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Cited by 1,408Battery Modeling and ManagementAdvancements in Battery MaterialsAdvanced Battery Materials and Technologies

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Capacity Fade Mechanisms and Side Reactions in Lithium‐Ion Batteries

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Arora, Pankaj, White, Ralph E., Doyle, Marc·1998·Journal of The Electrochemical Society
DOI 10.1149/1.1838857
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Abstract

The capacity of a lithium‐ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms which are due to or are associated with unwanted side reactions that occur in these batteries. These reactions occur during overcharge or overdischarge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. These capacity loss mechanisms are not included in the present lithium‐ion battery mathematical models available in the open literature. Consequently, these models cannot be used to predict cell performance during cycling and under abuse conditions. This article presents a review of the current literature on capacity fade mechanisms and attempts to describe the information needed and the directions that may be taken to include these mechanisms in advanced lithium‐ion battery models.

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Research works printed but not linked: 101

  1. B. Scrosati, J. Electrochem. Soc., 139, 10 (1992).
  2. S. Megahed and B. Scrosati, Elect rochem. Soc. Inter- face, 4(4), 34 (1995).
  3. T. Nagaura, Prog. Batteries Battery Mater., 10, 218 (1991).
  4. K. G. McColl, J. Power Sources, 48, 29 (1994).
  5. D. Linden, Handbook of Batteries and Fuel Cells, 1st ed., McGraw-Hill Book Company, New York (1984).
  6. K. M. Abraham, Elect rochim. Acta, 38, 1233 (1993).
  7. K. Brandt, Solid State lonics, 69, 173 (1994).
  8. K. Sekai, H. Azuma, A. Omaru, S. Fujita, H. Imoto, T. Endo, K. Yamaura, and Y. Nishi, J. Power Sources, 43-44, 241 (1993).
  9. K. Ozawa, Solid State lonics, 69, 212 (1994).
  10. B. A. Johnson and R. E. White, J. Power Sources, 70/1, 48 (1998).
  11. S. Yoda, .1. Power Sources, 68, 3 (1997).
  12. B. C. Knutz, K. West, B. Z.-Christiansen, and S. Atlung, J. Power Sources, 43-44, 733 (1993).
  13. K. West, T. Jacobsen, and S. Atlung, J. Electrochem. Soc., 129, 1480 (1982).
  14. S. Atlung, K. West, and T. Jacobsen, J. Electrochem. Soc., 126, 1311 (1979).
  15. Atlung, B. Z,-Christiansen, K. West, and T. Jacob- sen, J. Electrochem. Soc., 131, 1200 (1984).
  16. Z. Mao and R. E. White, J. Power Sources, 43-44, 181 (1993).
  17. R. M. Spotnitz, D. Zuckerbrod, S. L. Johnson, J. T. Lundquist, and R. E. White, in Proceedings of the Symposium on Modeling of Batteries and Fuel Cells, R. E. White, M. W. Verbrugge, and J. F Stock- el, Editors, PV 91-10, p. 88, The Electrochemical Society, Proceedings Series, Pennington, NJ (1991).
  18. M. Doyle, T. F Fuller, and J. Newman, J. Electrochem. Soc., 140, 1527 (1993).
  19. T. F Fuller, M. Doyle, and J. Newman, J. Electrochem. Soc., 141, 1 (1994).
  20. M. Doyle, Ph.D Thesis, University of California, Berkeley, CA (1995).
  21. T. F Fuller, M. Doyle, and J. Newman, J. Electrochem. Soc., 141, 982 (1994).
  22. M. Doyle, J. Newman, A. S. Gozdz, C. N. Schmutz, and J. M. Tarascon, J. Electrochem. Soc., 143, 1890 (1996).
  23. M. Doyle, J. Newman, and J. Reimers, J. Power Sources, 52, 211 (1994).
  24. M. Doyle and J. Newman, J. Power Sources, 54, 46 (1995).
  25. Y. Chen and J. W. Evans, J. Electrochem Soc., 140, 1833 (1993).
  26. Y. Chen and J. W. Evans, J. Electrochem Soc., 141, 2947 (1994).
  27. Y. Chen and J. W. Evans, J. Electrochem Soc., 143, 2708 (1996).
  28. C. R. Pals and J. Newman, J. Electrochem Soc., 142, 3274 (1995).
  29. C. R. Pals and J. Newman, J. Electrochem Soc., 142, 3282 (1995).
  30. M. W. Verbrugge and B. J. Koch, J. Electrochem. Soc., 143, 24 (1996).
  31. M. W. Verbrugge and B. J. Koch, J. Elect rochem. Soc., 143, 600 (1996).
  32. S. R. Narayanan, S. Surampudi, A. I. Attia, and C. P. Bankston, J. Electrochem. Soc., 138, 8 (1991).
  33. R. Darling and J. Newman, J. Electrochem. Soc., 144, 4201 (1997).
  34. G. Nagarajan, J. W. VanZee, and R. M. Spotnitz, J. Electrochem. Soc., 145, 771 (1998).
  35. F. Darling and J. Newman, J. Electrochem. Soc., 145, 990 (1998).
  36. M. Armand, Solid State lonics, 9&10, 745 (1983).
  37. J. M. Tarascon and D. Guyomard, Electrochim. Acta, 38, 1221 (1993).
  38. D. Guyomard and J. M. Tarascon, Solid State lonics, 69, 222 (1994).
  39. R. Pollard and J. Newman, J. Electrochem Soc., 128, 491 (1981).
  40. A. B. Yu, R. P. Zou, and N. Standish, md. Eng. Chem. Res., 35, 3730 (1996).
  41. D. Guyomard and J. M. Tarascon, J. Electrochem. Soc., 139, 4 (1992).
  42. R. Fong, U. von Sacken, and J. R. Dahn, J. Elec- trochem. Soc., 137, 2009 (1990).
  43. D. Fauteux and R. Kosbang, J. Appl. Electrochem., 22, 1 (1992).
  44. T. Zheng, Y. Liu, E, W. Fuller, S. Tseng, U. von Sack- en, and J. R. Dahn, J. Electrochem. Soc., 142, 2581 (1995).
  45. W. Xing and J. R. Dahn, J. Electrochem. Soc., 144, 1195 (1997).
  46. J. R. Dahn, T. Zheng, Y. Liu, and J. S. Xue, Science, 270, 590 (1995).
  47. J. M. Tarascon and D. Guyomard, J. Electrochem. Soc., 138, 2865 (1991).
  48. J. M. Tarascon and D. Guyomard, J. Power Sources, 43-44, 689 (1993).
  49. D. Peramunage, K. M. Abraham, and E. B. Willstaedt, in 13th Proceedings of the Annual Battery Confer- ence on Applications and Advances, Long Beach, CA, p. 107, Jan 13-16, 1998.
  50. E. Peled, Abstract 72, p. 114, The Electrochemical Society Meeting Abstracts, Vol. 94-2, Miami Beach, FL, Oct 9-14, 1994.
  51. F. Peled, in Lithium Batteries, J. P Gabano, Editor, Academic Press New York (1983).
  52. J. F. Dahn, E, W. Fuller, M. Obravae, and U. von Sacken, Solid State lonics, 69, 265 (1994).
  53. A. S. Gozdz and R. K. Jaworski, Abstract 43, p. 52, The Electrochemical Society Meeting Abstracts, Vol. 96-1, Los Angeles, CA, May 5-10, 1996.
  54. Y. Em-Eli, B. Markovsky, D. Aurbach, Y. Carmeli, H. Yamin, and S. Luski, Electrochim. Acta, 39, 2559 (1994).
  55. R. J. Staniewicz, in 13th Proceedings of The Interna- tional Seminar on Primary and Secondary Battery Technology and Applications, Boca Raton, FL, March 4-7, 1996.
  56. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 3rd ed. John Wiley & Sons, Inc., New York (1993).
  57. G. A. Nazri, A. Rougier, and K. F Kia, Mater. Res. Soc. Symp. Proc., 453, 635 (1997).
  58. M. Hasegawa, B. Yasuhiko, M. Toshihide, and T. Yoshinori, U.S. Pat. 5,631,105 (1997).
  59. Y. Junichi, 0. Kazuhiro, and N. Yoshiaki, U.S. Pat. 5,626,635 (1997).
  60. C. Delmas, Solid State lonics, 53-56, 370 (1992).
  61. W Li and J. C. Currie, J. Electrochem. Soc., 144, 2773 (1997).
  62. M. M. Thackeray, M. F Mansuetto, D. W. Dees, and D. R. Vissers, Mater. Res. Bull., 31, 133 (1996).
  63. Y. Gao and J. F. Dahn, Solid State Ionics, 84, 33 (1996).
  64. J. M. Tarascon and D. Guyomard, Solid State Ionics, 69, 293 (1994).
  65. A. Campbell, C. Bowes, and R. S. McMillan, J. Electroanal. Chem., 284, 195 (1990).
  66. K. Kanamura, S. Toriyama, S. Shiraishi, and Z. Take- hara, J. Elect rochem. Soc., 142, 1383 (1995).
  67. A. M. Christie and C. A. Vincent, J. Appl. Electro- chem., 26, 255 (1996),
  68. J. Electrochem. Soc., Vol. 145, No. 10, October 1998 Electrochemical Society, Inc.
  69. F Ossola, G. Pistoia, F. Seeber, and P. Ugo, Electro- chim. Acta, 33, 47 (1988).
  70. P Novak, P. A. Christensen, T. Iwasita, and W. Viel- stich, J. Elect roanal. Chem., 263, 37 (1989).
  71. F. Cattaneo and J. Ruch, J. Power Sources, 43-44, 341 (1993).
  72. G. Eggert, and J. Heitbaum, Electrochim. Acta, 31, 1443 (1986).
  73. K. Kanamura, H. Takezawa, S. Shiraishi, and Z. Takehara, J. Elect rochem. Soc., 144, 1900 (1997).
  74. K. Kanamura, S. Toriyama, S. Shiraishi, and Z. Take- hara, J. Electrochem. Soc., 143, 2548 (1996).
  75. Oishi, T. Abe, T. Nagaura, and M. Watanabe, U.S. Pat. 4,943,497 (1990).
  76. M. N. Golovin, D. P. Wilkinson, J. T. Dudley, D. Holonko, and S. Woo, J. Electrochem. Soc., 139, 5 (1992).
  77. T. J. Richardson and P. N. Ross, Jr., J. Electrochem. Soc., 143, 3992 (1996).
  78. K. M. Abraham, D. M. Pasquariello, and E. B. Will- staedt, in Proceedings of the 33rd Power Sources Symposium, Cherry Hill, NJ, June 13-16, p. 38, The Electrochemical Society, Inc. (1988).
  79. W. K. Behl and D. T. Chin, J. Electrochem. Soc., 135, 18 (1988).
  80. W. K. Behl and D. T. Chin, J. Electrochem. Soc., 135, 21 (1988).
  81. K. J. Hanson and C. W Tobias, J. Electroche;n. Soc., 134, 2204 (1987).
  82. K. J. Hanson, M. J. Matlosz, C. W Tobias, andJ. New- man, J. Electrochem. Soc., 134, 2210 (1987).
  83. K. Ozawa, Solid State Ionics, 69, 212 (1994).
  84. F. C. Laman, M. A. Gee, and J. Denovan, J. Elec- trochem. Soc., 140, L51 (1993).
  85. J. P Lundquist, C. B. Lundsager, N. I. Palmer, and H. J. Troffkin, U.S. Pat. 4,650,730 (1987).
  86. J. T. Lundquist, C. B. Lundsager, N. I. Palmer, and H. J. Troffkin, U.S. Pat. 4,731,304 (1988).
  87. H. T. Taskier, S. M. Mullins, F. A. Langford, and R. J. Fleming, U.S. Pat. 4,973,532 (1990).
  88. H. Spotnitz and M. Ferebree, Abstract 132, p. 179, The Electrochemical Society Meeting Abstracts, Vol. 96- 2, San Antonio, TX, Oct 6-11, 1996.
  89. U. von Sacken, Paper presented at POWER '97, 5th International Conference on Power Requirements for Mobile Computing and Wireless Communica- tions, Santa Clara, CA, Oct 12-15, 1997.
  90. D. Guyomard and J. M. Tarascon, J. Power Sources, 54, 92 (1995).
  91. D. Aurbach, Y. Em-Eli, 0. Chusid, Y. Carmeli, M. Babai, and H. Yamin, J. Electrochem. Soc., 141, 603 (1994).
  92. A. N. Dey and B. P. Sullivan, J. Electrochem. Soc., 117, 222 (1970).
  93. Chusid, Y. Em-Eli, and D. Aurbach, J. Power Sources, 43-44, 47 (1993).
  94. Y. Matsumura, S. Wang, and J. Mondori, J. Elec- trochem. Soc., 142, 2914 (1995).
  95. Z. X. Shu, R. S. McMillan, and J. J. Murray, J. Elec- trochem. Soc., 140, 922 (1993).
  96. A. C. Chu, J. V. Josefowicz, and G. C. Farrington, J. Electrochem. Soc., 144, 4161 (1997).
  97. D. Aurbach, M. L. Daroux, P. W. Faguy, and E. Yeager, J. Electrochem. Soc., 134, 1611 (1987).
  98. V. Em-Eli, S. R. Thomas, and V. R. Koch, J. Elec- trochem. Soc, 144, 1159 (1997). 100. V. Em-Eli, S. F McDevitt, D. Aurbach, B. Markovsky, and A. Schechter, J. Electrochem. Soc., 144, L180 (1997), 101.
  99. K. Yokoyama, A. Hiwara, S. Fujita, and A. Omaru, U.S. Pat. 5,633,099 (1997). 102. Z. X. Shu, F. S. McMHlan and J. J. Murray, U.S. Pat. 5,571,635 (1996). 103. Z. X. Shu, R. S. McMillan, J. J. Murray, and I. J. Davidson, J. Electrochem. Soc., 142, L161 (1995): 104.
  100. D. Aurbach, B. Markovsky, A Shechter, and V. Em- Eli, J. Electrochem. Soc., 143, 3809 (1996). 105. D. Aurbach, B. Markovsky, A. Shechter, and V. Em- Eli, J. Electrochem. Soc., 143, 3809 (1997). 106. D. Aurbach, V. Em-Eli, B. Markovsky, A. Zaban, A. Schechter, S. Luski, V. Carmeli, and H. Yamin, in Rechargeable Lithium and Lithium-Ion Batteries S. Megahed, B. M. Barnett, and L. Xie, Editors, PV 94-28, p. 26, The Electrochemical Society Proceed- ings Series, Pennington, NJ (1994). 107. F. Imhof and P. Novak, Abstract 125, p. 139, The Elec- trochemical Society Meeting Abstracts. Vol. 97-2, Paris, France, Aug 31-Sept 5, 1997. 108. M. Jean, A. Chausse, and F. Messina, Abstract 146, p. 169, The Electrochemical Society Meeting Ab- stracts, Vol. 97-2, Paris, France, Aug 3l-Sept 5, 1997. 109. B. Simon, J. P Boeuve, and M. Broussely, J. Power Sources, 43-44, 65 (1993). 110. G. Pistoia, D. Zane, and V. Zhang, J. Electrochem. Soc., 142, 2551 (1995). 111. G. Pistoia, A. Antonini, R. Rosati and D. Zane, Elec- trochim. Acta, 41, 2683 (1996). 112. F. Peled, D. Golodnitsky, G. Ardel, C. Menachem, D. Bar Tow, and V. Eshkenazy, Moter. Res. Soc. Symp. Proc., 393, 209 (1995). 113. F. Peled, J. Power Sources, 9, 253 (1983). 114. F. Peled, D. Golodnitsky, C. Ardel, and V Eshkenazy, Electrochim. Acta, 40, 2197 (1995). 115. A. Meitav and F. Peled, J. Electrochem. Soc., 128, 825 (1981). 116. F. Peled and H. Straze, J. Electrochem. Soc., 124, 1030 (1977). 117. U. von Sacken, F. Nodwell, A. Sundher, and J. R. Dahn, Solid State lonics, 69, 284 (1994). 118. M. Garreau, J. Thevenin, and B. Milandou, in Lithium Batteries, A. N. Dey, Editor, PV 84-1, p. 28, The Flectrochemical Society Proceedings Series, Pen- nington, NJ (1984). 119. J. W. Braithwaite, A. Gonzales, S. L. Lucero, D. F. Peebles, J. A. Ohlhausen, W. R. Ciesalk, and C. Nagasubramanian, Sandia National Laboratories Report, SAND97-0507 (1997). 120. J. Braithwaite, C. Nagasubramanian, S. Lucero, and W Cieslak, Abstract 64, p. 85, The Flectrochemical Society Meeting Abstracts, Vol. 96-2, San Antonio, TX, Oct 6-11, 1996. 121. C. Pistoia, A. Antonini, F. Rosati, and C. Bellitto, Abstract 213, p. 257, The Flectrochemical Society Meeting Abstracts, Vol. 97-2, Paris, France, Aug 31- Sept 5, 1997. 122. V. Chen, L. Song, T. M. Devine, and J. W. Evans, Two papers presented at Advanced Non-Aqueous Bat- tery Technology Research and Development Work- shop, p. 49, Oct 15-17, 1997. 123. IUPAC Chemical Data Series-No.22, Stability Con- stants of Metal-Ion Complexes, Part B, Organic Lig- ands, Compiled by Douglas D. Perrin, Pergamon Press, New York (1979). 124. G. G. Amatucci, Unpublished results. 125. M. M. Thackeray, J. Electrochem. Soc., 142, 2558 (1995). 126. M. M. Thackeray, J. Electrochem. Soc., 144, L100 (1997). 127. J. M. Tarascon, W. R. McKinnon, F Coowar, P N. Bowmer, G. Amatucci, and D. Guyomard, J. Elec- trochem. Soc., 141, 1421 (1994). 128. R. J. Gummow, A. de Kock, and M. M. Thackeray, Solid State lonics, 69, 59 (1994). 129. S. J. Wen, T. J. Richardson, L. Ma, K. A. Striebel, P. N. Ross, Jr., and E. J. Cairns, J. Elect rochem. Soc., 143, L136 (1996). 130. Y. Xia, V. Zhou, and M. Yoshio, J. Electrochem. Soc., 144, 2593 (1997). 131. A. Blyr, C. Sigala, G. Amatucci, D. Guyomard, V. Chabre, and J-M. Tarascon, J. Electrochem. Soc., 145, 194 (1998). 132.
  101. Levenspiel, Chemical Reaction Engineering, 2nd ed., Wiley Eastern Limited, New York (1972).

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Metadata

Authors
Arora, P., White, R. E., & Doyle, M.
Affiliations
DuPont (United States) (US)
ORCID
White, Ralph E.
Venue
Journal of The Electrochemical Society
Publisher
The Electrochemical Society
Published
1998-10-01
Volume
145
Issue
10
Pages
3647-3667
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
DOI
10.1149/1.1838857
OpenAlex
W2014862314
Cited by
1,408
References
0
Citations by year
2026: 43 · 2025: 69 · 2024: 59 · 2023: 75 · 2022: 74 · 2021: 70 · 2020: 89 · 2019: 96 · 2018: 86 · 2017: 117 · 2016: 87 · 2015: 96 · 2014: 92 · 2013: 63 · 2012: 39
FWCI
47.70
Type
journal article
Language
en
Open access
Licence
Locations
  • Journal of The Electrochemical Society (publishedVersion)
  • Scholar Commons (University of South Carolina) (submittedVersion)
Topics
  • Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Keywords
lithium-ion batteries, capacity fade, capacity loss mechanisms, side reactions, overcharging, overdischarge, electrolyte decomposition, passive film formation, active material dissolution, cycling performance

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