/b507599h · Cited by 132

Synthesis of Polyoxometalate−Polymer Hybrid Polymers and Their Hybrid Vesicular Assembly

Han, Y., Xiao, Y., Zhang, Z., Liu, B., Zheng, P., He, S., & Wang, W. (2009) · Macromolecules · doi:10.1021/ma9011686 · Cited by 131

Synthesis and Photocatalytic Properties of Mixed Polyoxometalate−Porphyrin Copolymers Obtained from Anderson-Type Polyoxomolybdates

Schaming, D., Allain, C., Farha, R., Goldmann, M., Lobstein, S., Giraudeau, A., Hasenknopf, B., & Ruhlmann, L. (2009) · Langmuir · doi:10.1021/la903564d · Cited by 126

Intramolecular Electron Transfer Reactions Observed for Dawson-Type Polyoxometalates Covalently Linked to Porphyrin Residues

Harriman, A., Elliott, K. J., Alamiry, M. A. H., Pleux, L. L., Séverac, M., Pellegrin, Y., Blart, E., Fosse, C., Cannizzo, C., Mayer, C. R., et al. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp900643m · Cited by 125

Hybrid Materials Based on the Embedding of Organically Modified Transition Metal Oxoclusters or Polyoxometalates into Polymers for Functional Applications: A Review

Carraro, M., & Gross, S. (2014) · Materials · doi:10.3390/ma7053956 · Cited by 117

Hierarchical Self-Assembly of Polyoxometalate-Based Hybrids Driven by Metal Coordination and Electrostatic Interactions: From Discrete Supramolecular Species to Dense Monodisperse Nanoparticles

Izzet, G., Abécassis, B., Brouri, D., Piot, M., Matt, B., Serapian, S. A., Bó, C., & Proust, A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00972 · Cited by 115

A porphyrin–polyoxometallate bio-inspired mimic for artificial photosynthesis

Elliott, K. J., Harriman, A., Pleux, L. L., Pellegrin, Y., Blart, E., Mayer, C. R., & Odobel, F. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b905548g · Cited by 101

Manipulation of Self-Assembled Nanostructure Dimensions in Molecular Janus Particles

Liu, H., Luo, J., Shan, W., Guo, D. L., Wang, J., Hsu, C., Huang, M., Zhang, W., Lotz, B., Zhang, W., et al. (2016) · ACS Nano · doi:10.1021/acsnano.6b01336 · Cited by 99

Polyoxometalate–biomolecule conjugates: A new approach to create hybrid drugs for cancer therapeutics

Yang, H., Cheng, Y.-X., Su, M.-M., Xiao, Y., Hu, M., Wang, W., & Wang, Q. (2013) · Bioorganic & Medicinal Chemistry Letters · doi:10.1016/j.bmcl.2012.12.081 · Cited by 95

Target Delivery of a Novel Antitumor Organoplatinum(IV)‐Substituted Polyoxometalate Complex for Safer and More Effective Colorectal Cancer Therapy In Vivo

Sun, T., Cui, W., Yan, M., Qin, G., Guo, W., Gu, H., Liu, S., & Wu, Q. (2016) · Advanced Materials · doi:10.1002/adma.201601778 · Cited by 94

Synthesis, Characterization, and Photochemical Behavior of {Ru(arene)}2+Derivatives of α-[PW11O39]7-: An Organometallic Way to Ruthenium-Substituted Heteropolytungstates

Artero, V., Laurencin, D., Villanneau, R., Thouvenot, R., Herson, P., Gouzerh, P., & Proust, A. (2005) · Inorganic Chemistry · doi:10.1021/ic0482180 · Cited by 90

Substance of Civilization: Materials and Human History from the Stone Age to the Age of Silicon

Cohen, E. A., & Sass, S. L. (1998) · Foreign Affairs · doi:10.2307/20048999 · Cited by 89

Organometal hydroxide route to [(C5Me5)Rh]4(V6O19)

Chae, H. K., Klemperer, W. G., & Day, V. W. (1989) · Inorganic Chemistry · doi:10.1021/ic00307a001 · Cited by 88

A novel polyoxometalate-functionalized mesoporous hybrid silica: synthesis and characterization

Zhang, R., & Yang, C. L. (2008) · Journal of Materials Chemistry · doi:10.1039/b800025e · Cited by 75

Charge-Transfer Hybrids Containing Covalently Bonded Polyoxometalates and Ferrocenyl Units

Kang, J., Nelson, J. A., Lü, M. K., Xie, B., Peng, Z., & Powell, D. R. (2004) · Inorganic Chemistry · doi:10.1021/ic049250x · Cited by 69

Copolymerization of Divinylsilyl‐11‐silicotungstic Acid with Butyl Acrylate and Hexanediol Diacrylate: Synthesis of a Highly Proton‐Conductive Membrane for Fuel‐Cell Applications

Horan, J. L., Genupur, A., Ren, H. J., Sikora, B. J., Kuo, M., Meng, F., Dec, S. F., Haugen, G. M., Yandrasits, M., Hamrock, S. J., et al. (2009) · ChemSusChem · doi:10.1002/cssc.200800237 · Cited by 59

Orbital Engineering: Photoactivation of an Organofunctionalized Polyoxotungstate

Cameron, J. M., Fujimoto, S., Kastner, K., Wei, R., Robinson, D., Sans, V., Newton, G. N., & Oshio, H. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201605021 · Cited by 51

Control of the Grafting of Hybrid Polyoxometalates on Metal and Carbon Surfaces: Toward Submonolayers

Gam‐Derouich, S., Rinfray, C., Izzet, G., Pinson, J., Gallet, J., Kanoufi, F., Proust, A., & Combellas, C. (2014) · Langmuir · doi:10.1021/la500067e · Cited by 47

A click chemistry approach to the efficient synthesis of polyoxometalate–polymer hybrids with well-defined structures

Hu, M., Xia, N., Yu, W., Ma, C., Tang, J., Hou, Z., Zheng, P., & Wang, W. (2012) · Polymer Chemistry · doi:10.1039/c2py00546h · Cited by 46

New Polyoxometalates Containing Hybrid Polymers and Their Potential for Nano‐Patterning

Kalyani, V., Satyanarayana, V. S. V., Singh, V., Pradeep, C. P., Ghosh, S., Sharma, S. K., & Gonsalves, K. E. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201405369 · Cited by 46

Stabilization of Palladium Nanoparticles by Polyoxometalates Appended with Alkylthiol Tethers and their Use as Binary Catalysts for Liquid Phase Aerobic Oxydehydrogenation

bruyn, M. D., & Neumann, R. (2007) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200600613 · Cited by 42

A processable hybrid supramolecular polymer formed by base pair modified polyoxometalate clusters

He, Z., Li, B., Ai, H., Li, H., & Wu, L. (2013) · Chemical Communications · doi:10.1039/c3cc44718a · Cited by 40

A comparative study of oxidation of alkanes and alkenes by hydrogen peroxide catalyzed by Cu(salen) complex covalently bound to a Keggin type polyoxometalate and its neat counterpart

Mirkhani, V., Moghadam, M., Tangestaninejad, S., Mohammadpoor‐Baltork, I., & Rasouli, N. (2008) · Catalysis Communications · doi:10.1016/j.catcom.2008.05.040 · Cited by 35

Manipulation of Ordered Nanostructures of Protonated Polyoxometalate through Covalently Bonded Modification

Wang, Y., Wang, X., Zhang, X., Xia, N., Liu, B., Yang, J., Yu, W., Hu, M., Yang, M., & Wang, W. (2010) · Chemistry - A European Journal · doi:10.1002/chem.201001674 · Cited by 35

Diversified polyoxovanadate derivatives obtained by copper( i )-catalysed azide–alkyne cycloaddition reaction: their synthesis and structural characterization

Jia, H., Li, Q., Bayaguud, A., Huang, Y., She, S., Chen, K., & Wei, Y. (2017) · Dalton Transactions · doi:10.1039/c7dt03822d · Cited by 34

Amphiphilic Polyoxometalates for the Controlled Synthesis of Hybrid Polystyrene Particles with Surface Reactivity

de la Haye, J. L., Guigner, J., Marceau, É., Ruhlmann, L., Hasenknopf, B., Lacôte, E., & Rieger, J. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201405708 · Cited by 32

A poly(polyoxometalate)-b-poly(hexanoic acid) block copolymer: synthesis, self-assembled micelles and catalytic activity

Miao, W., Yi, A., Yan, Y., Ren, L.-J., Chen, D., Wang, C., & Wang, W. (2015) · Polymer Chemistry · doi:10.1039/c5py00855g · Cited by 28

Inserting polyoxomolybdate cluster into poly(ɛ-caprolactone) to create a class of new heteropolymer: Synthesis and supramolecular structures

Xia, N., Yu, W., Wang, Y., Han, Y., Zheng, P., Wang, W., Sakaguchi, G., Matsuda, K., Saijo, K., Takenaka, M., et al. (2011) · Polymer · doi:10.1016/j.polymer.2011.02.018 · Cited by 27

Metallopolymers from organically modified polyoxometalates (MOMPs): A review

Yan, J., Zheng, X., Yao, J., Xu, P., Miao, Z., Li, J., Lv, Z., Zhang, Q., & Yan, Y. (2019) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2019.01.012 · Cited by 26

Electrochemical primer extension based on polyoxometalate electroactive labels for multiplexed detection of single nucleotide polymorphisms

Chahin, N., Uribe, L. A., Debela, A. M., Thorimbert, S., Hasenknopf, B., Ortiz, M., Katakis, I., & O’Sullivan, C. K. (2018) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2018.06.014 · Cited by 17

Redox chemistry of ruthenium ions in mono-substituted Keggin tungstophosphate: a new synthetic extension for ruthenium derivatives based on [PW 11 O 39 Ru VI N] 4−

Liu, B., Yan, J., Wang, Y., & Yi, X. (2015) · Dalton Transactions · doi:10.1039/c5dt02826d · Cited by 16

Grand Challenges in Computational Materials Science: From Description to Prediction at all Scales

Heine, T. (2014) · Frontiers in Materials · doi:10.3389/fmats.2014.00007 · Cited by 13

Using a facile experimental manipulation to fabricate and tune a polyoxometalate-cholesterol hybrid material

Yang, H., Liu, L., Yuan, X., & Wu, S.-M. (2017) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2017.02.026 · Cited by 9

Molecular Metal Oxides in Protein Cages/Cavities

Müller, A., & Rehder, D. (2013) · Wiley eBooks · doi:10.1002/9781118571811.ch2 · Cited by 3