Impact of hydrolysis pretreatment on the compostability of biodegradable poly (caprolactone) and poly (lactic acid) films
Open accessAbstract
Hydrolysis pretreatment accelerated PLA biodegradation by disrupting its amorphous regions, reducing molecular weight, and forming less stable crystalline structures, while its impact on PCL was minimal.
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High crystallinity and hydrophobicity of PCL slow its degradation rate.
“High crystallinity and hydrophobicity of PCL also slow the degradation rate [6,49]”
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Cites
The return of a forgotten polymer—Polycaprolactone in the 21st century
Woodruff, M. A., & Hutmacher, D. W. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2010.04.002 · Cited by 4,033 · see citing works
Mechanisms of polymer degradation and erosion
Göpferich, A. (1996) · Biomaterials · doi:10.1016/0142-9612(96)85755-3 · Cited by 1,781 · see citing works
Fischer, E. W., Sterzel, H. J., & Wegner, G. (1973) · Kolloid-Zeitschrift und Zeitschrift für Polymere · doi:10.1007/bf01498927 · Cited by 1,704 · see citing works
Poly(lactic acid) crystallization
Saeidlou, S., Huneault, M. A., Li, H., & Park, C. B. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.07.005 · Cited by 1,606 · see citing works
Twenty years of microplastic pollution research—what have we learned?
Thompson, R. C., Courtene-Jones, W., Boucher, J., Pahl, S., Raubenheimer, K., & Koelmans, A. A. (2024) · Science · doi:10.1126/science.adl2746 · Cited by 1,521 · see citing works
Poly(lactic acid)—Mass production, processing, industrial applications, and end of life
Castro‐Aguirre, E., Iñiguez‐Franco, F., Samsudin, H., Fang, X., & Auras, R. A. (2016) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2016.03.010 · Cited by 1,338 · see citing works
Self-citationWhy degradable polymers undergo surface erosion or bulk erosion
Burkersroda, F. V., Schedl, L., & Göpferich, A. (2002) · Biomaterials · doi:10.1016/s0142-9612(02)00170-9 · Cited by 1,146 · see citing works
The in vivo degradation, absorption and excretion of PCL-based implant
Sun, H., Mei, L., Song, C. X., Cui, X., & Wang, P. (2005) · Biomaterials · doi:10.1016/j.biomaterials.2005.09.019 · Cited by 977 · see citing works
Pitt, G. G., Gratzl, M. M., Kimmel, G. L., Surles, J., & Sohindler, A. (1981) · Biomaterials · doi:10.1016/0142-9612(81)90060-0 · Cited by 857 · see citing works
Ncube, L. K., Ude, A. U., Ogunmuyiwa, E. N., Zulkifli, R., & Beas, I. N. (2020) · Materials · doi:10.3390/ma13214994 · Cited by 767 · see citing works
Lifetime prediction of biodegradable polymers
Laycock, B. G., Nikolić, M., Colwell, J. M., Gauthier, E., Halley, P. J., Bottle, S. E., & George, G. A. (2017) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2017.02.004 · Cited by 661 · see citing works
Crystallization behavior of poly(l-lactic acid)
Yasuniwa, M., Tsubakihara, S., Iura, K., Ono, Y., Dan, Y., & Takahashi, K. (2006) · Polymer · doi:10.1016/j.polymer.2006.08.054 · Cited by 478 · see citing works
Tsuji, H., & Suzuyoshi, K. (2002) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(01)00240-3 · Cited by 260 · see citing works
A review on the thermomechanical properties and biodegradation behaviour of polyesters
Larrañaga, A., & Lizundia, E. (2019) · European Polymer Journal · doi:10.1016/j.eurpolymj.2019.109296 · Cited by 259 · see citing works
Assessment of aliphatic–aromatic copolyester biodegradable mulch films. Part I: Field study
Kijchavengkul, T., Auras, R. A., Rubino, M. I., Ngouajio, M., & Fernandez, R. T. (2008) · Chemosphere · doi:10.1016/j.chemosphere.2007.10.074 · Cited by 217 · see citing works
Self-citationProgress in upcycling polylactic acid waste as an alternative carbon source: A review
Sun, C., Wei, S., Tan, H., Huang, Y., & Zhang, Y. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.136881 · Cited by 207 · see citing works
Effect of Molecular Weight on the Crystallization and Melt Memory of Poly(ε-caprolactone) (PCL)
Fernández-Tena, A., Pérez-Camargo, R. A., Coulembier, O., Sangroniz, L., Aranburu, N., Guerrica-Echevarria, G., Liu, G., Wang, D., Cavallo, D., & Müller, A. J. (2023) · Macromolecules · doi:10.1021/acs.macromol.3c00234 · Cited by 200 · see citing works
Nizamuddin, S., Baloch, A. J., Chen, C. R., Arif, M., & Mubarak, N. M. (2024) · International Biodeterioration & Biodegradation · doi:10.1016/j.ibiod.2024.105887 · Cited by 194 · see citing works
Hydrolytic and enzymatic degradation of a poly(ε-caprolactone) network
Castilla-Cortázar, I., Más-Estellés, J., Dueñas, J. M. M., Ivirico, J. L. E., Marí, B., & Vidaurre, A. (2012) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2012.05.038 · Cited by 182 · see citing works
Fundamental solution and single‐chain properties of polylactides
Dorgan, J. R., Janzen, J., Knauss, D. M., Hait, S. B., Limoges, B. R., & Hutchinson, M. H. (2005) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.20577 · Cited by 173 · see citing works
The biodegradation of amorphous and crystalline regions in film-blown poly(ε-caprolactone)
Eldsäter, C. (2000) · Polymer · doi:10.1016/s0032-3861(99)00278-5 · Cited by 162 · see citing works
Iñiguez-Franco, F., Auras, R., Burgess, G., Holmes, D., Fang, X., Rubino, M., & Soto-Valdez, H. (2016) · Polymer · doi:10.1016/j.polymer.2016.07.018 · Cited by 159 · see citing works
Self-citationCastro‐Aguirre, E., Auras, R. A., Selke, S. E. M., Rubino, M. I., & Marsh, T. L. (2017) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2017.01.017 · Cited by 153 · see citing works
Self-citationWurm, A., Zhuravlev, E., Eckstein, K., Jehnichen, D., Pospiech, D., Androsch, R., Wunderlich, B., & Schick, C. H. (2012) · Macromolecules · doi:10.1021/ma300363b · Cited by 147 · see citing works
Poly(ε‐caprolactone): A potential polymer for biodegradable food packaging applications
Thakur, M., Majid, I., Hussain, S., & Nanda, V. (2021) · Packaging Technology and Science · doi:10.1002/pts.2572 · Cited by 145 · see citing works
A model for simultaneous crystallisation and biodegradation of biodegradable polymers
Han, X., & Pan, J. (2009) · Biomaterials · doi:10.1016/j.biomaterials.2008.10.001 · Cited by 143 · see citing works
Limsukon, W., Rubino, M. I., Rabnawaz, M., Lim, L., & Auras, R. A. (2023) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2023.110537 · Cited by 138 · see citing works
Self-citationFormation of Segregation Morphology in Crystalline/Amorphous Polymer Blends: Molecular Weight Effect
Chen, H., Li, L., & Lin, T. (1998) · Macromolecules · doi:10.1021/ma9715740 · Cited by 132 · see citing works
Kijchavengkul, T., Auras, R. A., Rubino, M. I., Ngouajio, M., & Fernandez, R. T. (2008) · Chemosphere · doi:10.1016/j.chemosphere.2008.01.037 · Cited by 125 · see citing works
Self-citationEnhancing the biodegradation of (bio)plastic through pretreatments: A critical review
Yasin, N. M., Akkermans, S., & van Impe, J. F. M. (2022) · Waste Management · doi:10.1016/j.wasman.2022.06.004 · Cited by 100 · see citing works
Kijchavengkul, T., Auras, R. A., Rubino, M. I., Ngouajio, M., & Fernandez, R. T. (2006) · Polymer Testing · doi:10.1016/j.polymertesting.2006.06.008 · Cited by 99 · see citing works
Self-citationBoosting Degradation of Biodegradable Polymers
Bher, A., Cho, Y., & Auras, R. A. (2023) · Macromolecular Rapid Communications · doi:10.1002/marc.202200769 · Cited by 97 · see citing works
Self-citationTurning off the Tap: How the World can End Plastic Pollution and Create a Circular Economy
United Nations Environment Programme (2023) · United Nations Environment Programme eBooks · doi:10.59117/20.500.11822/42277 · Cited by 97 · see citing works
Limsukon, W., Auras, R. A., & Selke, S. E. M. (2019) · Polymer Testing · doi:10.1016/j.polymertesting.2019.106108 · Cited by 83 · see citing works
Self-citationEnhancing plastic biodegradation process: strategies and opportunities
Thew, X. E. C., Lo, S. C., Ramanan, R., Tey, B., Nguyễn, H. Đ., & Wei, O. C. (2023) · Critical Reviews in Biotechnology · doi:10.1080/07388551.2023.2170861 · Cited by 78 · see citing works
Leroux, A., Nguyễn, T. N., Rangel, A. L. R., Cacciapuoti, I., Duprez, D., Castner, D. G., & Migonney, V. (2020) · Biointerphases · doi:10.1116/6.0000429 · Cited by 68 · see citing works
Tsuji, H., Ishida, T., & Fukuda, N. (2003) · Polymer International · doi:10.1002/pi.1199 · Cited by 54 · see citing works
Bher, A., Uysal‐Unalan, I., Auras, R. A., Rubino, M. I., & Schvezov, C. E. (2019) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2019.04.014 · Cited by 42 · see citing works
Self-citationGastaldi, E., Buendia-Kandia, F., Greuet, P., Bouchou, Z. B., Benihya, A., César, G., & Domenek, S. (2024) · Bioresource Technology · doi:10.1016/j.biortech.2024.130670 · Cited by 40 · see citing works
Acceleration of Biodegradation Using Polymer Blends and Composites
Easton, Z. H. W., Essink, M. A. J., Comas, L. R., Wurm, F. R., & Gojżewski, H. (2023) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202200421 · Cited by 38 · see citing works
Wan, H., Sun, C., Xu, C., Wang, B., Chen, Y., Yang, Y., Tan, H., & Zhang, Y. (2023) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2023.140207 · Cited by 34 · see citing works
Yusefi, M., Khalid, M., Yasin, F. M., Abdullah, L. C., Ketabchi, M. R., & Walvekar, R. (2017) · Journal of Polymers and the Environment · doi:10.1007/s10924-017-0963-z · Cited by 29 · see citing works
Recyclable and Biodegradable Paper Coating with Functionalized PLA and PBAT
Hamdani, S. S., Elkholy, H. M., Alghaysh, M. O., Wyman, I., Bher, A., Auras, R. A., & Rabnawaz, M. (2025) · ACS Omega · doi:10.1021/acsomega.4c11134 · Cited by 22 · see citing works
Self-citationTsuji, H. (2022) · Wiley eBooks · doi:10.1002/9781119767480.ch21 · Cited by 19 · see citing works
Flagged first, then by citations
1 of the 45 references couldn’t be matched to a known paper.
Research works printed but not linked: 2
- R. Auras, H. Tsuji, S. Selke and L. Loong-Tak, Poly(Lactic Acid) synthesis, structures, properties, processing, Wiley- Blackwell, 2022.
- G. L. Siparsky, K. J. Voorhees and F. Miao, Hydrolysis of Polylactic Acid (PLA) and Polycaprolactone (PCL) in Aqueous Acetonitrile Solutions: Autocatalysis, J. Environ. Polym. Degrad., 1998, 6, 31-41.
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Degradation and Disintegration Behavior of PHBV- and PLA-Based Films Under Composting Conditions
Lyshtva, P., Kuusik, A., & Voronova, V. (2025) · Sustainability · doi:10.3390/su17198657 · Cited by 14 · see citing works
Assessing the Role of Compostable Plastics in Circular Economy Transition
Hwang, D. K., Park, J., Oh, D. X., Jeon, H., & Koo, J. M. (2025) · ChemSusChem · doi:10.1002/cssc.202501938 · Cited by 14 · see citing works
Muñoz-Shugulí, C., Morán, D., Velásquez, E., López-Vilariño, J. M., & López-de-Dicastillo, C. (2025) · Polymers · doi:10.3390/polym17182542 · Cited by 11 · see citing works
Loughlin, J. O., McDonnell, H., Lawless, R., Kelleher, S. M., Fahy, S., Freeland, B., Rochfort, K. D., & Gaughran, J. (2025) · RSC Sustainability · doi:10.1039/d5su00623f · Cited by 11 · see citing works
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Repinc, S. K., Stres, B., Karlovits, M., Karlovits, I., Jerič, P., Panák, O., Verbič, A., Likozar, B., & Novak, U. (2025) · FEBS Open Bio · doi:10.1002/2211-5463.70183 · Cited by 6 · see citing works
Wu, B., Diao, H., Chen, S., Shi, S., & Wang, X. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.172284 · Cited by 5 · see citing works
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Wang, T., Zhang, Y., Zhou, H., Shi, X., Zhang, Y., Li, Z., Peng, C., Wang, Y., Luo, D., Zhang, X., et al. (2026) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2026.121241 · Cited by 1 · see citing works
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Self-citation
- Authors
- D'Amario, J., Limsukon, W., Bher, A., & Auras, R.
- Affiliations
- Michigan State University (US)
- Rajamangala University of Technology Tawan-ok (TH)
- Corresponding author
- Bher, Anibal
- Auras, Rafael
- Venue
- RSC Applied Polymers
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2025
- Volume
- 3
- Issue
- 3
- Pages
- 711-721
- ISSN
- 2755-371X (ISSN-L)
- OpenAlex
- W4409210843
- Cited by
- 22
- References
- 45
- Citations by year
- 2026: 10 · 2025: 12
- FWCI
- 4.65
- Type
- journal article
- Language
- en
- Open access
- diamond
- doi.org
- Licence
- Locations
- RSC Applied Polymers (publishedVersion, cc-by)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › Nanocomposite Films for Food Packaging
- Keywords
- hydrolysis pretreatment, compostability, biodegradable films, polycaprolactone, polylactic acid, biodegradation, amorphous regions, molecular weight reduction, crystallinity, polymer crystallization
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