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Thermal Conductance of Hydrophilic and Hydrophobic Interfaces
Abstract
Using time-domain thermoreflectance, we have measured the transport of thermally excited vibrational energy across planar interfaces between water and solids that have been chemically functionalized with a self-assembled monolayer (SAM). The Kapitza length--i.e., the thermal conductivity of water divided by the thermal conductance per unit area of the interface--is analogous to the "slip length" for water flowing tangentially past a solid surface. We find that the Kapitza length at hydrophobic interfaces (10-12 nm) is a factor of 2-3 larger than the Kapitza length at hydrophilic interfaces (3-6 nm). If a vapor layer is present at the hydrophobic interface, and this vapor layer has a thermal conductivity that is comparable to bulk water vapor, then our experimental results constrain the thickness of the vapor layer to be less than 0.25 nm.
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“For example, TDTR can also be applied to characterize thermal properties of liquids and fluids, such as the thermal conductivity/heat capacity of liquids, 103 thermal conductance of solid/liquid interfaces, 80, 233, 234 the heat transfer coefficient of fluids during evaporation, 235, 236 condensation, 237 microchannel cooling, 238 and flow boiling. 239”
From Tutorial: Time-domain thermoreflectance (TDTR) for thermal property characterization of bulk and thin film materials (2018) · cites this paper as [80]
In the citing paper
“TDTR technique is therefore implemented extensively to study the thermal transport mechanisms across interfaces, including the effect of surface chemistry on interfacial thermal conductance across functionalized liquid-solid boundary[95,117,118] and solid-solid interfaces[119], interfacial thermal conductance between metals and dielectrics,[120][121][122][123][124] and interface between low dim”
From Measurement Techniques for Thermal Conductivity and Interfacial Thermal Conductance of Bulk and Thin Film Materials (2016) · cites this paper as [95]
In the citing paper
“With the advancement of pico-and femtosecond pulsed laser after 1980, this technique has been widely used for studying non-equilibrium electron-phonon interaction [89,90], detecting coherent phonon transport [91][92][93] and thermal transport across interfaces [94][95][96] .”
From Measurement Techniques for Thermal Conductivity and Interfacial Thermal Conductance of Bulk and Thin Film Materials (2016) · cites this paper as [95]
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Metadata
- Authors
- Ge, Z., Cahill, D. G., & Braun, P. V.
- Affiliations
- University of Illinois Urbana-Champaign (US)
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2006-05-08
- Volume
- 96
- Issue
- 18
- Pages
- 186101-186101
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W1996203962
- Cited by
- 455
- References
- 34
- Citations by year
- 2026: 19 · 2025: 26 · 2024: 17 · 2023: 24 · 2022: 27 · 2021: 29 · 2020: 30 · 2019: 29 · 2018: 23 · 2017: 43 · 2016: 37 · 2015: 17 · 2014: 20 · 2013: 20 · 2012: 16
- FWCI
- 10.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Physical Review Letters (publishedVersion)
- PubMed (publishedVersion)
- Bulletin of the American Physical Society
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Thermal properties of materials
- Physical Sciences › Engineering › Mechanics of Materials › Thermography and Photoacoustic Techniques
- Physical Sciences › Engineering › Mechanical Engineering › Heat Transfer and Boiling Studies
- Keywords
- thermal conductance, hydrophobic interface, hydrophilic interfaces, self-assembled monolayers, solid-water interface, vibrational energy transport, time-domain thermoreflectance, interfacial thermal resistance
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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