The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect‐Rich Plasma‐Activated Silver Catalysts
Open accessAbstract
Efficient, stable catalysts with high selectivity for a single product are essential if electroreduction of CO 2 is to become a viable route to the synthesis of industrial feedstocks and fuels. A plasma oxidation pre‐treatment of silver foil enhances the number of low‐coordinated catalytically active sites, which dramatically lowers the overpotential and increases the activity of CO 2 electroreduction to CO. At −0.6 V versus RHE more than 90 % Faradaic efficiency towards CO was achieved on a pre‐oxidized silver foil. While transmission electron microscopy (TEM) and operando X‐ray absorption spectroscopy showed that oxygen species can survive in the bulk of the catalyst during the reaction, quasi in situ X‐ray photoelectron spectroscopy showed that the surface is metallic under reaction conditions. DFT calculations reveal that the defect‐rich surface of the plasma‐oxidized silver foils in the presence of local electric fields drastically decrease the overpotential of CO 2 electroreduction.
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Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Self-citationElectric Field Effects in Electrochemical CO 2 Reduction
Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702
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Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443
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Insight into Electrochemical CO 2 Reduction on Surface-Molecule-Mediated Ag Nanoparticles
Kim, C., Eom, T., Jee, M. S., Jung, H., Kim, H., Min, B. K., & Hwang, Y. J. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b01862 · Cited by 265
Carbon Foam Decorated with Silver Nanoparticles for Electrochemical CO2 Conversion
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Cited by
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Defect and Interface Engineering for Aqueous Electrocatalytic CO2 Reduction
Wang, Y., Han, P., Lv, X., Zhang, L., & Zheng, G. (2018) · Joule · doi:10.1016/j.joule.2018.09.021 · Cited by 677
Theoretical Insights into Heterogeneous (Photo)electrochemical CO2Reduction
Xu, S., & Carter, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00481 · Cited by 652
Recent Advances in Electrochemical CO2‐to‐CO Conversion on Heterogeneous Catalysts
Zheng, T., Jiang, K., & Wang, H. (2018) · Advanced Materials · doi:10.1002/adma.201802066 · Cited by 579
Metadata
- Authors
- Mistry, H., Choi, Y., Bagger, A., Scholten, F., Bonifacio, C. S., Sinev, I., Divins, N. J., Zegkinoglou, I., Jeon, H. S., Kisslinger, K., Stach, E. A., Yang, J. C., Rossmeisl, J., & Roldan Cuenya, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-08-10
- Volume
- 56
- Issue
- 38
- Pages
- 11394-11398
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2736202589
- Cited by
- 234
- References
- 8
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- green
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- Mistry, H., Choi, Y., Bagger, A., Scholten, F., Bonifacio, C. S., Sinev, I., Divins, N. J., Zegkinoglou, I., Jeon, H. S., Kisslinger, K., Stach, E. A., Yang, J. C., Rossmeisl, J., & Roldan Cuenya, B. (2017). Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect‐Rich Plasma‐Activated Silver Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201704613
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