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The Effect of Water upon Deep Eutectic Solvent Nanostructure: An Unusual Transition from Ionic Mixture to Aqueous Solution
Open accessAbstract
The nanostructure of a series of choline chloride/urea/water deep eutectic solvent mixtures was characterized across a wide hydration range by neutron total scattering and empirical potential structure refinement (EPSR). As the structure is significantly altered, even at low hydration levels, reporting the DES water content is important. However, the DES nanostructure is retained to a remarkably high level of water (ca. 42 wt % H 2 O) because of solvophobic sequestration of water into nanostructured domains around cholinium cations. At 51 wt %/83 mol % H 2 O, this segregation becomes unfavorable, and the DES structure is disrupted; instead, water–water and DES–water interactions dominate. At and above this hydration level, the DES–water mixture is best described as an aqueous solution of DES components.
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Cites
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Cited by
Deep eutectic solvents: A review of fundamentals and applications
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Metadata
- Authors
- Hammond, O. S., Bowron, D. T., & Edler, K. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-05-29
- Volume
- 56
- Issue
- 33
- Pages
- 9782-9785
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2610973917
- Cited by
- 779
- References
- 7
- FWCI
- 17.24
- Type
- journal article
- Language
- en
- Open access
- hybrid
- Funders
- Engineering and Physical Sciences Research Council (EP/L016354/1)
- Science and Technology Facilities Council (ISIS Studentship 3578)
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- Hammond, O. S., Bowron, D. T., & Edler, K. J. (2017). The Effect of Water upon Deep Eutectic Solvent Nanostructure: An Unusual Transition from Ionic Mixture to Aqueous Solution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201702486
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