The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Chemical reactions induced by low-energy electron exposure on a novel inorganic-organic hybrid dry EUV photoresist deposited by molecular atomic layer deposition (MALD)
Abstract
Herein, we investigated the chemical reactions associated with low-energy electron exposures on an inorganic-organic hybrid thin film system deposited using molecular atomic layer deposition (MALD) for EUV photoresist applications. Using the hybrid thin films consisting of trimethylaluminum (TMA) and hydroquinone (HQ), we determined the critical doses and thickness contrast of the hybrid materials at various electron energies (up to 400 eV). The custom-built in-situ Fourier-Transform Infrared (FTIR) spectroscopy system, equipped with an electron flood gun and gas residual analyzer (RGA), was employed to monitor the chemical changes induced by low-energy electrons in the hybrid thin films. Based on the in-situ FTIR and RGA results, potential chemical reaction mechanisms responsible for the change in solubility of the TMA/HQ material are proposed.
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Le et al. explored MALD films composed of TMA and hydroquinone, demonstrating utility in generating negative-tone patterns using low-energy electron exposure.
“Further research by Le et al. explored MALD films composed of TMA and hydroquinone (HQ), demonstrating the utility of the technique in generating negative-tone patterns using low-energy electron exposure [40].”
From Recent Advances in Metal-Oxide-Based Photoresists for EUV Lithography (2024) · cites this paper as [40]
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Mattson, E. C., Cabrera, Y., Rupich, S. M., Wang, Y., Oyekan, K. A., Mustard, T. J., Halls, M. D., Bechtel, H. A., Martin, M. C., & Chabal, Y. J. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b03149 · Cited by 66
Molecular layer deposition of a hafnium-based hybrid thin film as an electron beam resist
Shi, J., Ravi, A., Richey, N. E., Gong, H., & Bent, S. F. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c04092 · Cited by 54
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Research works printed but not linked: 15
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Recent Advances in Metal-Oxide-Based Photoresists for EUV Lithography
Hasan, M. W., Deeb, L., Kumaniaev, S., Wei, C., & Wang, K. (2024) · Micromachines · doi:10.3390/mi15091122 · Cited by 35
“( b ) Workflow Molecular atomic layer deposition (MALD) Further research by Le et al. explored MALD films composed of TMA and hydro-quinone (HQ), demonstrating the utility of the technique in generating negative-tone patterns using low-energy electron exposure [40].”
MethodAtomic layer deposition and its derivatives for extreme ultraviolet (EUV) photoresist applications
Le, D. N., Park, T., Hwang, S. M., Kim, J.-H., Jung, Y. C., Tiwale, N., Subramanian, A., Lee, W.-I., Choi, R., Sung, M. M., et al. (2023) · Japanese Journal of Applied Physics · doi:10.35848/1347-4065/acce43 · Cited by 26
Metadata
- Authors
- Le, D. N., Hwang, S. M., Woo, J., Choi, S., Park, T., Veyan, J.-F., Tiwale, N. M., Subramanian, A., Lee, W.-I., Nam, C.-Y., Choi, R., & Kim, J.
- Affiliations
- The University of Texas at Dallas (US)
- Stony Brook University (US)
- Inha University (KR)
- ORCID
- Venue
- International Conference on Extreme Ultraviolet Lithography 2022
- Publisher
- SPIE
- Published
- 2022-12-01
- Pages
- 6
- OpenAlex
- W4308702036
- Cited by
- 11
- References
- 2
- Citations by year
- 2026: 4 · 2025: 2 · 2024: 4 · 2023: 1
- FWCI
- 2.83
- Type
- conference paper
- Language
- en
- Open access
- closed
- Locations
- International Conference on Extreme Ultraviolet Lithography (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Photolithography Techniques
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Semiconductor materials and devices
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › Electron and X-Ray Spectroscopy Techniques
- Keywords
- EUV photoresists, trimethylaluminum, hydroquinone, critical dose, solubility, reaction mechanism, in situ FTIR spectroscopy, residual gas analysis
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