Extraction of Non-Ferrous Metals and Iron with Systems based on Bis(2,4,4-Trimethylpentyl)Dithiophosphinic Acid (CYANEX 301), A Review

Fleitlikh, I. Yu.; Grigorieva, N. A.; Logutenko, O. A.

doi:10.1080/07366299.2017.1411034

Cited by 19Extraction and Separation ProcessesRadioactive element chemistry and processingAnalytical chemistry methods development

Extraction of Non-Ferrous Metals and Iron with Systems based on Bis(2,4,4-Trimethylpentyl)Dithiophosphinic Acid (CYANEX 301), A Review

Fleitlikh, I. Yu., Grigorieva, N. A., Logutenko, O. A.·2018·Solvent Extraction and Ion Exchange

DOI 10.1080/07366299.2017.1411034

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Abstract

Extraction is widely used in the hydrometallurgy of nonferrous metals. In addition to such well-known extractants as oxygen-containing organophosphorus or monocarboxylic acids, thio-substituted organophosphorus acids in particular, the commercially available extractant CYANEX 301, the active component of which is bis(2,4,4-trimethylpentyl)dithiophosphinic acid (HR), is of interest. This extractant is a sulfur-containing analogue of CYANEX 272 (bis(2,4,4-trimethylpentyl) phosphinic acid). In this review, the state of CYANEX 301 in various solvents in the absence and presence of electron-donor additives, the chemistry of the extraction processes of non-ferrous metals in the HR systems, the compositions of the extracted compounds, stability of the extractant in aggressive media, technological developments, and prospects for using CYANEX 301 in hydrometallurgy of non-ferrous metals are discussed.

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CuR2 (extracted complex of Cu(II) with Cyanex 301/302) is further polymerized in the organic phase to form oligomeric multinuclear copper complexes.
“Namely, CuR2 (extracted complex of Cu(II) with Cyanex 301 / Cyanex 302) is further polymerized in the organic phase to form oligomeric multinuclear copper complexes.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [40]
High cost of thiourea and toxicity of hydrazine limits commercial application of this method.
“However, the high cost of thiourea and the toxicity of hydrazine limits the commercial application of this method [40].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [40]
In this mixture, thiourea acted as stripping agent, while hydrazine lessened formation of disulfide.
“In this mixture, thiourea acted as the stripping agent, while hydrazine lessened the formation of disulfide.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [40]
In case of Cu(II), stripping from loaded phase of Cyanex 301, an aqueous solution of thiourea, hydrazine, and sodium hydroxide was used, resulting in quantitative stripping as well as regeneration of extractant.
“In the case of Cu(II), stripping from the loaded phase of Cyanex 301, an aqueous solution of thiourea, hydrazine, and sodium hydroxide was used, resulting in a quantitative stripping as well as the regeneration of the extractant.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [40]
Extraction in an inert gas stream (nitrogen or carbon dioxide) can result in efficient stripping of Co(II) and prevent oxidation of Cyanex 301.
“This route can result in an e cient stripping of Co(II) and prevent the oxidation of Cyanex 301.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [40]

<b>Hard and Soft Acids and Bases</b>
Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475 · see citing works
Handbook of Analytical Chemistry
Horwitz, W. (1963) · Journal of AOAC INTERNATIONAL · doi:10.1093/jaoac/46.6.1079 · Cited by 546 · see citing works
Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301
Zhu, Y., Chen, J., & Jiao, R. (1996) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299608918326 · Cited by 267 · see citing works
Solvent extraction characteristics of thiosubstituted organophosphinic acid extractants
Sole, K. C., & Hiskey, J. B. (1992) · Hydrometallurgy · doi:10.1016/0304-386x(92)90093-f · Cited by 200 · see citing works
Cobalt-nickel separation: the extraction of cobalt(II) and nickel(II) by Cyanex 301, Cyanex 302 and Cyanex 272
Tait, B. K. (1993) · Hydrometallurgy · doi:10.1016/0304-386x(93)90047-h · Cited by 199 · see citing works
Solvent extraction of copper by Cyanex 272, Cyanex 302 and Cyanex 301
Sole, K. C., & Hiskey, J. B. (1995) · Hydrometallurgy · doi:10.1016/0304-386x(94)00023-v · Cited by 173 · see citing works
The selective recovery of zinc with new thiophosphinic acids
RICKELTON, W. A., & BOYLE, R. J. (1990) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299008918030 · Cited by 118 · see citing works
Selective extraction of zinc(II) over iron(II) from spent hydrochloric acid pickling effluents by liquid-liquid extraction
Mansur, M. B., Rocha, S. D. F., Magalhães, F. S., & Benedetto, J. D. S. (2008) · Journal of hazardous materials · doi:10.1016/j.jhazmat.2007.05.019 · Cited by 112 · see citing works
Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301, and Cyanex 302
Jensen, M. P., & Bond, A. H. (2002) · Radiochimica Acta · doi:10.1524/ract.2002.90.4_2002.205 · Cited by 102 · see citing works
Simultaneous solvent extraction of cobalt and nickel in the presence of manganese and magnesium from sulfate solutions by Cyanex 301
Tsakiridis, P. E., & Agatzini-Leonardou, S. (2003) · Hydrometallurgy · doi:10.1016/s0304-386x(03)00180-4 · Cited by 93 · see citing works
MECHANISM OF TRIVALENT ACTINIDE/LANTHANIDE SEPARATION USING BIS(2,4,4-TRIMETHYLPENTYL) DITHIOPHOSPHINIC ACID (CYANEX 301) AND NEUTRAL O-BEARING CO-EXTRACTANT SYNERGISTIC MIXTURES
Ionova, G. V., Ionov, S., Rabbe, C., Hill, C., Madic, C., Guillaumont, R., & Krupa, J. (2001) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-100103277 · Cited by 83 · see citing works
THE EXTRACTION OF SOME BASE METAL IONS BY CYANEX 30L CYANEX 302 AND THEIR BINARY EXTRACTANT MIXTURES WITH ALIQUAT 336
Tait, B. K. (1992) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299208918136 · Cited by 81 · see citing works
The development of a novel hydrometallurgical process for nickel and cobalt recovery from Goro laterite ore
Mihaylov, I., Krause, E., Colton, D. F., Okita, Y., Duterque, J., & Perraud, J.-J. (2000) · CIM bulletin · Cited by 76 · see citing works
AN ASSESSMENT OF THE LONG-TERM STABILITIES OF CYANEX302 AND CYANEX301 IN SULFURIC AND NITRIC ACIDS
Sole, K. C., Brent Hiskey, J., & Ferguson, T. L. (1993) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299308918186 · Cited by 75 · see citing works
INVESTIGATION OF THE AGGREGATION OF THE NEODYMIUM COMPLEXES OF DIALKYLPHOSPHORIC, -OXOTHIOPHOSPHINIC, AND -DITHIOPHOSPHINIC ACIDS IN TOLUENE
Jensen, M. P., Chiarizia, R., & Urban, V. S. (2001) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-100107027 · Cited by 66 · see citing works
Recovery of cobalt, nickel, and copper from sea nodules by their extraction with alkylphosphines
Gupta, B., Deep, A., Singh, V. K., & Tandon, S. N. (2003) · Hydrometallurgy · doi:10.1016/s0304-386x(03)00052-5 · Cited by 57 · see citing works
SOLVENT EXTRACTION OF Sc(III), Zr(lV), Th(IV), Fe(lll), AND Lu(lll) WITH THIOSUBSTITUTED ORGANOPHOSPHINIC ACID EXTRACTANTS
Wang, C., & Li, D. (1995) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299508918288 · Cited by 57 · see citing works
CYANEX® 301 binary extractant systems in cobalt/nickel recovery from acidic chloride solutions
Jakovljevic, B., Bourget, C., & Nucciarone, D. (2004) · Hydrometallurgy · doi:10.1016/j.hydromet.2004.06.006 · Cited by 56 · see citing works
Leaching and separation of zinc from the black paste of spent MnO2-Zn dry cell batteries
El–Nadi, Y. A., Daoud, J. A., & Aly, H. F. (2006) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2006.09.027 · Cited by 54 · see citing works
Solvent extraction of silver from chloride media with some commercial sulfur-containing extractants
Alam, M. S., Inoue, K., Yoshizuka, K., Dong, Y., & Zhang, P. (1997) · Hydrometallurgy · doi:10.1016/s0304-386x(96)00053-9 · Cited by 49 · see citing works
Equilibrium Studies of Nickel(II), Copper(II), and Cobalt(II) Extraction with Aloxime 800, D<sub>2</sub>EHPA, and Cyanex Reagents
Van de Voorde, I., Pinoy, L., Courtijn, E., & Verpoort, F. (2006) · Solvent Extraction and Ion Exchange · doi:10.1080/07366290600952717 · Cited by 48 · see citing works
Separation of zinc and nickel ions in a strong acid through liquid–liquid extraction
Park, Y. J., & Fray, D. J. (2008) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2008.06.085 · Cited by 47 · see citing works
EXTRACTION AND SEPARATION OF NICKEL(H) USING BIS (2,4,4-TRIMETHYLPENTYL) DITHIOPHOSPHINIC ACID (CYANEX 301) AND ITS RECOVERY FROM SPENT CATALYST AND ELECTROPLATING BATH RESIDUE
Singh, R., Kliwaja, A. R., Gupta, B., & Tandon, S. N. (1999) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299908934618 · Cited by 47 · see citing works
CYANEX® 301 binary extractant systems in cobalt/nickel recovery from acidic sulphate solutions
Bourget, C., Jakovljevic, B., & Nucciarone, D. (2005) · Hydrometallurgy · doi:10.1016/j.hydromet.2004.12.005 · Cited by 46 · see citing works
Separation of copper from aqueous sulfate solutions by mixtures of Cyanex 301 and LIX® 984N
Fouad, E. A. (2008) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2008.11.114 · Cited by 43 · see citing works
SOLVENT EXTRACTION OF PALLADIUM WITH BIS(2,4,4,-TRIMETHYLPENTYL)DITHIOPHOSPHINIC ACID AND BIS(2,4,4,-TRIMETHYLPENTYL)MONOTHIOPHOSPHINIC ACID
Kakoi, T., Goto, M., & Nakashio*, F. (1994) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299408918223 · Cited by 42 · see citing works
A Study on the Radiolytic Stability of Commercial and Purified Cyanex 301
Chen, J., Jiao, R., & Zhu, Y. (1996) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299608918356 · Cited by 42 · see citing works
Determination of the Degradation Compounds Formed by the Oxidation of Thiophosphinic Acids and Phosphine Sulfides with Nitric Acid
Menoyo, B., Elizalde, M. P., & Almela, A. (2002) · Analytical Sciences · doi:10.2116/analsci.18.799 · Cited by 38 · see citing works
Extraction of arsenic(III) and arsenic(V) with Cyanex 925, Cyanex 301 and their mixtures
Iberhan, L., & Wiśniewski, M. (2002) · Hydrometallurgy · doi:10.1016/s0304-386x(01)00198-0 · Cited by 38 · see citing works
Degradation in hydroxyoxime solvent extraction systems
Whewell, R. J., Foakes, H. J., & Hughes, M. A. (1981) · Hydrometallurgy · doi:10.1016/0304-386x(81)90010-4 · Cited by 37 · see citing works
Zn2+ sensor based onZn-bis(2,4,4-trimethylpentyl)dithiophosphinicacid complex in PVC matrix
Gupta, V. K., Jain, A. K., Singh, L. P., & Khurana, U. (1998) · Electrochimica Acta · doi:10.1016/s0013-4686(97)10112-8 · Cited by 32 · see citing works
777. Hydrogen bonding of the thiol group in phosphinodithioic acids
Allen, G., & Colclough, R. O. (1957) · Journal of the Chemical Society (Resumed) · doi:10.1039/jr9570003912 · Cited by 29 · see citing works
Degradation of organothiophosphorous extractant Cyanex 301
Wieszczycka, K., & Tomczyk, W. (2011) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2011.05.045 · Cited by 28 · see citing works
Cobalt and Nickel Recovery from Sulfate Media Containing Calcium, Manganese, and Magnesium with a Mixture of CYANEX 301 and a Trialkylamine
Fleitlikh, I. Y., Pashkov, G. L., Grigorieva, N. A., Nikiforova, L. K., Pleshkov, M. A., & Shneerson, Y. M. (2011) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299.2011.595627 · Cited by 27 · see citing works
Self-citation
Synergistic solvent extraction of manganese(II) with a mixture of Cyanex 272 and Cyanex 301 from chloride solutions
Batchu, N. K., Sonu, C. H., & Lee, M. S. (2013) · Hydrometallurgy · doi:10.1016/j.hydromet.2013.09.008 · Cited by 25 · see citing works
Cobalt-manganese separation: the extraction of cobalt(II) from manganese sulphate solutions by cyanex 301
Ocaña, N., & Alguacil, F. J. (1998) · Journal of Chemical Technology & Biotechnology · doi:10.1002/(sici)1097-4660(1998110)73:3 · Cited by 24 · see citing works
Solvent extraction equilibrium and modeling studies of manganese from sulfate solutions by a mixture of Cyanex 301 and TBP
Batchu, N. K., Sonu, C. H., & Lee, M. S. (2014) · Hydrometallurgy · doi:10.1016/j.hydromet.2014.01.009 · Cited by 24 · see citing works
Extraction Separation of Cd(II) and Zn(II) with Cyanex301 and Aqueous Nitrogen‐Donor Ligand TPEN
Takeshita, K., Watanabe, K., Nakano, Y., & Watanabe, M. (2004) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-120030388 · Cited by 23 · see citing works
Nickel(II) Extraction from Sulphate Media with Bis (2,4,4‐Trimethylpentyl)Dithiophosphinic Acid Dissolved in Nonane
Pashkov, G. L., Grigorieva, N. A., Pavlenko, N. I., Fleitlikh, I. Y., Nikiforova, L. K., & Pleshkov, M. A. (2008) · Solvent Extraction and Ion Exchange · doi:10.1080/07366290802495192 · Cited by 22 · see citing works
Self-citation
Nickel extraction from sulfate media with Cyanex 301 in the presence of electron donor additives
Grigorieva, N. A., Pashkov, G. L., Fleitlikh, I. Y., Nikiforova, L. K., & Pleshkov, M. A. (2010) · Hydrometallurgy · doi:10.1016/j.hydromet.2010.08.001 · Cited by 20 · see citing works
Self-citation
Cadmium(II) Extraction from Phosphoric Media bybis(2,4,4‐Trimethylpentyl)dithiophosphinic Acid (CYANEX 301)
Ocio, A., Almela, A., & Elizalde, M. P. (2004) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-200037455 · Cited by 20 · see citing works
Investigation of the State of Bis(2,4,4-trimethylpentyl)dithiophosphinic Acid in Nonane in the Presence of Electron-Donor Additives
Grigorieva, N. A., Pavlenko, N. I., Pashkov, G. L., Fleitlikh, I. Y., & Nikiforova, L. K. (2010) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299.2010.482457 · Cited by 17 · see citing works
Self-citation
EXTRACTION OF COBALT(II) BY CYANEX
Menoyo, B., & Elizalde, M. P. (1997) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299708934494 · Cited by 16 · see citing works
Stripping of copper from CYANEX® 301 extract with thiourea–hydrazine–sodium hydroxide solution
Facon, S., Adekola, F. A., & Cote, G. (2007) · Hydrometallurgy · doi:10.1016/j.hydromet.2007.08.003 · Cited by 16 · see citing works
Investigation of the State of Bis(2,4,4‐Trimethylpentyl)dithiophosphinic Acid in Nonane and Toluene Solutions
Grigorieva, N. A., Pavlenko, N. I., Pleshkov, M. A., Pashkov, G. L., & Fleitlikh, I. Y. (2009) · Solvent Extraction and Ion Exchange · doi:10.1080/07366290903113983 · Cited by 15 · see citing works
Self-citation
Interactions of metal extractant reagents. Part VIII. Comparative aggregation equilibria of Cyanex 302 and Cyanex 301 in heptane
Almela, A., & Elizalde, M. P. (1995) · Analytical Proceedings · doi:10.1039/ai9953200145 · Cited by 15 · see citing works
Cobalt extraction from sulfate media with bis(2,4,4-trimethylpentyl)dithiophosphinic acid in the presence of electron donor additives
Grigorieva, N. A., & Fleitlikh, I. Y. (2013) · Hydrometallurgy · doi:10.1016/j.hydromet.2013.06.011 · Cited by 14 · see citing works
Self-citation
Oxidative degradation of bis(2,4,4‐trimethylpentyl)dithiophosphinic acid in nitric acid studied by electrospray ionization mass spectrometry
Groenewold, G. S., Peterman, D. R., Klaehn, J. R., Delmau, L. H., Marc, P., & Custelcean, R. (2012) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.6339 · Cited by 14 · see citing works
Complexation Behavior of Iron(III) with Aloxime 800, D2EHPA, CYANEX 272, CYANEX 302, and CYANEX 301
Voorde, I. V. D., Latruwe, K., Pinoy, L., Courtijn, E., & Verpoort, F. (2007) · Solvent Extraction and Ion Exchange · doi:10.1080/07366290701634297 · Cited by 12 · see citing works
Penta- and hexa-coordinate adducts of bis(diaryldithiophosphinato) cobalt(II)
Mukherjee, R. N., VENKATESHAN, M. S., & ZINGDE, M. D. (1974) · Journal of Inorganic and Nuclear Chemistry · doi:10.1016/0022-1902(74)80111-9 · Cited by 12 · see citing works
Purification and Properties of Cyanex 301
Chen, J., Jiao, R., & Zhu, Y. (1996) · Chinese Journal of Applied Chemistry · doi:10.3724/j.issn.1000-0518.1996.2.4548 · Cited by 10 · see citing works
Zinc(II) Extraction from Phosphoric Media bybis(2,4,4‐Trimethylpentyl)dithiophosphinic Acid (CYANEX 301)
Ocio, A., & Elizalde, M. P. (2003) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-120018949 · Cited by 9 · see citing works
COMPOSITION OF CYANEX 301 BY GAS CHROMATOGRAPHY–MASS SPECTROMETRY
Menoyo, B., & Elizalde, M. P. (2002) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-100108823 · Cited by 8 · see citing works
Physico-chemical characterization and biological screening of metal complexes with Cyanex 301
Pal, T. K., Alam, M. A., & Paul, S. R. (1970) · Journal of Bangladesh Academy of Sciences · doi:10.3329/jbas.v34i2.6859 · Cited by 8 · see citing works
Zinc extraction from sulfate media with bis(2,4,4-trimethylpentyl)dithiophosphinic acid in the absence and in the presence of electron donor additives
Fleitlikh, I. Y., Pashkov, G. L., Grigorieva, N. A., Nikiforova, L. K., & Logutenko, O. A. (2011) · Hydrometallurgy · doi:10.1016/j.hydromet.2011.08.010 · Cited by 8 · see citing works
Self-citation
Spectroscopic, NMR and PMR studies on monoadducts of cobalt(II) and nickel(II) diaryldithiophosphinates with oxygen donor ligands
Mukherjee, R. N., VENKATESHAN, M. S., ZINGDE, M. D., & Dhingra, M. M. (1976) · Journal of Inorganic and Nuclear Chemistry · doi:10.1016/0022-1902(76)80338-7 · Cited by 8 · see citing works
The Extraction of Tc(VII), Fe(III), Ru(II), Pd(II) and Mo(VI) from Nitric Acid Solution by Bis(2,4,4-trimethylpentyl)dithiophosphinic acid (HBTMPDTP)
Chen, J., Jiao, R., & Zhu, Y. (1999) · Radiochimica Acta · doi:10.1524/ract.1999.86.34.151 · Cited by 7 · see citing works
Solvent Extraction of Fe(III) from Aqueous Chloride Solution by Cyanex 301 Dissolved in Kerosene
Biswas, R. K., Ali, M. R., Habib, M. A., Salam, S. M. A., Karmakar, A. K., & Ullah, M. H. (2010) · Journal of Scientific Research · doi:10.3329/jsr.v3i1.6263 · Cited by 7 · see citing works
Redox Processes in the Organic Phase during Cobalt Extraction with the bis(2,4,4-trimethylpentyl)dithiophosphinic Acid and Trioctyl Phosphine Oxide Mixtures
Grigorieva, N. A., & Fleitlikh, I. Y. (2015) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299.2014.993232 · Cited by 7 · see citing works
Self-citation
Iron(III) Extraction from Phosphoric Acid Solutions by Cyanex 301
Ocio, A., & Elizalde, M. P. (2011) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299.2011.573431 · Cited by 7 · see citing works
Solvent extraction of cobalt(II) di(2-ethylhexyl)dithiophosphate adducts with oxygen donor ligands
Sabot, J. L., & Bauer, D. (1979) · Journal of Inorganic and Nuclear Chemistry · doi:10.1016/0022-1902(79)80377-2 · Cited by 7 · see citing works
Redox processes during cobalt extraction with bis(2,4,4-trimethylpentyl)dithiophosphinic acid
Fleitlikh, I. Y., Grigorieva, N. A., Kuzmin, V. I., & Pashkov, G. L. (2012) · Hydrometallurgy · doi:10.1016/j.hydromet.2012.08.009 · Cited by 5 · see citing works
Self-citation
The Binary Extraction
Kholkine, A. I., & Kousmine, V. I. (1984) · Isotopenpraxis Isotopes in Environmental and Health Studies · doi:10.1080/10256018408545069 · Cited by 4 · see citing works
Manganese extraction with mixtures of bis(2,4,4-trimethylpentyl)dithiophosphinic acid and trioctyl phosphine oxide
Fleitlikh, I. Y., Grigorieva, N. A., Nikiforova, L. K., Pavlenko, N. I., & Maksimov, N. G. (2017) · Separation Science and Technology · doi:10.1080/01496395.2017.1291682 · Cited by 4 · see citing works
Self-citation
COMPLEXING, REDOX AND EXTRACTIVE PROPERTIES OF CYCLIC AND ACYCLIC DERIVATIVES OF PHOSPHORUS DITHIOACIDS
Овчинников, В. В., Toropova, V. F., Garifzyanov, A. R., Cherkasov, R. А., & Pudovik, A. N. (1985) · Phosphorous and Sulfur and the Related Elements · doi:10.1080/03086648508073448 · Cited by 4 · see citing works
A Novel Spectrophotometric Method for Estimation of Fe in Metallurgical Samples Using Cyanex 301 as Extractant
Biswas, R. K., Karmakar, K., & Mondal, T. K. (2014) · Journal of Applied Spectroscopy · doi:10.1007/s10812-014-9987-5 · Cited by 1 · see citing works

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Authors: Fleitlikh, I. Y., Grigorieva, N. A., & Logutenko, O. A.
Affiliations: Krasnoyarsk Scientific Center (RU)
Siberian Branch of the Russian Academy of Sciences (RU)
Corresponding author: Grigorieva, N. A.
ORCID: Grigorieva, N. A.
Logutenko, O. A.
Venue: Solvent Extraction and Ion Exchange
Publisher: Informa UK Limited
Published: 2017-12-07
Volume: 36
Issue: 1
Pages: 1-21
ISSN: 0736-6299 (ISSN-L)
1532-2262
DOI: 10.1080/07366299.2017.1411034
OpenAlex: W2773099858
Cited by: 19
References: 69
Citations by year: 2026: 2 · 2025: 1 · 2024: 2 · 2022: 2 · 2021: 4 · 2020: 5 · 2019: 3
FWCI: 1.70
Type: journal article
Language: en
Open access: closed
Locations: Solvent Extraction and Ion Exchange (publishedVersion)
Topics: Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
Physical Sciences › Chemistry › Inorganic Chemistry › Radioactive element chemistry and processing
Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Keywords: Cyanex 301, iron extraction, hydrometallurgy, solvent extraction, Cyanex 272

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Extraction of Non-Ferrous Metals and Iron with Systems based on Bis(2,4,4-Trimethylpentyl)Dithiophosphinic Acid (CYANEX 301), A Review

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