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AB-polymer networks based on oligo(ɛ-caprolactone) segments showing shape-memory properties
Open accessAbstract
Although shape-memory metal alloys have wide use in medicine and other areas, improved properties, particularly easy shaping, high shape stability, and adjustable transition temperature, are realizable only by polymer systems. In this paper, a polymer system of shape-memory polymer networks based on oligo(ɛ-caprolactone) dimethacrylate as crosslinker and n -butyl acrylate as comonomer was introduced. The influence of two structural parameters, the molecular weight of oligo(ɛ-caprolactone) dimethacrylate and the weight content of n -butyl acrylate, on macroscopic properties of polymer networks such as thermal and mechanical properties has been investigated. Tensile tests above and below melting temperature showed a decrease in the elastic modulus with increasing comonomer weight content. The crystallization behavior of the new materials has been investigated, and key parameters for the programming procedure of the temporary shape have been evaluated. Shape-memory properties have been quantified by thermocyclic experiments. All samples reached uniform deformation properties with recovery rates above 99% after 3 cycles. Whereas strain recovery increased with increasing n -butyl acrylate content, strain fixity decreased, reflecting the decreasing degree of crystallinity of the material.
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“A SMP, N-PCLDMA-BA, based on PCLDMA and BA, was able to induce angiogenesis and strong tissue integration in male Naval Medical Research Institute mice 1 week after subcutaneous implantation [47].”
From Shape-memory polymers as a technology platform for biomedical applications (2010) · cites this paper as [47]
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Metadata
- Authors
- Lendlein, A., Schmidt, A. M., & Langer, R.
- Affiliations
- Massachusetts Institute of Technology (US)
- Institute for Technical and Macromolecular Chemistry, Rheinisch Westfälische Technische Hochschule (RWTH) Aachen, and German Wool Research Institute at RWTH Aachen e.V., Veltmanplatz 8, D-52062 Aachen, Germany; and Massachusetts Institute of Technology, Department of Chemical Engineering, 45 Carleton Street, Cambridge, MA 02139
- Venue
- Proceedings of the National Academy of Sciences
- Publisher
- National Academy of Sciences
- Published
- 2001-01-23
- Volume
- 98
- Issue
- 3
- Pages
- 842-847
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- PMC
- PMC14671
- OpenAlex
- W4240829654
- Cited by
- 303
- References
- 18
- Citations by year
- 2026: 2 · 2024: 5 · 2023: 9 · 2022: 3 · 2021: 9 · 2020: 13 · 2019: 18 · 2018: 12 · 2017: 15 · 2016: 20 · 2015: 13 · 2014: 16 · 2013: 5 · 2012: 23
- FWCI
- 7.21
- Type
- journal article
- Language
- en
- Open access
- green
- www.ncbi.nlm.nih.gov
- Locations
- Proceedings of the National Academy of Sciences (publishedVersion)
- Europe PMC (PubMed Central) (publishedVersion)
- PubMed Central (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- shape memory polymers, butyl acrylate, polymer networks, crosslinking, shape programming, crystallization behavior, strain recovery, elastic modulus, molecular weight effects
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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