Temperature-Dependent Thermal Boundary Conductance at Metal/Indium-Based III–V Semiconductor Interfaces
Abstract
At the microscale length and smaller, solid–solid interfaces pose a significant contribution to resistance, resulting in a build-up of energy carriers, in turn leading to extreme temperature gradients within a single electronic component. These localized temperature gradients, or “hot spots,” are known to promote degradation, thus reducing device longevity and performance. To mitigate thermal management issues, it is crucial to both measure and understand conductance at interfaces in technologically relevant thin film systems. Recent trends in photonic devices have been pushing the consumption of indium in the U.S. to grow exponentially each year. Thus, we report on the temperature-dependent thermal boundary conductances at a series of metal/In-based III–V semiconductor interfaces. These measurements were made using time-domain thermoreflectance (TDTR) from 80 to 350 K. The high-temperature thermal boundary conductance results indicate, for these interfaces, that interfacial transport is dominated by elastic transmission, despite varying levels of acoustic mismatch. There is a strong direct correlation between the interfacial bond strength, approximated by the picosecond acoustics, and the thermal boundary conductance values. Both the interfacial bond strength and the overlap in the phonon density of states (PDOS) play significant roles in the magnitude of the thermal boundary conductance values. Measurements are compared against two separate predictive models, one for a perfect interface and one which accounts for disorder, such as interfacial mixing and finite grain sizes.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
TDTR has been frequently used to measure the heat capacity of new materials and the thermal conductance of various solid/solid interfaces.
“The heat capacity of new materials 38, 39 and thermal conductance of various solid/solid interfaces 40-47 have also been frequently measured using TDTR.”
From Tutorial: Time-domain thermoreflectance (TDTR) for thermal property characterization of bulk and thin film materials (2018) · cites this paper as [45]
Cites
Introduction to Solid State Physics
KITTEL, C., & Fan, H. (1957) · American Journal of Physics · doi:10.1119/1.1934457 · Cited by 22,539 · see citing works
Thermophysical Properties of Matter
Touloukian, Y. S. (1995) · CERN Document Server (European Organization for Nuclear Research) · Cited by 3,283 · see citing works
Nozik, A. J. (2002) · Physica E Low-dimensional Systems and Nanostructures · doi:10.1016/s1386-9477(02)00374-0 · Cited by 2,664 · see citing works
InP Nanowire Array Solar Cells Achieving 13.8% Efficiency by Exceeding the Ray Optics Limit
Wallentin, J., Anttu, N., Asoli, D., Huffman, M., Åberg, I., Magnusson, M. H., Siefer, G., Fuß-Kailuweit, P., Dimroth, F., Witzigmann, B., et al. (2013) · Science · doi:10.1126/science.1230969 · Cited by 1,186 · see citing works
Anharmonic Decay of Optical Phonons
Klemens, P. G. (1966) · Physical Review · doi:10.1103/physrev.148.845 · Cited by 1,051 · see citing works
Compilation of Energy Band Gaps in Elemental and Binary Compound Semiconductors and Insulators
Strehlow, W. H., & Cook, E. L. (1973) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.3253115 · Cited by 683 · see citing works
Kapitza conductance and heat flow between solids at temperatures from 50 to 300 K
Stoner, R. J., & Maris, H. J. (1993) · Physical Review B · doi:10.1103/physrevb.48.16373 · Cited by 646 · see citing works
Thermal conductance of interfaces between highly dissimilar materials
Lyeo, H.-K., & Cahill, D. G. (2006) · Physical Review B · doi:10.1103/physrevb.73.144301 · Cited by 576 · see citing works
Thermal Conductivity Spectroscopy Technique to Measure Phonon Mean Free Paths
Minnich, A. J., Johnson, J. A., Schmidt, A. J., Esfarjani, K., Dresselhaus, M. S., Nelson, K. A., & Chen, G. (2011) · Physical Review Letters · doi:10.1103/physrevlett.107.095901 · Cited by 556 · see citing works
Thermal resistance at interfaces
Swartz, E. T., & Pohl, R. O. (1987) · Applied Physics Letters · doi:10.1063/1.98939 · Cited by 410 · see citing works
Frequency dependence of the thermal conductivity of semiconductor alloys
Koh, Y. K., & Cahill, D. G. (2007) · Physical Review B · doi:10.1103/physrevb.76.075207 · Cited by 383 · see citing works
Landry, E. S., & McGaughey, A. J. H. (2009) · Physical Review B · doi:10.1103/physrevb.80.165304 · Cited by 344 · see citing works
Hopkins, P. E. (2013) · ISRN Mechanical Engineering · doi:10.1155/2013/682586 · Cited by 302 · see citing works
Stevens, R. J., Smith, A. N., & Norris, P. M. (2005) · Journal of Heat Transfer · doi:10.1115/1.1857944 · Cited by 293 · see citing works
Self-citationDispersion Relations for Phonons in Aluminum at 80 and 300°K
Stedman, R., & Nilsson, G. (1966) · Physical Review · doi:10.1103/physrev.145.492 · Cited by 281 · see citing works
Lattice Dynamics of Grey Tin and Indium Antimonide
Price, D. L., Rowe, J. M., & Nicklow, R. M. (1971) · Physical review. B, Solid state · doi:10.1103/physrevb.3.1268 · Cited by 260 · see citing works
Diffuse mismatch model of thermal boundary conductance using exact phonon dispersion
Reddy, P., Castelino, K., & Majumdar, A. (2005) · Applied Physics Letters · doi:10.1063/1.2133890 · Cited by 252 · see citing works
A survey of ohmic contacts to III-V compound semiconductors
Baca, A. G., Ren, F., Zolper, J. C., Briggs, R. D., & Pearton, S. J. (1997) · Thin Solid Films · doi:10.1016/s0040-6090(97)00439-2 · Cited by 243 · see citing works
Thermal conductance of metal–diamond interfaces at high pressure
Hohensee, G. T., Wilson, R. B., & Cahill, D. G. (2015) · Nature Communications · doi:10.1038/ncomms7578 · Cited by 197 · see citing works
Hopkins, P. E., Serrano, J. R., Phinney, L. M., Kearney, S. P., Grasser, T. W., & Harris, C. T. (2010) · ASME Journal of Heat and Mass Transfer · doi:10.1115/1.4000993 · Cited by 192 · see citing works
Physical Properties of III-V Semiconductor Compounds: InP, InAs, GaAs, GaP, InGaAs and InGaAsP
Adachi, S., & Tu, C. W. (1992) · Cited by 172 · see citing works
Thermal Boundary Resistance Measurements for Phase-Change Memory Devices
Reifenberg, J. P., Chang, K.-W., Panzer, M. A., Kim, S., Rowlette, J. A., Asheghi, M., Wong, H. ‐. P., & Goodson, K. E. (2009) · IEEE Electron Device Letters · doi:10.1109/led.2009.2035139 · Cited by 124 · see citing works
Handbook Series on Semiconductor Parameters
Levinshteĭn, M. E., Rumyantsev, S., & Shur, M. S. (1996) · WORLD SCIENTIFIC eBooks · doi:10.1142/2046-vol1 · Cited by 124 · see citing works
Hopkins, P. E. (2009) · Journal of Applied Physics · doi:10.1063/1.3169515 · Cited by 123 · see citing works
Buyco, E. H., & Davis, F. E. (1970) · Journal of Chemical & Engineering Data · doi:10.1021/je60047a035 · Cited by 108 · see citing works
Abruptness of Semiconductor-Metal Interfaces
Brillson, L. J., Brucker, C. F., Stoffel, N. G., Katnani, A. D., & Margaritondo, G. (1981) · Physical Review Letters · doi:10.1103/physrevlett.46.838 · Cited by 108 · see citing works
Indium arsenide: a semiconductor for high speed and electro-optical devices
Milnes, A. G., & Polyakov, A. Y. (1993) · Materials Science and Engineering B · doi:10.1016/0921-5107(93)90140-i · Cited by 105 · see citing works
Role of dispersion on phononic thermal boundary conductance
Duda, J. C., Beechem, T. E., Smoyer, J. L., Norris, P. M., & Hopkins, P. E. (2010) · Journal of Applied Physics · doi:10.1063/1.3483943 · Cited by 104 · see citing works
Self-citationThermal Interface Conductance Between Aluminum and Silicon by Molecular Dynamics Simulations
Yang, N., Luo, T., Esfarjani, K., Henry, A. S., Tian, Z., Shiomi, J., Chalopin, Y., Li, B., & Chen, G. (2015) · Journal of Computational and Theoretical Nanoscience · doi:10.1166/jctn.2015.3710 · Cited by 102 · see citing works
Role of interface disorder on thermal boundary conductance using a virtual crystal approach
Beechem, T. E., Graham, S. L., Hopkins, P. E., & Norris, P. M. (2007) · Applied Physics Letters · doi:10.1063/1.2437685 · Cited by 100 · see citing works
Self-citationSystematically controlling Kapitza conductance via chemical etching
Duda, J. C., & Hopkins, P. E. (2012) · Applied Physics Letters · doi:10.1063/1.3695058 · Cited by 98 · see citing works
Characterization of nanostructured metal films by picosecond acoustics and interferometry
O’Hara, K. E., Hu, X., & Cahill, D. G. (2001) · Journal of Applied Physics · doi:10.1063/1.1406543 · Cited by 95 · see citing works
Thermal Interface Conductance Between Aluminum and Silicon by Molecular Dynamics SimulationsPreprint
Yang, N., Luo, T., Esfarjani, K., Henry, A. S., Tian, Z., Shiomi, J., Chalopin, Y., Li, B., & Chen, G. (2015) · DSpace@MIT (Massachusetts Institute of Technology) · Cited by 92 · see citing works
Ground-state properties of GaAs and AlAs
Ihm, J., & Joannopoulos, J. D. (1981) · Physical review. B, Condensed matter · doi:10.1103/physrevb.24.4191 · Cited by 90 · see citing works
Interpreting picosecond acoustics in the case of low interface stiffness
Hohensee, G. T., Hsieh, W.-P., Losego, M. D., & Cahill, D. G. (2012) · Review of Scientific Instruments · doi:10.1063/1.4766957 · Cited by 87 · see citing works
Hopkins, P. E., & Norris, P. M. (2009) · ASME Journal of Heat and Mass Transfer · doi:10.1115/1.2995623 · Cited by 84 · see citing works
Self-citationBonding and pressure-tunable interfacial thermal conductance
Shen, M., Evans, W. J., Cahill, D. G., & Keblinski, P. (2011) · Physical Review B · doi:10.1103/physrevb.84.195432 · Cited by 82 · see citing works
Picosecond ultrasonics study of the modification of interfacial bonding by ion implantation
Tas, G., Loomis, J. J., Maris, H. J., Bailes, A. A., & Seiberling, L. E. (1998) · Applied Physics Letters · doi:10.1063/1.121276 · Cited by 81 · see citing works
Anomalous Behavior of the Lattice Vibrations and the Electronic Specific Heat of Palladium
Miiller, A. P., & Brockhouse, B. N. (1968) · Physical Review Letters · doi:10.1103/physrevlett.20.798 · Cited by 72 · see citing works
Anharmonic decay of optical phonon in diamond
Klemens, P. G. (1975) · Physical review. B, Solid state · doi:10.1103/physrevb.11.3206 · Cited by 51 · see citing works
THIN-FILM THERMAL CONDUCTIVITY AND THICKNESS MEASUREMENTS USING PICOSECOND ULTRASONICS
Hostetler, A. N. S. J. L. (1997) · Microscale Thermophysical Engineering · doi:10.1080/108939597200250 · Cited by 50 · see citing works
InP-Based Active and Passive Components for Communication Systems at 2 μm
Ye, N., Gleeson, M. R., Sadiq, M. U., Roycroft, B. J., Robert, C., Yang, H., Zhang, H., Morrissey, P. E., Suibhne, N. M., Thomas, K., et al. (2014) · Journal of Lightwave Technology · doi:10.1109/jlt.2014.2383492 · Cited by 49 · see citing works
Predictions of thermal boundary conductance for systems of disordered solids and interfaces
Beechem, T. E., & Hopkins, P. E. (2009) · Journal of Applied Physics · doi:10.1063/1.3267496 · Cited by 48 · see citing works
Vaporization of Aluminum Phosphide
Maria, G. D., Gingerich, K. A., & Piacente, V. (1968) · The Journal of Chemical Physics · doi:10.1063/1.1669933 · Cited by 37 · see citing works
Structure of the Al–GaP(110) and Al–InP(110) interfaces
Kahn, A., Bonapace, C. R., Duke, C. B., & Paton, A. (1983) · Journal of Vacuum Science & Technology B Microelectronics Processing and Phenomena · doi:10.1116/1.582609 · Cited by 36 · see citing works
Norris, P. M., Smoyer, J. L., Duda, J. C., & Hopkins, P. E. (2011) · ASME Journal of Heat and Mass Transfer · doi:10.1115/1.4004932 · Cited by 35 · see citing works
Self-citationOn the Linear Temperature Dependence of Phonon Thermal Boundary Conductance in the Classical Limit
Duda, J. C., Norris, P. M., & Hopkins, P. E. (2011) · ASME Journal of Heat and Mass Transfer · doi:10.1115/1.4003575 · Cited by 34 · see citing works
Self-citationInteratomic potentials for the vibrational properties of III-V semiconductor nanostructures
Han, P., & Bester, G. (2011) · Physical Review B · doi:10.1103/physrevb.83.174304 · Cited by 30 · see citing works
Gordiz, K., & Henry, A. S. (2015) · Scientific Reports · doi:10.1038/srep18361 · Cited by 24 · see citing works
ab initioシミュレーションによるPd 40 Ni 40 P 20 バルク金属ガラスの原子及び電子構造
Vijay, K., Fujita, T., Konno, K., Matsuura, M., Chen, M. W., Inoue, A., & Kawazoe, Y. (2011) · Physical Review B · Cited by 23 · see citing works
Evidence of palladium phosphide formation at the Pd/InP(110) interface
Kendelewicz, T., Petro, W. G., Lindau, I., & Spicer, W. E. (1983) · Physical review. B, Condensed matter · doi:10.1103/physrevb.28.3618 · Cited by 20 · see citing works
Exchange reaction, clustering, and surface segregation at the Al/InSb(110) interface
Boscherini, F., Shapira, Y., Capasso, C., Aldao, C. M., del Giudice, M., & Weaver, J. H. (1987) · Physical review. B, Condensed matter · doi:10.1103/physrevb.35.9580 · Cited by 16 · see citing works
The formation of the Al-InSb(110) interface
Sporken, R., Xhonneux, P., Caudano, R., & Delrue, J. P. (1988) · Surface Science · doi:10.1016/0039-6028(88)90322-6 · Cited by 9 · see citing works
The history and future of InP based electronics and optoelectronics
Lile, D. L. (2002) · Conference proceedings. ... International Conference on Indium Phosphide and Related Materials · doi:10.1109/iciprm.1998.712387 · Cited by 6 · see citing works
Dixit, V. K., & Bhat, H. L. (2010) · Springer eBooks · doi:10.1007/978-3-540-74761-1_11 · Cited by 4 · see citing works
Investigation of Nanoscale Heat Transfer with Highly Versatile Phase-Locked Thermoreflectance
Norris, P. M., Smoyer, J. L., Redding, M. R., & Larkin, L. S. (2014) · International Heat Transfer Conference (IHTC) · doi:10.1615/ihtc15.kn.000025 · Cited by 2 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Jiang, P., Qian, X., & Yang, R. (2018) · Journal of Applied Physics · doi:10.1063/1.5046944 · Cited by 424 · see citing works
Song, S., Oh, I., Jang, S., Yoon, A., Han, J., Lee, Z., Yoo, J., & Kwon, S. (2022) · iScience · doi:10.1016/j.isci.2022.105346 · Cited by 16 · see citing works
Pfeifer, T. W., Schonfeld, H. B., Scott, E. A., Aller, H. T., Gaskins, J. T., OLSON, D. H. L., Braun, J. L., Graham, S. L., & Hopkins, P. E. (2025) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-080423-010435 · Cited by 13 · see citing works
Incoherent-to-coherent crossover in thermal transport through III–V alloy superlattices
Perez, C., Avazpour, L., Eryilmaz, M. K., Earles, T. L., Ruder, S., Gopalan, V., Botez, D., Knežević, I., Ramos-Alvarado, B., Foley, B. M., et al. (2022) · Applied Physics Letters · doi:10.1063/5.0123711 · Cited by 11 · see citing works
Nonequilibrium thermal resistance of interfaces between III-V compounds
Han, J., & Lee, S. (2024) · Physical Review Materials · doi:10.1103/physrevmaterials.8.014604 · Cited by 9 · see citing works
Badine, E., Bardoux, M., Abboud, N., Depriester, M., Longuemart, S., Herro, Z., & Hadj-Sahraoui, A. (2019) · Journal of Physics D Applied Physics · doi:10.1088/1361-6463/ab0ac7 · Cited by 8 · see citing works
Progress in measuring, modeling, and manipulating thermal boundary conductance
Norris, P. M., Larkin, L. S., Le, N. Q., Polanco, C. A., Smoyer, J. L., & Zhang, J. (2021) · Advances in heat transfer · doi:10.1016/bs.aiht.2021.07.001 · Cited by 4 · see citing works
Self-citationPerez, C., Talreja, D., Kirch, J. D., Zhang, S., Gopalan, V., Botez, D., Foley, B. M., Ramos-Alvarado, B., & Mawst, L. J. (2023) · APL Materials · doi:10.1063/5.0141252 · Cited by 1 · see citing works
Engineering Interfaces at the Nanoscale
Norris, P. M., & Larkin, L. S. (2019) · Women in engineering and science · doi:10.1007/978-3-030-19951-7_8
Self-citation
- Authors
- Larkin, L. S., Redding, M. R., Le, N. Q., & Norris, P. M.
- Affiliations
- University of Virginia (US)
- Corresponding author
- Larkin, LeighAnn S.
- Venue
- Journal of Heat Transfer
- Publisher
- Wiley
- Published
- 2016-11-22
- Volume
- 139
- Issue
- 3
- ISSN
- 0022-1481 (ISSN-L)
- 1528-8943
- OpenAlex
- W2530279685
- Cited by
- 10
- References
- 56
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 1 · 2022: 2 · 2021: 1 · 2019: 3 · 2018: 1
- FWCI
- 0.59
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ASME Journal of Heat and Mass Transfer (publishedVersion)
- Funders
- National Science Foundation
- Johns Hopkins University
- National Defense Science and Engineering Graduate
- Air Force Office of Scientific Research
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Thermal properties of materials
- Physical Sciences › Engineering › Mechanics of Materials › Thermography and Photoacoustic Techniques
- Physical Sciences › Engineering › Mechanics of Materials › Thermoelastic and Magnetoelastic Phenomena
- Keywords
- thermal boundary conductance, III-V semiconductors, indium, time-domain thermoreflectance, acoustic mismatch, interfacial strength, phonon density of states, interfacial mixing, grain size effects, hot spots, thermal management, thin film interfaces
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review