Hierarchical chemomechanical encoding of multi-responsive hydrogel actuators via 3D printing
Open accessAbstract
A family of multi-responsive hydrogel-based actuators capable of rapid and controllable motion in response to any immediate environmental change is herein demonstrated towards the 3D-printing of functionally graded structures that are encoded with anisotropic swelling behavior.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Synthetic hydrogels (PEG, PVA, PHEMA, PAM) with enhanced mechanical deformability and controlled structure and degradation can be used in sensors, actuators, soft robots, and wastewater treatment.
“synthetic hydrogels with enhanced mechanical deformability and controlled structure and degradation, such as polyethylene glycol (PEG), polyvinyl alcohol (PVA), poly(2-hydroxyethyl methacrylate) (PHEMA) and polyacrylamide (PAM), can be used in sensors, actuators, soft robots, and wastewater treatment”
From Functionalized Hydrogel-Based Wearable Gas and Humidity Sensors. (2023) · cites this paper as [99]
Cites
Emerging applications of stimuli-responsive polymer materials
Stuart, M. A. C., Huck, W. T. S., Genzer, J., Müller, M., Ober, C. K., Stamm, M., Sukhorukov, G. B., Szleifer, I. G., Tsukruk, V. V., Urban, M. W., et al. (2010) · Nature Materials · doi:10.1038/nmat2614 · Cited by 5,720 · see citing works
Gibson, I., Rosen, D., & Stucker, B. (2015) · doi:10.1007/978-1-4939-2113-3 · Cited by 3,299 · see citing works
Sydney Gladman, A., Matsumoto, E. A., Nuzzo, R. G., Mahadevan, L., & Lewis, J. A. (2016) · Nature Materials · doi:10.1038/nmat4544 · Cited by 3,027 · see citing works
Tanaka, T., & Fillmore, D. J. (1979) · The Journal of Chemical Physics · doi:10.1063/1.437602 · Cited by 1,630 · see citing works
New directions in thermoresponsive polymers
Roy, D., Brooks, W. L. A., & Sumerlin, B. S. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35499g · Cited by 1,311 · see citing works
Momeni, F., M.Mehdi Hassani.N, S., Liu, X., & Ni, J. (2017) · Materials & Design · doi:10.1016/j.matdes.2017.02.068 · Cited by 1,165 · see citing works
Forterre, Y., Skotheim, J. M., Dumais, J., & Mahadevan, L. (2005) · Nature · doi:10.1038/nature03185 · Cited by 1,093 · see citing works
Functionally graded materials: A review of fabrication and properties
Naebe, M., & Shirvanimoghaddam, K. (2016) · Applied Materials Today · doi:10.1016/j.apmt.2016.10.001 · Cited by 987 · see citing works
Hydraulic hydrogel actuators and robots optically and sonically camouflaged in water
Yuk, H., Lin, S., Ma, C., Takaffoli, M., Fang, N. X., & Zhao, X. (2017) · Nature Communications · doi:10.1038/ncomms14230 · Cited by 986 · see citing works
A method for building self-folding machines
Felton, S. M., Tolley, M. T., Demaine, E. D., Rus, D. L., & Wood, R. J. (2014) · Science · doi:10.1126/science.1252610 · Cited by 962 · see citing works
3D printing of soft robotic systems
Wallin, T. J., Pikul, J. H., & Shepherd, R. F. (2018) · Nature Reviews Materials · doi:10.1038/s41578-018-0002-2 · Cited by 941 · see citing works
Self-citationDesigning Responsive Buckled Surfaces by Halftone Gel Lithography
Kim, J., Hanna, J. A., Byun, M., Santangelo, C. D., & Hayward, R. C. (2012) · Science · doi:10.1126/science.1215309 · Cited by 873 · see citing works
Rizwan, M., Yahya, R., Hassan, A., Yar, M., Azzahari, A., Selvanathan, V., Sonsudin, F., & Abouloula, C. (2017) · Polymers · doi:10.3390/polym9040137 · Cited by 844 · see citing works
Geometry and Mechanics in the Opening of Chiral Seed Pods
Armon, S., Efrati, E., Raz Kupferman, B., & Sharon, E. (2011) · Science · doi:10.1126/science.1203874 · Cited by 785 · see citing works
Hydrogel-based actuators: possibilities and limitations
Ionov, L. (2014) · Materials Today · doi:10.1016/j.mattod.2014.07.002 · Cited by 679 · see citing works
Nano-structured smart hydrogels with rapid response and high elasticity
Lie-wen, X., Xie, R., Ju, X., Wang, W., Chen, Q., & Chu, L. (2013) · Nature Communications · doi:10.1038/ncomms3226 · Cited by 671 · see citing works
Wu, Z. L., Moshe, M., Greener, J., Thérien‐Aubin, H., Nie, Z., Sharon, E., & Kumacheva, E. (2013) · Nature Communications · doi:10.1038/ncomms2549 · Cited by 607 · see citing works
Active printed materials for complex self-evolving deformations
Raviv, D., Zhao, W., McKnelly, C., Papadopoulou, A., Kadambi, A., Shi, B., Hirsch, S., Dikovsky, D., Zyracki, M., Olguin, C., et al. (2014) · Scientific Reports · doi:10.1038/srep07422 · Cited by 568 · see citing works
An instant multi-responsive porous polymer actuator driven by solvent molecule sorption
Zhao, Q., Dunlop, J., Qiu, X., Huang, F., Zhang, Z., Heyda, J., Dzubiella, J., Antonietti, M., & Yuan, J. (2014) · Nature Communications · doi:10.1038/ncomms5293 · Cited by 513 · see citing works
Sequential Self-Folding Structures by 3D Printed Digital Shape Memory Polymers
Mao, Y., Yu, K., Isakov, M., Wu, J., Dunn, M. L., & Qi, H. J. (2015) · Scientific Reports · doi:10.1038/srep13616 · Cited by 511 · see citing works
Ma, C., Lü, W., Yang, X., He, J., Le, X., Wang, L., Zhang, J., Serpe, M. J., Huang, Y., & Chen, T. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201704568 · Cited by 486 · see citing works
Biomimetic Hydrogel‐Based Actuating Systems
Ionov, L. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201203692 · Cited by 468 · see citing works
Reversible patterning and actuation of hydrogels by electrically assisted ionoprinting
Palleau, É., Morales, D., Dickey, M. D., & Velev, O. D. (2013) · Nature Communications · doi:10.1038/ncomms3257 · Cited by 445 · see citing works
4D printing of polymeric materials for tissue and organ regeneration
Miao, S., Castro, N., Nowicki, M., Xia, L., Cui, H., Zhou, X., Zhu, W., Lee, S.-J., Sarkar, K., Vozzi, G., et al. (2017) · Materials Today · doi:10.1016/j.mattod.2017.06.005 · Cited by 408 · see citing works
Chen, Y., Liu, Z., Yang, C., Wang, W., Ju, X., Xie, R., & Chu, L. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201500420 · Cited by 381 · see citing works
Calculation of crosslink density in short chain networks
Hill, L. W. (1997) · Progress in Organic Coatings · doi:10.1016/s0300-9440(97)00081-7 · Cited by 376 · see citing works
Multi-material stereolithography
Choi, J.-W., Kim, H.-C., & Wicker, R. B. (2010) · Journal of Materials Processing Technology · doi:10.1016/j.jmatprotec.2010.10.003 · Cited by 307 · see citing works
Mimosa inspired bilayer hydrogel actuator functioning in multi-environments
Zheng, J., Xiao, P., Le, X., Lü, W., Théato, P., Ma, C., Du, B., Zhang, J., Huang, Y., & Chen, T. (2017) · Journal of Materials Chemistry C · doi:10.1039/c7tc04879c · Cited by 290 · see citing works
Self-folding devices and materials for biomedical applications
Randall, C. L., Gultepe, E., & Gracias, D. H. (2011) · Trends in biotechnology · doi:10.1016/j.tibtech.2011.06.013 · Cited by 269 · see citing works
3D printing and additive manufacturing : principles and applications
Chua, C. K., & Leong, K. F. (2015) · Cited by 246 · see citing works
Soft microorigami: self-folding polymer films
Ionov, L. (2011) · Soft Matter · doi:10.1039/c1sm05476g · Cited by 233 · see citing works
Smart hydrogels as functional biomimetic systems
Lim, H. L., Hwang, Y., Kar, M., & Varghese, S. (2014) · Biomaterials Science · doi:10.1039/c3bm60288e · Cited by 232 · see citing works
Fabrication of Temperature‐Responsive Bending Hydrogels with a Nanostructured Gradient
Asoh, T., Matsusaki, M., Kaneko, T., & Akashi, M. (2008) · Advanced Materials · doi:10.1002/adma.200702727 · Cited by 186 · see citing works
Variable property rapid prototyping
Oxman, N. (2011) · Virtual and Physical Prototyping · doi:10.1080/17452759.2011.558588 · Cited by 183 · see citing works
Ionov, L. (2014) · Langmuir · doi:10.1021/la503407z · Cited by 180 · see citing works
Technological considerations for 4D printing: An overview
Pei, E., & Loh, G. H. (2018) · Progress in Additive Manufacturing · doi:10.1007/s40964-018-0047-1 · Cited by 171 · see citing works
Advanced Self-Deployable Structures for Space Applications
Sokolowski, W. M., & Tan, S. C. (2007) · Journal of Spacecraft and Rockets · doi:10.2514/1.22854 · Cited by 160 · see citing works
Reversible bidirectional bending of hydrogel-based bilayer actuators
Li, X., Cai, X., Gao, Y., & Serpe, M. J. (2017) · Journal of Materials Chemistry B · doi:10.1039/c7tb00426e · Cited by 147 · see citing works
Pei, Y., Chen, J., Yang, L., Shi, L., Tao, Q., Hui, B., & Li, J. (2004) · Journal of Biomaterials Science Polymer Edition · doi:10.1163/156856204323046852 · Cited by 125 · see citing works
Programmable Deployment of Tensegrity Structures by Stimulus-Responsive Polymers
Liu, K., Wu, J., Paulino, G. H., & Qi, H. J. (2017) · Scientific Reports · doi:10.1038/s41598-017-03412-6 · Cited by 121 · see citing works
Actuating and memorizing bilayer hydrogels for a self-deformed shape memory function
Wang, L., Jian, Y., Le, X., Lü, W., Ma, C., Zhang, J., Huang, Y., Huang, C., & Chen, T. (2018) · Chemical Communications · doi:10.1039/c7cc09456f · Cited by 115 · see citing works
Polymer Gradient Materials: Can Nature Teach Us New Tricks?
Claußen, K. U., Scheibel, T., Schmidt, H., & Giesa, R. (2012) · Macromolecular Materials and Engineering · doi:10.1002/mame.201200032 · Cited by 97 · see citing works
Multi-material, multi-technology stereolithography
Wicker, R. B., & MacDonald, E. W. (2012) · Virtual and Physical Prototyping · doi:10.1080/17452759.2012.721119 · Cited by 93 · see citing works
Grayscale gel lithography for programmed buckling of non-Euclidean hydrogel plates
Na, J., Bende, N. P., Bae, J., Santangelo, C. D., & Hayward, R. C. (2016) · Soft Matter · doi:10.1039/c6sm00714g · Cited by 90 · see citing works
Actively-moving materials based on stimuli-responsive polymers
Ionov, L. (2010) · Journal of Materials Chemistry · doi:10.1039/b922718k · Cited by 86 · see citing works
Liu, Y., Takafuji, M., Ihara, H., Zhu, M., Yang, M., Gu, K. X., & Guo, W. (2012) · Soft Matter · doi:10.1039/c2sm07206h · Cited by 76 · see citing works
Reprogrammable, magnetically controlled polymeric nanocomposite actuators
Wang, L., Razzaq, M. Y., Rudolph, T., Heuchel, M., Nöchel, U., Mansfeld, U., Jiang, Y., Gould, O. E. C., Behl, M., Kratz, K. L., et al. (2018) · Materials Horizons · doi:10.1039/c8mh00266e · Cited by 63 · see citing works
Digital anisotropy: A variable elasticity rapid prototyping platform
Oxman, N., Tsai, E., & Firstenberg, M. (2012) · Virtual and Physical Prototyping · doi:10.1080/17452759.2012.731369 · Cited by 59 · see citing works
Ionoprinted Multi-Responsive Hydrogel Actuators
Morales, D., Podolsky, I., Mailen, R. W., Shay, T., Dickey, M. D., & Velev, O. D. (2016) · Micromachines · doi:10.3390/mi7060098 · Cited by 58 · see citing works
Another Lesson from Plants: The Forward Osmosis-Based Actuator
Sinibaldi, E., Argiolas, A., Puleo, G. L., & Mazzolai, B. (2014) · PLoS ONE · doi:10.1371/journal.pone.0102461 · Cited by 54 · see citing works
Petruš̆̌̌̌ić, S., Lewandowski, M., Giraud, S., Jovanĉić, P., Bugarski, B., Ostojić, S., & Končar, V. (2011) · Journal of Applied Polymer Science · doi:10.1002/app.35122 · Cited by 36 · see citing works
Super Water-Retainer Hydrogels: Crosslinked Acrylamide/Succinic Acid Copolymers
Saraydın, D., Karadağ, E., & Güven, O. (1997) · Polymer Journal · doi:10.1295/polymj.29.631 · Cited by 31 · see citing works
Coupek, D., Kovaleva, D., Christof, H., Wurst, K.-H., Verl, A. W., Sobek, W., Haase, W., Gresser, G. T., & Lechler, A. (2016) · Biologically-inspired systems · doi:10.1007/978-3-319-46374-2_16 · Cited by 6 · see citing works
Flagged first, then by citations
1 of the 54 references couldn’t be matched to a known paper.
Cited by
Sorted by citations
3D printing of hydrogels: Rational design strategies and emerging biomedical applications
Li, J., Wu, C., Chu, P. K.-H., & Gelinsky, M. (2020) · Materials Science and Engineering R Reports · doi:10.1016/j.mser.2020.100543 · Cited by 867 · see citing works
4D Printing of Hydrogels: A Review
Champeau, M., Heinze, D. A., Viana, T. N., de Souza, E. R., Chinellato, A. C., & Titotto, S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201910606 · Cited by 445 · see citing works
3D Printing Materials for Soft Robotics
Keneth, E. S., Kamyshny, A. L., Totaro, M., Beccai, L., & Magdassi, S. (2020) · Advanced Materials · doi:10.1002/adma.202003387 · Cited by 356 · see citing works
Recent advances of additive manufacturing in implant fabrication – A review
Mobarak, M. H., Islam, M. A., Hossain, N., Mahmud, M. Z. A., Rayhan, M. T., Nishi, N. J., & Chowdhury, M. A. (2023) · Applied Surface Science Advances · doi:10.1016/j.apsadv.2023.100462 · Cited by 313 · see citing works
3D‐Printed Anisotropic Polymer Materials for Functional Applications
Chen, J., Liu, X., Tian, Y., Zhu, W., Yan, C., Shi, Y., Kong, L. B., Qi, H. J., & Zhou, K. (2021) · Advanced Materials · doi:10.1002/adma.202102877 · Cited by 284 · see citing works
Stimuli‐responsive hydrogels: Fabrication and biomedical applications
Li, Z., Zhou, Y., Li, T., Zhang, J., & Tian, H. (2021) · Open Research (University of Surrey) · doi:10.1002/viw.20200112 · Cited by 275 · see citing works
Smart polymers and nanocomposites for 3D and 4D printing
Falahati, M., Ahmadvand, P., Safaee, S., Chang, Y., Lyu, Z., Chen, R. K., Li, L., & Lin, Y. (2020) · Materials Today · doi:10.1016/j.mattod.2020.06.001 · Cited by 251 · see citing works
Functionalized Hydrogel-Based Wearable Gas and Humidity Sensors.
Luo, Y., Li, J., Ding, Q., Wang, H., Liu, C., & Wu, J. (2023) · Nano-Micro Letters · doi:10.1007/s40820-023-01109-2 · Cited by 236 · see citing works
Recent Advances in Stimuli‐Responsive Shape‐Morphing Hydrogels
Liu, X., Gao, M. X., Chen, J., Guo, S., Zhu, W., Bai, L., Zhai, W., Du, H., Wu, H. P., Yan, C., et al. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202203323 · Cited by 233 · see citing works
A Review of Multi-Material 3D Printing of Functional Materials via Vat Photopolymerization
Shaukat, U., Rossegger, E., & Schlögl, S. (2022) · Polymers · doi:10.3390/polym14122449 · Cited by 233 · see citing works
Closed-loop 4D-printed soft robots
Zolfagharian, A., Kaynak, A., & Kouzani, A. Z. (2019) · Materials & Design · doi:10.1016/j.matdes.2019.108411 · Cited by 231 · see citing works
All-Lignin-Based Hydrogel with Fast pH-Stimuli Responsiveness for Mechanical Switching and Actuation
Dai, L., Ma, M., Xu, J., Si, C., Wang, X., Liu, Z., & Ni, Y. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c01198 · Cited by 214 · see citing works
Hydrogel: Diversity of Structures and Applications in Food Science
Li, J., Jia, X. T., & Yin, L. (2021) · Food Reviews International · doi:10.1080/87559129.2020.1858313 · Cited by 211 · see citing works
3D Printing of Polymer Hydrogels—From Basic Techniques to Programmable Actuation
Puza, F., & Lienkamp, K. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202205345 · Cited by 148 · see citing works
Multimaterial Vat Polymerization Additive Manufacturing
Sampson, K. L., Deore, B., Go, A., Nayak, M. A., Orth, A., Gallerneault, M., Malenfant, P. R. L., & Paquet, C. (2021) · ACS Applied Polymer Materials · doi:10.1021/acsapm.1c00262 · Cited by 140 · see citing works
3D printing of stimuli-responsive hydrogel materials: Literature review and emerging applications
Arif, Z. U., Khalid, M. Y., Tariq, A., Hossain, M., & Umer, R. (2023) · Giant · doi:10.1016/j.giant.2023.100209 · Cited by 139 · see citing works
Catalyst-Free Partially Bio-Based Polyester Vitrimers
Debnath, S., Kaushal, S., & Ojha, U. (2020) · ACS Applied Polymer Materials · doi:10.1021/acsapm.0c00016 · Cited by 125 · see citing works
Zhao, W., Wang, Z., Zhang, J., Wang, X., Xu, Y., Ding, N., & Peng, Z. (2021) · Advanced Materials Technologies · doi:10.1002/admt.202001218 · Cited by 122 · see citing works
Bioinspired gradient structured soft actuators: From fabrication to application
Liu, H., Liu, R., Chen, K., Liu, Y., Zhao, Y., Cui, X., & Tian, Y. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.141966 · Cited by 121 · see citing works
3D printing hydrogels for actuators: A review
Zhang, A., Wang, F., Lian, C., Wei, X., Xue, M., Yang, F. L., & Jiang, S. (2021) · Chinese Chemical Letters · doi:10.1016/j.cclet.2021.03.073 · Cited by 112 · see citing works
Calafel, I., Criado‐Gonzalez, M., Aguirresarobe, R., Fernández, M., & Mijangos, C. (2025) · Materials Advances · doi:10.1039/d5ma00019j · Cited by 123 · see citing works
Programmable Mechanically Active Hydrogel‐Based Materials
Dong, Y., Ramey‐Ward, A. N., & Salaita, K. S. (2021) · Advanced Materials · doi:10.1002/adma.202006600 · Cited by 109 · see citing works
Lithography-based 3D printing of hydrogels
Dhand, A. P., Davidson, M. D., & Burdick, J. A. (2024) · Nature Reviews Bioengineering · doi:10.1038/s44222-024-00251-9 · Cited by 104 · see citing works
Wei, X., Lian, C., Wang, Y., Sun, Y., Ma, C., Yang, X., Jiang, S., & Duan, G. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.134258 · Cited by 103 · see citing works
Control-Based 4D Printing: Adaptive 4D-Printed Systems
Zolfagharian, A., Kaynak, A., Bodaghi, M., Kouzani, A. Z., Gharaie, S., & Nahavandi, S. (2020) · Applied Sciences · doi:10.3390/app10093020 · Cited by 105 · see citing works
Sadraei, A., & Naghib, S. M. (2024) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1080/15583724.2024.2427184 · Cited by 98 · see citing works
Shahbazi, M., Jäger, H., Ettelaie, R., Mohammadi, A., & Kashi, P. A. (2023) · Additive manufacturing · doi:10.1016/j.addma.2023.103598 · Cited by 95 · see citing works
3D‐Printed Polymeric Biomaterials for Health Applications
Zhu, Y., Guo, S., Ravichandran, D., Ramanathan, A., Sobczak, M. T., Sacco, A. F., Patil, D., Thummalapalli, S. V., Pulido, T. V., Lancaster, J. N., et al. (2024) · Advanced Healthcare Materials · doi:10.1002/adhm.202402571 · Cited by 100 · see citing works
Momeni, F., & Ni, J. (2020) · Engineering · doi:10.1016/j.eng.2020.01.015 · Cited by 94 · see citing works
Tao, Y., Lee, Y.-C., Liu, H., Zhang, X., Cui, J., Mondoa, C., Babaei, M., Santillan, J., Wang, G., Luo, D., et al. (2021) · Science Advances · doi:10.1126/sciadv.abf4098 · Cited by 92 · see citing works
Hydrogel prepared by 3D printing technology and its applications in the medical field
Liu, C., Xu, N., Zong, Q., Yu, J., & Zhang, P. (2021) · Colloids and Interface Science Communications · doi:10.1016/j.colcom.2021.100498 · Cited by 82 · see citing works
Soft Actuators and Robots Enabled by Additive Manufacturing
Wang, D., Wang, J., Shen, Z., Jiang, C., Zou, J., Dong, L., Fang, N. X., & Gu, G. (2023) · Annual Review of Control Robotics and Autonomous Systems · doi:10.1146/annurev-control-061022-012035 · Cited by 81 · see citing works
Smart Actuators Based on External Stimulus Response
Zheng, Q., Xu, C., Jiang, Z., Zhu, M., Chen, C., & Fu, F. (2021) · Frontiers in Chemistry · doi:10.3389/fchem.2021.650358 · Cited by 77 · see citing works
Yang, M. Y., Chu, L., Zhuang, Y., Cheng, Q., Meng, S., Liu, Z., & Kong, T. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202316456 · Cited by 72 · see citing works
Willemen, N. G. A., Morsink, M. A. J., Veerman, D., da Silva, C. F., Cardoso, J. C., Souto, E. B., & Severino, P. B. (2021) · Bio-Design and Manufacturing · doi:10.1007/s42242-021-00157-0 · Cited by 66 · see citing works
Bioinspired Structures for Soft Actuators
Wei, S., & Ghosh, T. K. (2022) · Advanced Materials Technologies · doi:10.1002/admt.202101521 · Cited by 61 · see citing works
3D‐Printed Stacked Ionic Assemblies for Iontronic Touch Sensors
Odent, J., Baleine, N., Biard, V., Dobashi, Y., Vancaeyzeele, C., Nguyen, G. T. M., Madden, J. D. W., Plesse, C., & Raquez, J. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202210485 · Cited by 60 · see citing works
Self-citationContactless reversible 4D-printing for 3D-to-3D shape morphing
Lee, A. Y., Zhou, A., An, J., Chua, C. K., & Zhang, Y. (2020) · Virtual and Physical Prototyping · doi:10.1080/17452759.2020.1822189 · Cited by 59 · see citing works
Sun, W., Schaffer, S., Dai, K., Yao, L., Feinberg, A. W., & Webster‐Wood, V. A. (2021) · Frontiers in Robotics and AI · doi:10.3389/frobt.2021.673533 · Cited by 55 · see citing works
Cazin, I., Gleirscher, M., Fleisch, M., Berer, M., Sangermano, M., & Schlögl, S. (2022) · Additive manufacturing · doi:10.1016/j.addma.2022.102977 · Cited by 50 · see citing works
Lu, G., Tang, R., Nie, J., & Zhu, X. (2024) · Macromolecular Rapid Communications · doi:10.1002/marc.202300661 · Cited by 46 · see citing works
Programming the time into 3D printing: current advances and future directions in 4D printing
Shen, B., Erol, O., Fang, L., & Kang, S. H. (2019) · Multifunctional Materials · doi:10.1088/2399-7532/ab54ea · Cited by 46 · see citing works
Decroly, G., Toncheva, A., Blanc, L., Raquez, J., Lessinnes, T., Delchambre, A., & Lambert, P. (2020) · Actuators · doi:10.3390/act9040131 · Cited by 45 · see citing works
Self-citationZhao, Y., Cui, J., Qiu, X., Yan, Y., Zhang, Z., Fang, K., Yang, Y. L., Zhang, X., & Huang, J. S. (2022) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2022.102749 · Cited by 45 · see citing works
3D shape morphing of stimuli-responsive composite hydrogels
Xiao, L., Li, M., Tang, L., Shi, D., Lam, E., & Bae, J. (2023) · Materials Chemistry Frontiers · doi:10.1039/d3qm00856h · Cited by 44 · see citing works
Wan, J., Zhou, S., Mea, H. J., Guo, Y., Ku, H., & Urbina, B. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00480 · Cited by 43 · see citing works
Lin, J., Han, Y., Cui, Y., Zhao, W. D., & Chang, C. (2022) · Composites Part B Engineering · doi:10.1016/j.compositesb.2022.110210 · Cited by 43 · see citing works
Acoustophoretic Liquefaction for 3D Printing Ultrahigh‐Viscosity Nanoparticle Suspensions
Liu, Z., Pan, W., Wang, K., Matia, Y., Xu, A., Barreiros, J. A. L., Darkes‐Burkey, C., Giannelis, E. P., Mengüç, Y., Shepherd, R. F., et al. (2021) · Advanced Materials · doi:10.1002/adma.202106183 · Cited by 37 · see citing works
Self-citationGuo, X., Yang, F., Liu, W., Han, C., Bai, Y., Sun, X., Hao, L., Jiao, W., & Wang, R. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta01892b · Cited by 36 · see citing works
Programmable Auxeticity in Hydrogel Metamaterials via Shape‐Morphing Unit Cells
Skarsetz, O., Slesarenko, V., & Walther, A. (2022) · Advanced Science · doi:10.1002/advs.202201867 · Cited by 36 · see citing works
Multi-thermo responsive double network composite hydrogel for 3D printing medical hydrogel mask
Bauman, L. A., & Zhao, B. (2023) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2023.02.021 · Cited by 36 · see citing works
Material Design for Enhancing Properties of 3D Printed Polymer Composites for Target Applications
Shinde, V. V., Wang, Y., Salek, M. F., Auad, M. L., Beckingham, L. E., & Beckingham, B. S. (2022) · Technologies · doi:10.3390/technologies10020045 · Cited by 34 · see citing works
Three-Dimensional Printing Strategies for Enhanced Hydrogel Applications
Omidian, H., & Mfoafo, K. A. (2024) · Gels · doi:10.3390/gels10040220 · Cited by 30 · see citing works
Long-Fiber Embedded Hydrogel 3D Printing for Structural Reinforcement
Sun, W., Tashman, J. W., Shiwarski, D. J., Feinberg, A. W., & Webster‐Wood, V. A. (2021) · ACS Biomaterials Science & Engineering · doi:10.1021/acsbiomaterials.1c00908 · Cited by 30 · see citing works
Xiao, M., Luo, Y., Chen, H., Wang, H., Yao, D., Wang, D., Pan, Y., Zha, B., Yu, Q., Xie, R., et al. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202522153 · Cited by 29 · see citing works
Lin, J., Zhou, P., Chen, Q., Zhang, W., Luo, Z., & Chen, L. (2022) · Sensors and Actuators B Chemical · doi:10.1016/j.snb.2022.131776 · Cited by 29 · see citing works
4D-Printed Hydrogel Actuators through Diffusion-Path Architecture Design
Pruksawan, S., Lin, Z., Lee, Y. L., Chee, H. L., & Wang, F. (2023) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.3c10112 · Cited by 29 · see citing works
Morph-genetic bamboo-reinforced hydrogel complex for bio-mimetic actuator
Chen, L., Zhang, K., Ahn, J., Wang, F., Sun, Y., Lee, J., Lee, J.-Y., Ma, C., Zhao, H., Duan, G., et al. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.142391 · Cited by 28 · see citing works
One-pot ternary sequential reactions for photopatterned gradient multimaterials
Huang, S., Adelmund, S. M., Pichumani, P. S., Schwartz, J. J., Mengüç, Y., Shusteff, M., & Wallin, T. J. (2023) · Matter · doi:10.1016/j.matt.2023.05.040 · Cited by 26 · see citing works
Self-citationApplication of 4D printing and AI to cardiovascular devices
Faruque, M. O., Lee, Y., Wyckoff, G. J., & Lee, C. H. (2023) · Journal of Drug Delivery Science and Technology · doi:10.1016/j.jddst.2023.104162 · Cited by 26 · see citing works
Programmable materials: Current trends, challenges, and perspectives
Scalet, G. (2024) · Applied Materials Today · doi:10.1016/j.apmt.2024.102372 · Cited by 25 · see citing works
Emerging Applications of Smart Hydrogel Nanocomposites in 3D Printing
Heidari, M., Shahi, F., Afshar, H., Nobre, M. A. L., Dawi, E. A., & Khonakdar, H. A. (2024) · Polymers for Advanced Technologies · doi:10.1002/pat.70021 · Cited by 25 · see citing works
Rossegger, E., Shaukat, U., Moazzen, K., Fleisch, M., Berer, M., & Schlögl, S. (2023) · Polymer Chemistry · doi:10.1039/d3py00333g · Cited by 25 · see citing works
Zheng, Q., Jiang, Z., Xu, X., Xu, C., Zhu, M., Chen, C., & Fu, F. (2021) · ACS Applied Polymer Materials · doi:10.1021/acsapm.1c00335 · Cited by 23 · see citing works
Application of 4D printing and bioprinting in cardiovascular tissue engineering
Zhou, Z., Tang, W., Yang, J., & Fan, C. (2023) · Biomaterials Science · doi:10.1039/d3bm00312d · Cited by 22 · see citing works
Fellin, C. R., & Nelson, A. (2022) · ACS Applied Polymer Materials · doi:10.1021/acsapm.1c01538 · Cited by 21 · see citing works
3D printable and stretchable PVA‐PAAm dual network hydrogel with conductivities for wearable sensors
Wei, F., Duan, T., Yao, L., & Yang, W. (2022) · Journal of Applied Polymer Science · doi:10.1002/app.53468 · Cited by 21 · see citing works
Recent advances in 4D printing of hydrogels
Li, T., Huang, Z., Tsui, C. P., Tang, C. Y., & Deng, Y. (2024) · REVIEWS ON ADVANCED MATERIALS SCIENCE · doi:10.1515/rams-2024-0028 · Cited by 20 · see citing works
Sadraei, A., Naghib, S. M., & Rabiee, N. (2025) · Expert Opinion on Drug Delivery · doi:10.1080/17425247.2025.2466768 · Cited by 21 · see citing works
Tsai, W.-H., & Su, C. (2024) · Analytical Chemistry · doi:10.1021/acs.analchem.3c04961 · Cited by 16 · see citing works
Soft Actuator Based on Metal/Hydrogel Nanocomposites with Anisotropic Structure
Gao, Y., Zhao, X., Han, X., Wang, P., & Zheng, W. J. (2021) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202100117 · Cited by 16 · see citing works
Smart polymers for 3D printing applications: current status and future outlook
Singh, N., Sinha, P., Sinha, D. K., & Banerjee, S. (2025) · Polymer Chemistry · doi:10.1039/d5py00741k · Cited by 16 · see citing works
Development of Hydrogels Fabricated via Stereolithography for Bioengineering Applications
Jeon, Y., Kim, M., & Song, K. H. (2025) · Polymers · doi:10.3390/polym17060765 · Cited by 14 · see citing works
Wu, C., Su, Y.-T., & Su, C. (2023) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2023.115500 · Cited by 13 · see citing works
Insight into constitutive theories of 4D printed polymer materials: a review
Rodriguez-Morales, J. A., Duan, H., Gu, J., Zeng, H., & Sun, H. (2024) · Smart Materials and Structures · doi:10.1088/1361-665x/ad523c · Cited by 12 · see citing works
Photocuring 3D printable self-healing polymers
Zhu, J., Chen, J., An, Z., Kankala, R. K., Chen, A., Wang, S., & Li, Y. (2023) · European Polymer Journal · doi:10.1016/j.eurpolymj.2023.112471 · Cited by 11 · see citing works
Programmable Hydrogel-Based Soft Robotics via Encoded Building Block Design
Pruksawan, S., Chua, Z. A., Chong, Y. T., & Wang, F. (2024) · Actuators · doi:10.3390/act13100383 · Cited by 11 · see citing works
Bonetti, L., Cobianchi, A., Natali, D., Pandini, S., Messori, M., Toselli, M., & Scalet, G. (2024) · Soft Matter · doi:10.1039/d4sm00304g · Cited by 10 · see citing works
Lee, J. H., Hyun, J. E., Kim, J.-S., Yang, J., Zhang, H., Ahn, H., Lee, S., Kim, J. H., & Lim, T. (2024) · Journal of Materials Chemistry B · doi:10.1039/d4tb00209a · Cited by 10 · see citing works
pH-responsive anisotropic hydrogels: A mini review from fabrication to simulation
Li, B. J., Guo, M., Xue, P., Yang, M., Liu, G., & Wang, X. (2025) · Sensors and Actuators A Physical · doi:10.1016/j.sna.2025.116697 · Cited by 10 · see citing works
3D Printed Hydrogels for Soft Robotic Applications
Wu, K., Xiao, J., Li, J., & Wang, Y. (2025) · JOURNAL OF POLYMER MATERIALS · doi:10.32604/jpm.2025.065269 · Cited by 9 · see citing works
Multiresponsive Microgels: Toward an Independent Tuning of Swelling and Surface Properties
Guerron, A., & Giasson, S. (2021) · Langmuir · doi:10.1021/acs.langmuir.1c01269 · Cited by 9 · see citing works
Bioinspired Morphing Mechanisms for Soft Systems: A Review
Rabaux, O., & Jérôme, C. (2024) · Advanced Intelligent Systems · doi:10.1002/aisy.202400331 · Cited by 8 · see citing works
Zhang, H., Huang, S. T., Zhang, Y., Qian, Z., Sheng, J., Zhang, J., Agyenim-Boateng, E., Zhu, M., & Zhou, J. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.162877 · Cited by 8 · see citing works
From 3D to 6D bioprinting: emerging additive manufacturing technologies for biomedical applications
Derhambakhsh, S., Salehi, N., Changizi, S., & Solati‐Hashjin, M. (2025) · Biomedical Materials · doi:10.1088/1748-605x/ae3043 · Cited by 8 · see citing works
Manikandan, N., & Rajesh, P. K. (2023) · Progress in Additive Manufacturing · doi:10.1007/s40964-023-00408-9 · Cited by 7 · see citing works
Li, X., Li, L., Liu, X., & Hu, Y. (2025) · Soft Science · doi:10.20517/ss.2025.47 · Cited by 7 · see citing works
Anisotropic Responsive Microgels Based on the Cholesteric Phase of Chitin Nanocrystals
Lee, S. R., Reichmanis, E., & Srinivasarao, M. (2021) · ACS Macro Letters · doi:10.1021/acsmacrolett.1c00675 · Cited by 7 · see citing works
Klincewicz, F., Kalidindi, S., & Korley, L. T. J. (2024) · RSC Applied Polymers · doi:10.1039/d4lp00032c · Cited by 6 · see citing works
Stimuli‐Responsive Smart Materials for Additive Manufacturing
Pinho, A. C., & Piedade, A. P. (2022) · doi:10.1002/9783527835478.ch9 · Cited by 6 · see citing works
Enhanced thermal response of 3D-printed bilayer hydrogels via nanoclay incorporation
Klincewicz, F., Kalidindi, S., Liu, S., Sangroula, K., & Korley, L. T. J. (2025) · Molecular Systems Design & Engineering · doi:10.1039/d5me00018a · Cited by 5 · see citing works
Shape-morphing photo-crosslinked alginate hydrogels via digital light processing 4D printing
Habib, M., Liberati, A. F., Nieswic, N., Berthelot, J., Seriket, H., Demoly, F., Tourrette, A., Sharkawi, T., & Blanquer, S. (2025) · Applied Materials Today · doi:10.1016/j.apmt.2025.103064 · Cited by 5 · see citing works
Dual‐Responsive Gradient Structured Actuator via Photopolymerization‐Induced Diffusion
Polat, D. S., Buurman, V. E., Mulder, D. J., & Liu, D. (2024) · Chemistry - A European Journal · doi:10.1002/chem.202400515 · Cited by 5 · see citing works
A bionic mimosa soft robot based on a multi-responsive PNIPAM-PEGDA hydrogel composition
Yang, W., Wang, X., Teng, X., Qiao, Z., Yu, H., & Yuan, Z. (2024) · Biomicrofluidics · doi:10.1063/5.0203482 · Cited by 4 · see citing works
Bauman, L. A., & Zhao, B. (2025) · Carbohydrate Polymer Technologies and Applications · doi:10.1016/j.carpta.2025.100702 · Cited by 4 · see citing works
Introduction to vat polymerization 3D printing technologies
Yang, W., Zhang, M., Peng, S., Pan, R., & Liu, Y. (2024) · Elsevier eBooks · doi:10.1016/b978-0-443-15487-4.00010-8 · Cited by 4 · see citing works
Sun, Y., Qian, X., Gou, Y., Zheng, C., & Zhang, F. (2024) · Polymers · doi:10.3390/polym16111547 · Cited by 4 · see citing works
Gu, Y., Wang, X., Yu, W., Fan, W., Zhu, Z., He, J., Li, Y., & Zhao, Q. (2026) · Chemistry of Materials · doi:10.1021/acs.chemmater.6c00886 · Cited by 3 · see citing works
4D-printed stimuli-responsive hydrogels modeling and fabrication
Piedade, A. P., & Pinho, A. C. (2022) · Elsevier eBooks · doi:10.1016/b978-0-12-824082-3.00027-1 · Cited by 3 · see citing works
Nishimura, T., Guo, H., Kiyama, R., Katsuyama, Y., Gong, J. P., & Kurokawa, T. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c01435 · Cited by 3 · see citing works
- Authors
- Odent, J., Vanderstappen, S., Toncheva, A., Pichon, E., Wallin, T. J., Wang, K., Shepherd, R. F., Dubois, P., & Raquez, J.-M.
- Affiliations
- University of Mons (BE)
- Cornell University (US)
- Laboratory of Polymeric and Composite Materials (LPCM)
- Corresponding author
- Odent, Jérémy
- Raquez, Jean-Marie
- ORCID
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 7
- Issue
- 25
- Pages
- 15395-15403
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2947638614
- Cited by
- 115
- References
- 54
- Citations by year
- 2026: 8 · 2025: 17 · 2024: 21 · 2023: 17 · 2022: 19 · 2021: 21 · 2020: 10 · 2019: 2
- FWCI
- 7.31
- Type
- journal article
- Language
- en
- Open access
- green
- orbi.umons.ac.be
- Licence
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- ORBi UMONS (submittedVersion, other-oa)
- PolyPublie (École Polytechnique de Montréal) (submittedVersion)
- Funders
- National Science Foundation (DMR-1719875)
- Federaal Wetenschapsbeleid (SSTC-PAI 6/27)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
- Physical Sciences › Engineering › Automotive Engineering › Additive Manufacturing and 3D Printing Technologies
- Keywords
- hydrogel actuators, 3D printing, functionally graded structures, anisotropic swelling, hierarchy, stimuli-responsive materials
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review