Chemoselective Polymerization Control: From Mixed‐Monomer Feedstock to Copolymers

Controlled Ring-Opening Polymerization of Lactide and Glycolide

Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257

Copolymerization. I. A Basis for Comparing the Behavior of Monomers in Copolymerization; The Copolymerization of Styrene and Methyl Methacrylate

Mayo, F. R., & Lewis, F. M. (1944) · Journal of the American Chemical Society · doi:10.1021/ja01237a052 · Cited by 1,952

Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO 2

Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593

Chemical syntheses of biodegradable polymers

Okada, M. (2002) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00039-9 · Cited by 1,239

Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism

Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B., & Coates, G. W. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003851f · Cited by 1,207

Discrete Metal‐Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism

Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154

Cobalt catalysts for the coupling of CO 2 and epoxides to provide polycarbonates and cyclic carbonates

Lu, X., & Darensbourg, D. J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15142h · Cited by 1,127

Polymers from Renewable Resources: A Perspective for a Special Issue of Polymer Reviews

Williams, C. K., & Hillmyer, M. A. (2008) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1080/15583720701834133 · Cited by 992

Catalysts for CO 2 /epoxide copolymerisation

Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797

Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms

Klaus, S., Lehenmeier, M. W., Anderson, C. E., & Rieger, B. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.12.002 · Cited by 712

Fast and switchable ring-opening polymerization of biorenewable omega-substituted lactones towards sustainable copolymers with facile control over monomer sequences

Jiang, J., Xue, L., Wang, J., Qiang, H., Li, J., Du, J., & Zhu, Y. (2024) · Polymer Chemistry · doi:10.1039/d4py00404c · Cited by 4

Combining Sustainable Polymerization Routes for the Preparation of Polyesters, Polycarbonates, and Copolymers

Romain, C., & Williams, C. K. (2015) · ACS symposium series · doi:10.1021/bk-2015-1192.ch009 · Cited by 3

Recent progress in the preparation of multicomponent polyesters by selective catalysis from mixed monomers

Zhou, Y., Chen, X., & Pang, X. (2021) · Scientia Sinica Chimica · doi:10.1360/ssc-2020-0181 · Cited by 3

Polymerization of Epoxides

Darensbourg, D. J., & Bhat, G. A. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-820206-7.00123-2 · Cited by 3

Sequence‐Controlled Polymers by Chain Polymerization

He, J., Ren, J., & Mastan, E. (2017) · Wiley eBooks · doi:10.1002/9783527806096.ch10 · Cited by 3

Salen–cobalt catalyzed degradation of polypropylene carbonate and its application in one-pot tandem synthesis of propylene carbonate

Ge, Q., Dong, B., Chen, Y., Wang, X., Wang, X., Fan, C., Chen, C., Lin, S., Pan, Q., & Ng, F. T. T. (2024) · New Journal of Chemistry · doi:10.1039/d4nj02996h · Cited by 2

Access to Microstructurally Complex Block Copolymers via Switchable Ring-Opening Polymerization of Cyclic Ester Mixtures

Seed, D. J. E., Milner, A. B., Walker, G. R., & Platel, R. H. (2025) · Macromolecules · doi:10.1021/acs.macromol.5c00822 · Cited by 2

Carbon Dioxide and Epoxide Copolymerization Processes: Advances in Catalyst Design Over Decades

Wani, I. A., Hassan, M., & Bhat, G. A. (2025) · ChemCatChem · doi:10.1002/cctc.202500959 · Cited by 3

One-pot synthesis of sequence-controlled multiblock copolymers via intramolecular Lewis pair mediated switchable polymerization of epoxide/isocyanate mixtures

Zhao, J., Wang, X., Song, X., Guo, X., Kou, X., Shi, M., Gu, Y., Chen, Y., Zhong, R., & Li, Z. (2025) · Science China Chemistry · doi:10.1007/s11426-025-2811-y · Cited by 2

Multi‐Site Organoboron Catalysts Enable Sequence‐Regulated Terpolymerization of Epoxides, CO 2 , and β ‐Propiolactone via Intermolecular Chain Shuttling

Yan, R., Li, M., Li, S., Li, B., & Wu, G. (2025) · Angewandte Chemie International Edition · doi:10.1002/anie.202517263 · Cited by 2

Synthesis of Sequence‐specific Poly(ester‐carbonate) Copolymers via Chemoselective Terpolymerization Controlled by the Stoichiometric Ratio of Phosphazene/Triethylborane

Ma, Y., You, X.-X., Zhang, J., Wang, X., Kou, X., Liu, S., Zhong, R., & Li, Z. (2023) · Angewandte Chemie · doi:10.1002/ange.202303315 · Cited by 2

Sustainable polycarbonates production from CO2

Suo, H., Tang, H., Qu, R., Liu, J., & Qin, Y. (2024) · Advances in bioenergy · doi:10.1016/bs.aibe.2024.03.001 · Cited by 2

Preparation of CO2 ‐based poly(carbonate‐co‐lactide) with different porphyrin aluminum ( III ) catalysts

Li, T., Liu, Z., Chen, Y., Sun, N., Shu, H., Wu, L., Zhang, C., & Xie, D. (2023) · Journal of Polymer Science · doi:10.1002/pol.20230116 · Cited by 2

PolymerizationCatalysis by Metal Phenolates

Dagorne, S., & Romain, C. (2016) · Patai's chemistry of functional groups · doi:10.1002/9780470682531.pat0853 · Cited by 2

A Polymer Magician: Professor Charlotte K. Williams

Hopmann, K. H. (2020) · Organometallics · doi:10.1021/acs.organomet.0c00539 · Cited by 2

Selective Copolymerization from Mixed Monomers of Phthalic Anhydride, Propylene Oxide and Lactide Using Nano-Sized Zinc Glutarate

Zhang, X., Li, Z., Wang, L., Yu, J., Liu, Y., & Song, P. (2024) · Nanomaterials · doi:10.3390/nano14181535 · Cited by 1

Structural and Kinetics Studies of N^O‐, O^N^O‐, and N^N‐ Schiff Base Mn Complexes as Highly Active Catalysts in the Ring‐Opening Polymerization of rac‐Lactides

Zikode, M., Ngwenya, A., Becker, T., Herres‐Pawlis, S., & Ojwach, S. O. (2025) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.202500126 · Cited by 1

Tuneable zinc scorpionates for CO2 fixation into sustainable materials: access to polycarbonates and tailored hybrid poly(L-lactide)s-b-polycarbonates

Navarro, M., González, D., Moya‐López, C., Lara‐Sánchez, A., Fernández, I., Garcés, A., & Sánchez‐Barba, L. F. (2025) · European Polymer Journal · doi:10.1016/j.eurpolymj.2025.114361 · Cited by 1

Chiral proline-derived Zn( ii ) complexes as catalysts for ring-opening polymerization and ring-opening copolymerization reactions

Ray, R. K., Kumari, M., Mondal, K. C., & Chakraborty, D. (2026) · Polymer Chemistry · doi:10.1039/d5py01089f · Cited by 1

Silica-Supported Zinc(II)–Schiff-Base Catalysts for Lactide Ring-Opening Polymerization: Influence of Support Morphology and Ligand Substituents

González, D. M., Picero, F., Fuentes, O. R., Oyarce, J., & Blázquez‐Blázquez, E. (2026) · Polymers · doi:10.3390/polym18060737 · Cited by 1

Synthesis of sulfur-containing polycarbonate block copolymers via Salen-metal catalyzed copolymerization of CO2, propylene oxide, and phthalic thioanhydride

Lu, S., Ge, Q., Fan, C., Wang, X., Chen, Y., Lin, S., & Pan, Q. (2023) · Journal of Macromolecular Science Part A · doi:10.1080/10601325.2023.2218405 · Cited by 1

A photoswitchable organocatalyst controls trimethylene carbonate and δ-valerolactone copolymerization

Riffel, M. N., Hern, Z. C., & Diaconescu, P. L. (2018) · 中国科学通报：英文版 · doi:10.1016/j.scib.2018.11.001 · Cited by 1

Polymerization Reactions with CO 2

Li, W., & Lu, X. (2022) · Wiley eBooks · doi:10.1002/9783527831883.ch29 · Cited by 1

Aliphatic Poly(carbonate)s: Syntheses, Structures, and Applications

Hu, L., Zhang, C., & Zhang, X. (2022) · Wiley eBooks · doi:10.1002/9783527815562.mme0023

Mechanistic Study of Co2/Po Copolymerization Over Diethylzinc-Trihydric Glycerine CatalystPreprint

Nie, Y., Wu, Y., Sun, L., Mei, Y., Chen, L., Xi, Z., & Liu, Z. (2023) · SSRN Electronic Journal · doi:10.2139/ssrn.4569581

Using Redox‐Switchable Polymerization Catalysis to Synthesize a Chemically Recyclable Thermoplastic Elastomer

Liu, J., Blosch, S. E., Volokhova, A. S., Crater, E. R., Gallin, C. F., Moore, R. B., Matson, J. B., & Byers, J. A. (2024) · Angewandte Chemie · doi:10.1002/ange.202317699

Diethyl zinc/glycerol catalyzed CO2/PO copolymerization: A combined experimental and DFT study

Nie, Y., Mei, Y., Zhu, Y., Mu, Y., Wu, Y., Sun, L., Xi, Z., & Liu, Z. (2024) · Molecular Catalysis · doi:10.1016/j.mcat.2024.114328

Switchable, chiral aluminium catalysts for ring opening polymerisations

Jenkins, D. T., Trodden, E. C., Andrésen, J. M., Mansell, S. M., & McIntosh, R. D. (2024) · Dalton Transactions · doi:10.1039/d4dt02831g

Sequence Control of Degradable Polymers in Precision Polymerization

Li, F., Gao, T., Isono, T., & Satoh, T. (2025) · Kobunshi · doi:10.1295/kobunshi.74.4_184

Multi‐Site Organoboron Catalysts Enable Sequence‐Regulated Terpolymerization of Epoxides, CO 2 , and β ‐Propiolactone via Intermolecular Chain Shuttling

Yan, R., Li, M., Li, S., Li, B., & Wu, G. (2025) · Angewandte Chemie · doi:10.1002/ange.202517263

Kinetic research of PO-CO2 copolymerization via a micromixer embedded parallel reactor system

Zhang, Q., Song, J., Wang, X., Wang, K., Lu, Z., Yang, J., & Luo, G. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.174941

Nouveaux (co)polyesters à séquences contrôlées par catalyse de polymérisation stéréosélective

Ligny, R. (2018) · theses.fr (ABES) · doi:10.70675/0f21bd90z509fz4cd5zbc19z37703c956d74

Self-switchable terpolymerization of cyclic esters, epoxides and cyclic anhydrides using phosphazenium salt/urea binary catalyst

Zhang, Z., Song, J., & Ren, C. (2026) · European Polymer Journal · doi:10.1016/j.eurpolymj.2026.114746

Preparation and copolymerization behavior of recyclable copolyesters based on bio-based δ-valerolactone and α,α-dipropyl-δ-valerolactone

Chang, H., Niu, H., & Shen, Y. (2026) · Journal of Physics Conference Series · doi:10.1088/1742-6596/3269/1/012102

Terpolymerization of epoxide, oxetane, and CO 2 for the synthesis of polycarbonates with high CO 2 contents, physical tunability, and enzymatic degradability

Niki, K., Maeda, C., & Ema, T. (2026) · Green Chemistry · doi:10.1039/d6gc02175a

Direct Synthesis of Well‐Defined Epoxide‐Terminated Telechelic Polymers via an Alcohol‐Mediated Self‐Switching Strategy

Yan, S., Liu, S., Liu, Z., Liao, C., Qinghai, Z. H. O. U., Zhang, H., & Wang, X. (2026) · Angewandte Chemie International Edition · doi:10.1002/anie.4383253

Fluorine-Modulated Reactivity Enables One-Pot Kinetic Sequence Programming of Block Copolyesters

Ke, C., Suzuki, R., Yamamoto, T., Isono, T., Liou, G., & Satoh, T. (2026) · Polymers · doi:10.3390/polym18161977

Terpolymerization of Glycolide, Cyclohexene Oxide and CO2 for Crystalline Poly(carbonate-esters)

马静, Zhang, C., & Zhang, X. (2026) · Polymer science & technology. · doi:10.1021/polymscitech.6c00100

Selective Polymerization Catalysis: Controlling the Metal Chain End Group to Prepare Block Copolyesters

Zhu, Y., Romain, C., & Williams, C. K. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04541 · Cited by 178

Chemoselective Polymerizations from Mixtures of Epoxide, Lactone, Anhydride, and Carbon Dioxide

Romain, C., Zhu, Y., Dingwall, P., Paul, S., Rzepa, H. S., Buchard, A., & Williams, C. K. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b13070 · Cited by 258

Zinc versus Magnesium: Orthogonal Catalyst Reactivity in Selective Polymerizations of Epoxides, Bio‐derived Anhydrides and Carbon Dioxide

Saini, P. K., Fiorani, G., Mathers, R. T., & Williams, C. K. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201605690 · Cited by 52

Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity

Plajer, A. J., & Williams, C. K. (2021) · Angewandte Chemie · doi:10.1002/ange.202101180 · Cited by 11

Highly Active and Readily Accessible Proline‐Based Dizinc Catalyst for CO2/Epoxide Copolymerization

Schütze, M., Sebastian Dechert, B., & Meyer, F. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201704754 · Cited by 25