Hyperbranched polycoumarates with photofunctional multiple shape memory
Abstract
In good shape: The films of hyperbranched polycoumarate derivatives can undergo a reversible [2+2] cycloaddition under irradiation of UV light and behave like photomechanical elastomers. From a predetermined original shape A the photonically and thermally memorized shapes B and C were obtained. The original shape was recovered by photoirradiation (see picture; Tg =glass transition temperature).
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New t-SME was obtained by combining UV light irradiation and direct heating in order to fix successively both temporary shapes.
“New t-SME was obtained by combining UV light irradiation and direct heating in order to fix successively both temporary shapes [94].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [94]
Generated physical crosslinks by chain entanglement were sufficient for demonstrating the materials' thermal- and light-SMEs.
“The generated physical crosslinks, by chain entanglement, were sufficient on demonstrating the materials thermal- and light-SMEs.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [94]
Reheating shape (C) at 70°C gave the photo-active shape (D), the same as shape (B).
“Reheating of the shape (C) at 70 ° C gave the photo-active shape (D), the same as the shape (B).”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [94]
Shape (C) was obtained by hot-deformation at 70°C of shape (B).
“At the next step, the shape (C) was obtained by hot-deformation at 70 ° C of the shape (B).”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [94]
It was possible to recover the original shape (A) after 3 h upon UV light irradiation at λ = 250 nm.
“Finally it was possible to recover the original shape (A) after 3 h upon UV light irradiation at k = 250 nm.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [94]
The effect was demonstrated by bending the initial shape (A) of the film to a stable round shape (B) via irradiation upon UV light (λ = 280-450 nm).
“The said effect was demonstrated by the bending of the initial shape (A) of the film to a stable round shape (B) via its irradiation upon UV light ( k = 280-450 nm).”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [94]
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- Authors
- Wang, S., Kaneko, D., Okajima, M., Yasaki, K., Tateyama, S., & Kaneko, T.
- Affiliations
- Kyushu Institute of Technology (JP)
- Japan Advanced Institute of Science and Technology (JP)
- Corresponding author
- Kaneko, Tatsuo
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-09-05
- Volume
- 52
- Issue
- 42
- Pages
- 11143-11148
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2153906671
- Cited by
- 54
- References
- 46
- Citations by year
- 2025: 2 · 2024: 4 · 2023: 5 · 2022: 2 · 2021: 3 · 2020: 5 · 2019: 9 · 2018: 6 · 2017: 7 · 2016: 2 · 2015: 7 · 2014: 2
- FWCI
- 2.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- shape memory polymers, [2+2] cycloaddition, UV irradiation, glass transition temperature, polymer films
- MeSH terms
- Coumaric Acids, Polymers, Computer-Aided Design, Photochemical Processes
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