pH-induced shape-memory polymers
Abstract
A novel pH sensitive shape-memory polymer (SMP) is prepared by cross-linking the β-cyclodextrin modified alginate (β-CD-Alg) and diethylenetriamine modified alginate (DETA-Alg): The pH reversible β-CD-DETA inclusion complexes serve as a reversible phase, and the cross-linked alginate chains serve as a fixing phase. It is shown that this material can be processed into temporary shape as we needs at pH 11.5 and recover to its initial shape at pH 7. The recovery ratio and the fixity ratio were 95.7 ± 0.9% and 94.8 ± 1.1%, respectively. Furthermore, this material showed good degradability and biocompatibility. Because the shape transition pH value is quite close to that of our body fluid and this pH triggered shape-memory effect is convenient and safe to use, this material has a high potential for medical application.
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Han et al. proposed to use pH as trigger for SMPs for its convenience and safety in medical applications.
“In 2012 Han et al. proposed to use pH as trigger for SMPs for its convenience and safety in medical applications [59].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [59]
Chemo-responsive SMPs (pH-, redox-, moisture- and solvent-induced) are one of the barely studied systems in the literature.
“Chemo-responsive SMPs, pH-, redox- and moisture- and solvent-induced, are one of the barely studied systems in the literature [57-59].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [59]
In the pH-responsive system, alginate chains cross-linked with calcium cations served as the fixation domain, while the switching domain was constituted of β-cyclodextrin and diethylenetriamine when introduced in the Alg matrix.
“On the molecular level, such systems were dual-component, similar to the heating-responsive SMPs. Alginate (Alg) chains cross-linked with calcium cations served as the fixation domain, while the switching domain was constituted of b -cyclodextrin ( b -CD) and diethylenetriamine (DETA) when introduced in the Alg matrix.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [59]
At pH 11.5, inclusion complexes between β-CD and DETA were formed, and these complexes were dissociated at neutral pH.
“At pH 11.5, inclusion complexes between b -CD and DETA were formed. In return, these complexes were dissociated at neutral pH.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [59]
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- Authors
- Han, X., Dong, Z., Fan, M., Liu, Y., li, J., Wang, Y., Yuan, Q., Li, B., & Zhang, S.
- Affiliations
- Sichuan University (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Li, Bang‐Jing
- Zhang, Sheng
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2012-04-20
- Volume
- 33
- Issue
- 12
- Pages
- 1055-1060
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W1981343413
- Cited by
- 304
- References
- 22
- Citations by year
- 2026: 10 · 2025: 21 · 2024: 22 · 2023: 23 · 2022: 20 · 2021: 37 · 2020: 33 · 2019: 27 · 2018: 31 · 2017: 16 · 2016: 20 · 2015: 16 · 2014: 12 · 2013: 13 · 2012: 3
- FWCI
- 6.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Rapid Communications (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- shape memory polymers, pH-responsive materials, β-cyclodextrin, alginate, diethylenetriamine, inclusion complexes, shape recovery, biodegradability, biocompatibility, medical applications
- MeSH terms
- Alginates, Biocompatible Materials, Cross-Linking Reagents, Hydrogen-Ion Concentration, Polymers, Temperature, beta-Cyclodextrins
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