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A review of iron and cobalt porphyrins, phthalocyanines and related complexes for electrochemical and photochemical reduction of carbon dioxide

Open access
Manbeck, Gerald F., Fujita, Etsuko·2015·Journal of Porphyrins and Phthalocyanines

Abstract

This review summarizes research on the electrochemical and photochemical reduction of CO 2 using a variety of iron and cobalt porphyrins, phthalocyanines and related complexes. Metalloporphyrins and metallophthalocyanines are visible light absorbers with extremely large extinction coefficients. However, yields of photochemically-generated active catalysts for CO 2 reduction are typically low owing to the requirement of a second photoinduced electron. This requirement is not relevant to the case of electrochemical CO 2 reduction. Recent progress on efficient and stable electrochemical systems includes the use of FeTPP catalysts that have prepositioned phenyl OH groups in their second coordination spheres. This has led to remarkable progress in carrying out coupled proton-electron transfer reactions for CO 2 reduction. Such ground-breaking research has to be continued in order to produce renewable fuels in an economically feasible manner.

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Metadata

Authors
Manbeck, G. F., & Fujita, E.
Venue
Journal of Porphyrins and Phthalocyanines
Published
2015-01
Volume
19
Issue
01-03
Pages
45-64
ISSN
  • 1088-4246 (ISSN-L)
  • 1099-1409
OpenAlex
W2029265212
Cited by
239
References
3
FWCI
5.28
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: A review of iron and cobalt porphyrins, phthalocyanines and related complexes for electrochemical and photochemical reduction of carbon dioxide. https://app.cochat.ai/papers/10.1142/s1088424615300013
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Manbeck, G. F., & Fujita, E. (2015). A review of iron and cobalt porphyrins, phthalocyanines and related complexes for electrochemical and photochemical reduction of carbon dioxide. Journal of Porphyrins and Phthalocyanines. https://doi.org/10.1142/s1088424615300013

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.