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Stable perovskite solar cells with efficiency exceeding 24.8% and 0.3-V voltage loss
Abstract
Operating in wet conditions: The high efficiency of the complex organic molecule Spiro-OMeTAD as a hole-transporting material for perovskite solar cells requires the use of hygroscopic dopants that decrease stability. Jeong et al. synthesized hydrophobic fluorinated analogs of Spiro-OMeTAD as hole-transporting materials that have favorable shifting of the electronic state for hole extraction and used them to fabricate perovskite solar cells. A champion device had a certified power conversion efficiency of 24.8% and an open-circuit voltage near the Shockley-Queisser limit. These devices could maintain more than 87% of the original power conversion efficiency under 50% relative humidity for more than 500 hours. Science , this issue p. 1615
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Detailed Balance Limit of Efficiency of p-n Junction Solar Cells
Shockley, W., & Queisser, H. J. (1961) · Journal of Applied Physics · doi:10.1063/1.1736034 · Cited by 13,258
Electronic Population Analysis on LCAO–MO Molecular Wave Functions. I
Mulliken, R. S. (1955) · The Journal of Chemical Physics · doi:10.1063/1.1740588 · Cited by 11,049
From molecules to solids with the DMol3 approach
Delley, B. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1316015 · Cited by 11,026
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
Lee, M. M., Teuscher, J., Miyasaka, T., Murakami, T. N., & Snaith, H. J. (2012) · Science · doi:10.1126/science.1228604 · Cited by 10,687
An all-electron numerical method for solving the local density functional for polyatomic molecules
Delley, B. (1990) · The Journal of Chemical Physics · doi:10.1063/1.458452 · Cited by 10,536
Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
Burschka, J., Pellet, N., Moon, S.-J., Humphry-Baker, R., Gao, P., Nazeeruddin, M. K., & Grätzel, M. (2013) · Nature · doi:10.1038/nature12340 · Cited by 9,547
Efficient planar heterojunction perovskite solar cells by vapour deposition
Liu, M., Johnston, M. B., & Snaith, H. J. (2013) · Nature · doi:10.1038/nature12509 · Cited by 7,976
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Compositional engineering of perovskite materials for high-performance solar cells
Jeon, N. J., Noh, J. H., Yang, W. S., Kim, Y. C., Ryu, S., Seo, J., & Seok, S. I. (2015) · Nature · doi:10.1038/nature14133 · Cited by 6,431
Tkatchenko, A., & Scheffler, M. (2009) · Physical Review Letters · doi:10.1103/physrevlett.102.073005 · Cited by 6,286
Saliba, M., Matsui, T., Seo, J.-Y., Domanski, K., Correa-Baena, J.-P., Nazeeruddin, M. K., Zakeeruddin, S. M., Tress, W., Abate, A., Hagfeldt, A., et al. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03874j · Cited by 5,440
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
Shi, D., Adinolfi, V., Comin, R., Yuan, M., Alarousu, E., Buin, A., Chen, Y., Hoogland, S., Rothenberger, A., Katsiev, K., et al. (2015) · Science · doi:10.1126/science.aaa2725 · Cited by 5,139
Surface passivation of perovskite film for efficient solar cells
Jiang, Q., Zhao, Y., Zhang, X., Yang, X., Chen, Y., Chu, Z., Ye, Q., Li, X., Yin, Z., & You, J. (2019) · Nature Photonics · doi:10.1038/s41566-019-0398-2 · Cited by 4,736
Charge Transport in Organic Semiconductors
Coropceanu, V., Cornil, J., da Silva Filho, D. A., Olivier, Y., Silbey, R., & Brédas, J.-L. (2007) · Chemical Reviews · doi:10.1021/cr050140x · Cited by 4,607
Eperon, G. E., Stranks, S. D., Menelaou, C., Johnston, M. B., Herz, L. M., & Snaith, H. J. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43822h · Cited by 4,140
Bach, U., Lupo, D., Comte, P., Moser, J. E., Weissörtel, F., Salbeck, J., Spreitzer, H., & Grätzel, M. (1998) · Nature · doi:10.1038/26936 · Cited by 3,528
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
Snaith, H. J. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz4020162 · Cited by 3,042
Heo, J. H., Im, S. H., Noh, J. H., Mandal, T. N., Lim, C.-S., Chang, J. A., Lee, Y. H., Kim, H.-J., Sarkar, A., Nazeeruddin, M. K., et al. (2013) · Nature Photonics · doi:10.1038/nphoton.2013.80 · Cited by 2,684
Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene)
Jung, E. H., Jeon, N. J., Park, E. Y., Moon, C. S., Shin, T. J., Yang, T.-Y., Noh, J. H., & Seo, J. (2019) · Nature · doi:10.1038/s41586-019-1036-3 · Cited by 2,305
Jeon, N. J., Na, H., Jung, E. H., Yang, T.-Y., Lee, Y. G., Kim, G., Shin, H.-W., Il Seok, S., Lee, J., & Seo, J. (2018) · Nature Energy · doi:10.1038/s41560-018-0200-6 · Cited by 2,089
Self-citationEfficient luminescent solar cells based on tailored mixed-cation perovskites
Bi, D., Tress, W., Dar, M. I., Gao, P., Luo, J., Renevier, C., Schenk, K., Abate, A., Giordano, F., Correa Baena, J.-P., et al. (2016) · Science Advances · doi:10.1126/sciadv.1501170 · Cited by 1,864
Kim, M., Kim, G.-H., Lee, T. K., Choi, I. W., Choi, H. W., Jo, Y., Yoon, Y. J., Kim, J. W., Lee, J., Huh, D., et al. (2019) · Joule · doi:10.1016/j.joule.2019.06.014 · Cited by 1,753
Self-citationSolution-processed small-molecule solar cells with 6.7% efficiency
Sun, Y., Welch, G. C., Leong, W. L., Takacs, C. J., Bazan, G. C., & Heeger, A. J. (2012) · Nature Materials · doi:10.1038/nmat3160 · Cited by 1,496
Mixed‐Organic‐Cation Perovskite Photovoltaics for Enhanced Solar‐Light Harvesting
Pellet, N., Gao, P., Gregori, G., Yang, T., Nazeeruddin, M. K., Maier, J., & Grätzel, M. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309361 · Cited by 1,306
Efficient, stable solar cells by using inherent bandgap of α-phase formamidinium lead iodide
Min, H., Kim, M., Lee, S.-U., Kim, H., Kim, G., Choi, K., Lee, J. H., & Seok, S. I. (2019) · Science · doi:10.1126/science.aay7044 · Cited by 1,268
Self-citationHigh-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor
Holliday, S., Ashraf, R. S., Wadsworth, A., Baran, D., Yousaf, S. A., Nielsen, C. B., Tan, C.-H., Dimitrov, S. D., Shang, Z., Gasparini, N., et al. (2016) · Nature Communications · doi:10.1038/ncomms11585 · Cited by 1,195
Bin, H., Gao, L., Zhang, Z.-G., Yang, Y., Zhang, Y., Zhang, C., Chen, S., Xue, L., Yang, C., Xiao, M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13651 · Cited by 987
Self-citationHigh‐Efficiency Perovskite Solar Cells Based on the Black Polymorph of HC(NH2)2PbI3
Lee, J., Seol, D., Cho, A., & Park, N. (2014) · Advanced Materials · doi:10.1002/adma.201401137 · Cited by 951
Self-citationA molecularly engineered hole-transporting material for efficient perovskite solar cells
Saliba, M., Orlandi, S., Matsui, T., Aghazada, S., Cavazzini, M., Correa-Baena, J.-P., Gao, P., Scopelliti, R., Mosconi, E., Dahmen, K.-H., et al. (2016) · Nature Energy · doi:10.1038/nenergy.2015.17 · Cited by 944
Babudri, F., Farinola, G. M., Naso, F., & Ragni, R. (2007) · Chem. Commun. · doi:10.1039/b611336b · Cited by 895
o-Methoxy Substituents in Spiro-OMeTAD for Efficient Inorganic–Organic Hybrid Perovskite Solar Cells
Jeon, N. J., Lee, H. G., Kim, Y. C., Seo, J., Noh, J. H., Lee, J., & Seok, S. I. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502824c · Cited by 787
Self-citationHutchison, G. R., Ratner, M. A., & Marks, T. J. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0461421 · Cited by 742
A dopant-free hole-transporting material for efficient and stable perovskite solar cells
Liu, J., Wu, Y., Qin, C., Yang, X., Yasuda, T., Islam, A., Zhang, K., Peng, W., Chen, W., & Han, L. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01589d · Cited by 719
Liu, Y., Akin, S., Pan, L., Uchida, R., Arora, N., Milić, J. V., Hinderhofer, A., Schreiber, F., Uhl, A. R., Zakeeruddin, S. M., et al. (2019) · Science Advances · doi:10.1126/sciadv.aaw2543 · Cited by 710
Understanding Energy Loss in Organic Solar Cells: Toward a New Efficiency Regime
Menke, S. M., Ran, N. A., Bazan, G. C., & Friend, R. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.020 · Cited by 630
Low surface recombination velocity in solution-grown CH3NH3PbBr3 perovskite single crystal
Yang, Y., Yan, Y., Yang, M., Choi, S., Zhu, K., Luther, J. M., & Beard, M. C. (2015) · Nature Communications · doi:10.1038/ncomms8961 · Cited by 519
The Rise of Highly Efficient and Stable Perovskite Solar Cells
Grätzel, M. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00492 · Cited by 375
Carbon-based materials for stable, cheaper and large-scale processable perovskite solar cells
Fagiolari, L., & Bella, F. (2019) · Energy & Environmental Science · doi:10.1039/c9ee02115a · Cited by 355
Kawashima, K., Fukuhara, T., Suda, Y., Suzuki, Y., Koganezawa, T., Yoshida, H., Ohkita, H., Osaka, I., & Takimiya, K. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05418 · Cited by 342
Kirchartz, T., & Rau, U. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703385 · Cited by 305
Gradient Energy Alignment Engineering for Planar Perovskite Solar Cells with Efficiency Over 23%
Wang, P., Li, R., Chen, B., Hou, F., Zhang, J., Zhao, Y., & Zhang, X. (2020) · Advanced Materials · doi:10.1002/adma.201905766 · Cited by 257
Bronstein, H., Frost, J. M., Hadipour, A., Kim, Y., Nielsen, C. B., Ashraf, R. S., Rand, B. P., Watkins, S., & McCulloch, I. (2013) · Chemistry of Materials · doi:10.1021/cm301910t · Cited by 239
Li, Z., Zhu, Z., Chueh, C.-C., Jo, S. B., Luo, J., Jang, S.-H., & Jen, A. K.-Y. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06291 · Cited by 209
Caesium for Perovskite Solar Cells: An Overview
Bella, F., Renzi, P., Cavallo, C., & Gerbaldi, C. (2018) · Chemistry – A European Journal · doi:10.1002/chem.201801096 · Cited by 176
Jheng, J., Lai, Y., Wu, J., Chao, Y.-H., Wang, C., & Hsu, C. (2013) · Advanced Materials · doi:10.1002/adma.201300098 · Cited by 132
Chen, H., & Yang, S. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta04707g · Cited by 127
Torres, A., & Rego, L. G. C. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp510595s · Cited by 121
Carbon Counter Electrodes in Dye‐Sensitized and Perovskite Solar Cells
Wu, M., Sun, M., Zhou, H., Ma, J., & Ma, T. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201906451 · Cited by 115
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Jaiswal, K. K., Chowdhury, C. R., Yadav, D., Verma, R., Dutta, S., Jaiswal, K. S., SangmeshB, & Karuppasamy, K. S. K. (2022) · Energy Nexus · doi:10.1016/j.nexus.2022.100118 · Cited by 770
Bu, T., Li, J., Li, H., Tian, C., Su, J., Tong, G., Ono, L. K., Wang, C., Lin, Z., Chai, N., et al. (2021) · Science · doi:10.1126/science.abh1035 · Cited by 731
Regulating surface potential maximizes voltage in all-perovskite tandems
Chen, H., Maxwell, A., Li, C., Teale, S., Chen, B., Zhu, T., Ugur, E., Harrison, G., Grater, L., Wang, J., et al. (2023) · Nature · doi:10.1038/s41586-022-05541-z · Cited by 623
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Isikgor, F. H., Zhumagali, S., T. Merino, L. V., De Bastiani, M., McCulloch, I., & De Wolf, S. (2022) · Nature Reviews Materials · doi:10.1038/s41578-022-00503-3 · Cited by 600
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Green, M. A., Dunlop, E. D., Hohl‐Ebinger, J., Yoshita, M., Kopidakis, N., & Hao, X. (2021) · Progress in Photovoltaics: Research and Applications · doi:10.1002/pip.3444 · Cited by 503
Metadata
- Authors
- Jeong, M., Choi, I. W., Go, E. M., Cho, Y., Kim, M., Lee, B., Jeong, S., Jo, Y., Choi, H. W., Lee, J., Bae, J.-H., Kwak, S. K., Kim, D. S., & Yang, C.
- Venue
- Science
- Published
- 2020-09-25
- Volume
- 369
- Issue
- 6511
- Pages
- 1615-1620
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3088739094
- Cited by
- 1,517
- References
- 50
- FWCI
- 92.24
- Type
- journal article
- Language
- en
- Open access
- closed
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