Cited by 1,048Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsHydrogen Storage and Materials

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Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction

Kibsgaard, Jakob, Jaramillo, Thomas F.·2014·Angewandte Chemie International Edition

DOI 10.1002/anie.201408222

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Abstract

Introducing sulfur into the surface of molybdenum phosphide (MoP) produces a molybdenum phosphosulfide (MoP|S) catalyst with superb activity and stability for the hydrogen evolution reaction (HER) in acidic environments. The MoP|S catalyst reported herein exhibits one of the highest HER activities of any non-noble-metal electrocatalyst investigated in strong acid, while remaining perfectly stable in accelerated durability testing. Whereas mixed-metal alloy catalysts are well-known, MoP|S represents a more uncommon mixed-anion catalyst where synergistic effects between sulfur and phosphorus produce a high-surface-area electrode that is more active than those based on either the pure sulfide or the pure phosphide. The extraordinarily high activity and stability of this catalyst open up avenues to replace platinum in technologies relevant to renewable energies, such as proton exchange membrane (PEM) electrolyzers and solar photoelectrochemical (PEC) water-splitting cells.

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Authors: Kibsgaard, J., & Jaramillo, T. F.
Affiliations: Stanford University (US)
Corresponding author: Jaramillo, Thomas F.
ORCID: Kibsgaard, Jakob
Jaramillo, Thomas F.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2014-10-30
Volume: 53
Issue: 52
Pages: 14433-14437
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201408222
OpenAlex: W2167228022
Cited by: 1,048
References: 32
Citations by year: 2026: 31 · 2025: 47 · 2024: 62 · 2023: 71 · 2022: 83 · 2021: 103 · 2020: 121 · 2019: 145 · 2018: 132 · 2017: 111 · 2016: 87 · 2015: 52 · 2014: 1
FWCI: 27.53
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Keywords: hydrogen evolution reaction, electrocatalysts, acid stability, non-noble metal catalysts, accelerated durability testing, proton exchange membrane electrolyzer, platinum-free catalysts

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Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction

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